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प्रश्न
Does ionization isomer for the following compound exist? Justify your answer.
\[\ce{Hg[Co(SCN)4]}\]
उत्तर
No, ionization isomers are possible by exchange of ligand with counter ion only and not by exchange of central metal ion.
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संबंधित प्रश्न
Amongst the following, the most stable complex is:
How is Benzonitrile converted to Benzophenone?
Which of the following complexes are homoleptic?
(i) \[\ce{[Co(NH3)6]^{3+}}\]
(ii) \[\ce{[Co(NH3)4 Cl2]^{+}}\]
(iii) \[\ce{[Ni(CN)4]^{2-}}\]
(iv) \[\ce{[Ni(NH3)4Cl2]}\]
Which of the following complexes are heteroleptic?
(i) \[\ce{[Cr(NH3)6]^{3+}}\]
(ii) \[\ce{[Fe(NH3)4]Cl2]^+}\]
(iii) \[\ce{[Mn(CN)6]^{4-}}\]
(iv) \[\ce{[Co(NH3)4]Cl2]}\]
A complex of the type \[\ce{[M(AA)2X2]^{n+}}\] is known to be optically active. What does this indicate about the structure of the complex? Give one example of such complex.
Match the compounds given in Column I with the oxidation state of cobalt present in it (given in Column II) and assign the correct code:
Column I (Compound) | Column II (Oxidation state of Co) |
A. \[\ce{[Co(NCS)(NH3)5](SO3)}\] | 1. + 4 |
B. \[\ce{[Co(NH3)4 CL2]SO4}\] | 2. 0 |
C. \[\ce{Na4[Co(S2O3)3]}\] | 3. + 1 |
D. \[\ce{[Co2(CO)8]}\] | 4. + 2 |
5. + 3 |
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