Advertisements
Advertisements
प्रश्न
What is the relation between Kp and Kc? Given one example for which Kp is equal to Kc.
उत्तर
The relation between Kp and Kc is Kp =
KC (RT)∆ng
Kp = equilibrium constant is terms of partial pressure.
Kc = equilibrium constant is terms of concentration.
R = gas constant
T = Temperature.
∆ng = Difference between the sum of the number of moles of products and the sum of a number of moles of reactants in the gas phase.
When ∆ng = 0
Kp = KC(RT)0 = KC i.e., Kp = KC
Example: \[\ce{H2(g) + l2(g) <=> 2HI(g)}\]
∆ng = 2 – 2 = 0
∴ Kp = KC for the synthesis of HI.
APPEARS IN
संबंधित प्रश्न
An equilibrium constant of 3.2 × 10-6 for a reaction means, the equilibrium is
For the reaction \[\ce{AB(g) <=> A(g) + B(g)}\], at equilibrium, AB is 20 % dissociated at a total pressure of P, the equilibrium constant Kp is related to the total pressure by the expression
The values of Kp1 and Kp2; for the reactions,
X ⇌ Y + Z,
A ⇌ 2B are in the ratio 9 : 1 if degree of dissociation of X and A be equal then total pressure at equilibrium P1, and P2 are in the ratio
In a chemical equilibrium, the rate constant for the forward reaction is 2.5 × 10-2, and the equilibrium constant is 50. The rate constant for the reverse reaction is,
For the formation of Two moles of SO3(g) from SO2 and O2, the equilibrium constant is K1. The equilibrium constant for the dissociation of one mole of SO3 into SO2 and O2 is
For a given reaction at a particular temperature, the equilibrium constant has a constant value. Is the value of Q also constant? Explain.
One mole of PCl5 is heated in one litre closed container. If 0.6 mole of chlorine is found at equilibrium, Calculate the value of equilibrium constant.
For the reaction
\[\ce{SrCO3(s) <=> SrO(s) + CO2(g)}\]
the value of equilibrium constant Kp = 2.2 × 10-4 at 1002 K. Calculate Kc for the reaction.
To study the decomposition of hydrogen iodide, a student fills an evacuated 3 litre flask with 0.3 mol of HI gas and allows the reaction to proceed at 500°C. At equilibrium he found the concentration of HI which is equal to 0.05 M. Calculate Kc and Kp.
The equilibrium constant Kp for the reaction \[\ce{N2 (g) + 3H2 (g) <=> 2NH3 (g)}\] is 8.19 × 102 at 298 K and 4.6 × 10-1 at 498 K. Calculate ∆H° for the reaction.