English

Answer the following in brief. Explain the effect of dilution of the solution on conductivity. - Chemistry

Advertisements
Advertisements

Question

Answer the following in brief.

Explain the effect of dilution of the solution on conductivity.

Short Note

Solution

  1. The electrolytic conductivity is the electrical conductance of unit volume (1 cm3) of solution. It depends on the number of current-carrying ions present in unit volume of solution.
  2. On dilution total number of ions increases as a result of an increased degree of dissociation.
  3. An increase in the total number of ions is not in the proportion of dilution. Therefore, the number of ions per unit volume of solution decreases.
  4. This results in a decrease of conductivity with a decrease in the concentration of the solution.
shaalaa.com
Electrical Conductance of Solution
  Is there an error in this question or solution?
Chapter 5: Electrochemistry - Exercises [Page 118]

APPEARS IN

Balbharati Chemistry [English] 12 Standard HSC
Chapter 5 Electrochemistry
Exercises | Q 3.01 | Page 118

RELATED QUESTIONS

Choose the most correct option.

Two solutions have the ratio of their concentrations 0.4 and ratio of their conductivities 0.216. The ratio of their molar conductivities will be ______.


SI unit of conductivity is _______.


Give SI unit of resistivity.


Write an equation that shows the relationship between molar conductivity and degree of dissociation of weak electrolyte.


Write relation between electrolytic conductivity and molar conductivity.


The molar conductances at infinite dilution `(∧_0)` for electrolytes B+A and C+A are 140 and 120 S cm2 mol−1. The molar conductance at infinite dilution for B+X is 198 S cm2 mol−1. The `∧_0` (in S cm2 mol−1) of C+X is __________.


The conductivity of 0.02 M solution of NaCl is 2.6 × 10−2 S cm−1. What is its molar conductivity?


Which among the following solution has the highest conductivity (k) value?


Conductivity of KCI solution is 0.0027 Ω−1 m−1 at 25°C. The resistance of the solution is 82.4 Ω. The cell constant is ____________ m−1.


The SI unit of resistivity and molar conductivity are respectively ____________.


The molar conductivities at infinite dilution for sodium acetate, HCI and NaCl are 91 S cm2 mol-1, 425.9 S cm2 mol-1 and 126.4 S cm2 mol-1 respectively. The molar conductivity of acetic acid at infinite dilution is ______.


The resistance of a conductivity cell containing 0.001 M KCl solution at 298 K is 1500 Ω. What is the cell constant if conductivity of 0.001 M KCI solution at 298 K is 0.146 × 10−3 S cm−1?


What is the common unit of conductivity if the dimensions are expressed in centimeter?


Which of the following graph represents the variation of `∧` with `sqrt"c"` for acetic acid solution?


What is the cell constant of `"N"/10 "KCl"` solution at 25°C, if conductivity and resistance of a solution is 0.0112 Ω−1 cm−1 and 55.0 Ω respectively?


The distance between electrodes of a conductivity cell is 0.98 cm and area of cross section is 1.96 cm2. What is the cell constant?


What is the value of cell constant if conductance and conductivity of a solution is same?


If the resistivity of 0.1 M KCI solution is 50 Ω cm, what is it's molar conductivity?


Specific conductance of 0.1 M sodium chloride solution is 1.06 × 10−2 ohm−1 cm−1. Its molar conductance in ohm−1 cm2 mol−1 is ______.


What is the SI unit of conductivity?


Which of the following has least conductivity in aqueous solution? 


Molar conductivities at infinite dilution of Mg2+ and Br- are 105.8 Ω-1 cm2 mol-1 and 78.2 Ω-1 cm2 mol-1 respectively. Calculate molar conductivity at zero concentration of MgBr2.


A conductivity cell filled with 0.02 M AgNO3 gives at 25°C resistance of 947 ohms. If the cell constant is 2.3 cm-1, what is the molar conductivity of 0.02 M AgNO3 at 25°C?


Explain the determination of molar conductivity of a weak electrolyte at infinite dilution or zero concentration using Kohlrausch's law.


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×