Advertisements
Advertisements
प्रश्न
Arrange the following:
In increasing order of basic strength:
C6H5NH2, C6H5N(CH3)2, (C2H5)2NH and CH3NH2
उत्तर
C6H5N(CH3)2 is more basic than C6H5NH2 due to the presence of the +I effect of two −CH3 groups in C6H5N(CH3)2. Further, CH3NH2 contains one −CH3 group while (C2H5)2NH contains two −C2H5 groups. Thus, (C2H5)2NH is more basic than C2H5NH2.
Now, C6H5N(CH3)2 is less basic than CH3NH2 because of the −R effect of −C6H5 group.
Hence, the increasing order of the basic strengths of the given compounds is as follows:
C6H5NH2 < C6H5N(CH3)2 < CH3NH2 < (C2H5)2NH
APPEARS IN
संबंधित प्रश्न
Arrange the following in increasing order of their basic strength in aqueous solution:
\[\ce{CH3NH2, (CH3)3N, (CH3)2NH}\]
Arrange the following:
Aniline, p-nitroaniline, p-methylaniline - in the increasing order of their basic strength
Write the structures of main products when aniline reacts with the following reagents : HCl
Arrange the following:
In decreasing order of the pKb values:
C2H5NH2, C6H5NHCH3, (C2H5)2NH and C6H5NH2
Write the structures of the main products of the following reactions:
Write the structures of the main products of the following reactions:
The following reaction takes place in the presence of:
Arrange the following in decreasing order of their basic strength:
C6H5NH2, C2H5NH2, (C2H5)2NH2, NH3
Explain why \[\ce{MeNH2}\] is stronger base than \[\ce{MeOH}\]?
Account for the following:
Acylation of aniline is carried out in the presence of pyridine.
When ethanol is mixed with ammonia and passed over alumina the compound formed is which compound?
Which of the following statement is true about methyl amine?
What is the characteristic smell of liquid amines?
Give reasons for the following observation:
pKb of aniline is lower than the m-nitroaniline.
Which of the following compound cannot be produced if 1-propane amine is treated with NaNO2 and HCl?
Among the following, which has the highest value of pKb?
Arrange the decreasing order of pKb values.
\[\ce{C6H5NH2, C6H5NHCH3, C6H5CH2NH2, CH3NH2, NH3}\]
The correct order of the increasing basic nature of Ammonia, Methylamine and Aniline is:
