Advertisements
Advertisements
प्रश्न
Answer the following in brief.
Explain the effect of dilution of the solution on conductivity.
उत्तर
- The electrolytic conductivity is the electrical conductance of unit volume (1 cm3) of solution. It depends on the number of current-carrying ions present in unit volume of solution.
- On dilution total number of ions increases as a result of an increased degree of dissociation.
- An increase in the total number of ions is not in the proportion of dilution. Therefore, the number of ions per unit volume of solution decreases.
- This results in a decrease of conductivity with a decrease in the concentration of the solution.
APPEARS IN
संबंधित प्रश्न
The molar conductivity of 0.05 M BaCl2 solution at 25° C is 223Ω-1 cm2 mol-1. What is its conductivity?
Choose the most correct option.
Two solutions have the ratio of their concentrations 0.4 and ratio of their conductivities 0.216. The ratio of their molar conductivities will be ______.
Answer the following:
What is Kohlrausch law of independent migration of ions? How is it useful in obtaining molar conductivity at zero concentration of a weak electrolyte? Explain with an example.
In case of weak electrolyte the graph Λ vs `sqrt"c"` is _______.
State Kohlrausch law of independent migration of ions.
Write three important steps required to determine molar conductivity.
Molar conductance of BaCl2, H2SO4 and HCl at infinite dilution are X1, X2 and X3 respectively. Molar conductance of BaSO4 at infinite dilution is ____________.
If resistivity of 0.8 M KCI solution is 2.5 × 10-3 Ω cm. Calculate molar conductivity of solution?
What will be the concentration of NaCl solution, if the molar conductivity and conductivity of NaCl solution is 124.3 Ω−1 cm2 mol−1 and 1.243 × 10−4 Ω−1 cm2 respectively?
The molar conductance of 0.001 M acetic acid is 50 ohm−1 cm2 mol−1. The limiting molar conductance is 250 ohm−1 cm2 mol−1. What is its degree of ionization?
A conductivity cell having cell constant 8.76 cm−1, placed in 0.01 M solution of an electrolyte offered a resistance of 1000 ohms. What is the specific conductance of electrolytes?
What is the common unit of conductivity if the dimensions are expressed in centimeter?
In 2 hours, a certain current liberates 0.504 g hydrogen. How many grams of copper can be deposited by the same current flowing for the same time in a CuSO4 solution?
(Molar mass of Cu = 63.5 g mol−1, H2 = 2.0 g mol−1)
What is the cell constant of `"N"/10 "KCl"` solution at 25°C, if conductivity and resistance of a solution is 0.0112 Ω−1 cm−1 and 55.0 Ω respectively?
What is the relation between cell constant, conductivity and electrical resistance?
The distance between electrodes of a conductivity cell is 0.98 cm and area of cross section is 1.96 cm2. What is the cell constant?
A conductivity cell dipped in 0.01 M AgNO3 solution gives a resistance of 3160 ohms. If cell constant is 0.47 cm−1, what is the conductivity of AgNO3 solution?
The value of [H3O+] in mol lit–1 of 0.001 M acetic acid solution (Ka = 1.8 × 10–5) is ______.
Specific conductance of 0.1 M sodium chloride solution is 1.06 × 10−2 ohm−1 cm−1. Its molar conductance in ohm−1 cm2 mol−1 is ______.
What is the SI unit of conductivity?
Which of the following has least conductivity in aqueous solution?
Molar conductivities at infinite dilution of Mg2+ and Br- are 105.8 Ω-1 cm2 mol-1 and 78.2 Ω-1 cm2 mol-1 respectively. Calculate molar conductivity at zero concentration of MgBr2.
Define cell constant. Give its units.
Write the relation between molar conductivity and molar ionic conductivities for the electrolytes:
- Na2SO4
- AlCl3
