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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Complete the synthesis by giving missing starting material, reagent or product. CA6HA5CHO....................+......→Δdil⋅NaOH...CHA3CHA2CHO............ - Chemistry

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प्रश्न

Complete the synthesis by giving missing starting material, reagent or product.

\[\begin{array}{cc}
\ce{C6H5CHO}\phantom{............}\\
\phantom{........}\ce{+\phantom{......}\ce{->[dil.NaOH][\Delta]}}\phantom{...}\\
\ce{CH3CH2CHO}\phantom{............}
\end{array}\]

रासायनिक समीकरणे/रचना

उत्तर

\[\begin{array}{cc}
\phantom{......................................................}\ce{CH3}\\
\phantom{...................................................}|\\
\ce{\underset{Benzaldehyde}{C6H5CHO} + \underset{Propanal}{CH3CH2CHO} ->[dil.NaOH][Claisen-Schimdt reaction]\underset{2-Methyl-3-phenyl-prop-2-enal}{C6H5\overset{3}{C}H = \overset{2}{C} - \overset{1}{C}HO}}
\end{array}\]

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पाठ 12: Aldehydes, Ketones and Carboxylic Acids - Exercises [पृष्ठ ३७९]

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एनसीईआरटी Chemistry [English] Class 12
पाठ 12 Aldehydes, Ketones and Carboxylic Acids
Exercises | Q 17.07 | पृष्ठ ३७९

संबंधित प्रश्‍न

A compound 'A' of molecular formula C2H3OCl undergoes a series of reactions as shown below. Write the structures of A, B, C and D in the following reactions :


Which of the following compounds would undergo aldol condensation, which the Cannizzaro reaction and which neither? Write the structures of the expected products of aldol condensation and Cannizzaro reaction.

  1. Methanal
  2. 2-Methylpentanal
  3. Benzaldehyde
  4. Benzophenone
  5. Cyclohexanone
  6. 1-Phenylpropanone
  7. Phenylacetaldehyde
  8. Butan-1-ol
  9. 2, 2-Dimethylbutanal

How will you convert ethanal into the following compound?

But-2-enal


How will you bring about the following conversion in not more than two steps?

Ethanol to 3-Hydroxybutanal


Describe the following:

Cross aldol condensation


 Why is alpha (α) hydrogen of carbonyl compounds acidic in nature?


Write chemical equations of the following reaction : 

Propanone is treated with dilute Ba (OH)2-.


What is substituted imine called?


Cannizaro’s reaction is not given by ______.


Which of the following conversions can be carried out by Clemmensen Reduction?

(i) Benzaldehyde into benzyl alcohol

(ii) Cyclohexanone into cyclohexane

(iii) Benzoyl chloride into benzaldehyde

(iv) Benzophenone into diphenyl methane


Give reasons to support the answer:

Presence of Alpha hydrogen in aldehydes and ketones is essential for aldol condensation.


Which of the following gives aldol con~ensation reaction?


Identify A and B from the following reaction:

\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{....................}\\
\phantom{}\ce{2CH3 - C = O ->[Ba(OH)2] A ->[Δ] B + H2O}
\end{array}\]


\[\ce{CH3-CH2-CHO ->[dil][alkali] Product}\]

The product in the above reaction is:


Which of the following does not give aldol condensation reaction?


Which of the following compounds will undergo self-condensation in the presence of dilute NaOH solution?


Why is the α-hydrogens of aldehydes and ketones are acidic in nature?


Assertion (A): The final product in Aldol condensation is always α, β-unsaturated carbonyl compound.

Reason (R): α, β-unsaturated carbonyl compounds are stabilised due to conjugation.


Identify A and B:


Write a note on the aldol condensation reaction of acetaldehyde.


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