Advertisements
Advertisements
Question
Write an equation that shows the relationship between molar conductivity and degree of dissociation of weak electrolyte.
Solution
The relationship between molar conductivity (∧c) and degree of dissociation (α) of weak electrolyte is given as
`alpha = Λ_"c"/Λ_0`
where, Λ0 = Limiting molar conductivity
APPEARS IN
RELATED QUESTIONS
The molar conductivity of 0.05 M BaCl2 solution at 25° C is 223Ω-1 cm2 mol-1. What is its conductivity?
Choose the most correct option.
Two solutions have the ratio of their concentrations 0.4 and ratio of their conductivities 0.216. The ratio of their molar conductivities will be ______.
Answer the following in brief.
Explain the effect of dilution of the solution on conductivity.
SI unit of conductivity is _______.
In case of weak electrolyte the graph Λ vs `sqrt"c"` is _______.
The molar conductivity and conductivity of AgNO3 solution is 121.4 Ω–1 cm2 mol–1 and 2.428 × 10–3 Ω–1 cm–1 at 25 °C. What is molar concentration of AgNO3 solution?
Give SI unit of resistivity.
Molar conductance of BaCl2, H2SO4 and HCl at infinite dilution are X1, X2 and X3 respectively. Molar conductance of BaSO4 at infinite dilution is ____________.
The molar conductances at infinite dilution `(∧_0)` for electrolytes B+A− and C+A− are 140 and 120 S cm2 mol−1. The molar conductance at infinite dilution for B+X− is 198 S cm2 mol−1. The `∧_0` (in S cm2 mol−1) of C+X− is __________.
A conductivity cell having cell constant 8.76 cm−1, placed in 0.01 M solution of an electrolyte offered a resistance of 1000 ohms. What is the specific conductance of electrolytes?
The conductivity of 0.02 M solution of NaCl is 2.6 × 10−2 S cm−1. What is its molar conductivity?
The molar conductivities at zero concentration for Ca2+ and CaCl2 are 104 and 256.8 Ω−1 cm2 mol−1 respectively. The molar conductivity at zero concentration for Cl− is ____________.
The molar conductivities at infinite dilution for sodium acetate, HCI and NaCl are 91 S cm2 mol-1, 425.9 S cm2 mol-1 and 126.4 S cm2 mol-1 respectively. The molar conductivity of acetic acid at infinite dilution is ______.
The resistance of a conductivity cell containing 0.001 M KCl solution at 298 K is 1500 Ω. What is the cell constant if conductivity of 0.001 M KCI solution at 298 K is 0.146 × 10−3 S cm−1?
What is the common unit of conductivity if the dimensions are expressed in centimeter?
In 2 hours, a certain current liberates 0.504 g hydrogen. How many grams of copper can be deposited by the same current flowing for the same time in a CuSO4 solution?
(Molar mass of Cu = 63.5 g mol−1, H2 = 2.0 g mol−1)
The distance between electrodes of a conductivity cell is 0.98 cm and area of cross section is 1.96 cm2. What is the cell constant?
Conductivity of a conductor is ____________.
A conductivity cell dipped in 0.01 M AgNO3 solution gives a resistance of 3160 ohms. If cell constant is 0.47 cm−1, what is the conductivity of AgNO3 solution?
If the conductivity of 0.08 M KCl solution is 2 × 10-2 Ω-1, what is the molar conductivity of the solution?
Specific conductance of 0.1 M sodium chloride solution is 1.06 × 10−2 ohm−1 cm−1. Its molar conductance in ohm−1 cm2 mol−1 is ______.
What is the SI unit of conductivity?
Calculate molar conductivity for 0.5 M BaCl2 if its conductivity at 298K is 0.01 Ω–1 cm–1.
Molar conductivities at infinite dilution of Mg2+ and Br- are 105.8 Ω-1 cm2 mol-1 and 78.2 Ω-1 cm2 mol-1 respectively. Calculate molar conductivity at zero concentration of MgBr2.
Define cell constant. Give its units.
Write the relation between molar conductivity and molar ionic conductivities for the electrolytes:
- Na2SO4
- AlCl3
