Advertisements
Advertisements
Question
Answer the following in one or two sentences.
For the reaction, \[\ce{CH3Br_{(aq)} + OH^{-}_{(aq)} -> CH3OH^{\ominus}_{(aq)} + Br^{\ominus}_{(aq)}}\], rate law is rate = \[\ce{k[CH3Br][OH^\ominus]}\]
How does reaction rate changes if \[\ce{[OH^\ominus]}\] is decreased by a factor of 5?
Solution
For the reaction, \[\ce{CH3Br_{(aq)} + OH^{-}_{(aq)} -> CH3OH^{\ominus}_{(aq)} + Br^{\ominus}_{(aq)}}\]
Rate = \[\ce{k[CH3Br][OH^\ominus]}\]
If \[\ce{OH^\ominus}\] is decreased by a factor of 5, keeping \[\ce{CH3Br}\] constant rate will decrease by a factor of 5.
APPEARS IN
RELATED QUESTIONS
Choose the most correct option.
The order of the reaction for which the units of the rate constant are mol dm-3 s-1 is _______.
Choose the most correct option.
The rate constant for the reaction \[\ce{2N2O5_{(g)} -> 2N2O4_{(g)} + O2_{(g)}}\] is `4.98 xx 10^-4 "s"^-1`. The order of reaction is _____________.
What is the half life of a first order reaction if time required to decrease concentration of reactant from 0.8 M to 0.2 M is 12 h?
Choose the most correct option.
Rate law for the reaction, \[\ce{2NO + Cl2 -> 2NOCl}\] is rate = k[NO2]2[Cl2]. Thus of k would increase with _____________.
Choose the most correct option.
For an endothermic reaction, X ⇌ Y. If Ef is the activation energy of the forward reaction and Er that for the reverse reaction, which of the following is correct?
Answer the following in brief.
For the reaction 2A + B → products, find the rate law from the following data.
[A]/M | [B]/M | rate/M s-1 |
0.3 | 0.05 | 0.15 |
0.6 | 0.05 | 0.30 |
0.6 | 0.2 | 1.20 |
Order of reaction for which unit of rate constant is mol dm–3 s–1 is _______.
For the reaction \[\ce{2NO_{(g)} + 2H_{2(g)} -> N_{2(g)} + 2H2O_{(g)}}\],
The rate law is, rate = k[NO]2 [H2].
What is the overall order of reaction?
A reaction occurs in the following steps:
Step 1: \[\ce{NO_{2(g)} + F_2 -> NO2F_{(g)} + F_{(g)}}\] (slow)
Step 2: \[\ce{F_{(g)} + NO_{2(g)} -> NO_2F}\] (Fast)
- Write the equation of overall reaction.
- Write the rate law.
- Identify reaction intermediate.
For the reaction 2A + B → C, rate of disappearance of A 0.076 mol s –1.
- What is the rate of formation of C?
- What is the rate of consumption of B?
- What is the rate of the overall reaction?
A gaseous hypothetical chemical equation \[\ce{2A ⇌ 4B + C}\] is carried out in a closed vessel. The concentration of B is found to increase by 5 × 10−3 mol dm−3 in 10 second. The rate of ____________.
For a chemical reaction rate law is, rate = k[A]2[B]. If [A] is doubled at constant [B], the rate of reaction ______.
The order of the reaction occurring by following mechanism should be:
(i) \[\ce{A2 + B2 -> AB2 + A (slow)}\]
(ii) \[\ce{A + B2 -> AB2 (fast)}\]
The rate law for the reaction \[\ce{A + B + C -> Product}\] is expressed as Rate = k[A]2 [B]1 [C]0. What is the overall order of the reaction?
The rate law for the reaction \[\ce{2NO_{(g)} + O2_{(g)} -> 2NO2_{(g)}}\] is rate = k[NO]2 [O2] , then which among the following statement is correct?
In the reaction \[\ce{A + B2 -> AB + B}\], the rate of reaction is directly proportional to the concentration of A and independent on the concentration of B2. What is the rate law expression?
In the reaction, \[\ce{N2 + 3H2 -> 2NH3}\], the rate of disappearance of H2 is 0.02 Mis. The rate of appearance of NH3 is ______.
What is the molecularity and order of the following reaction if rate law is, rate = k[O3][O] respectively.
\[\ce{O_{3(g)} + O_{(g)} -> 2O_{2(g)}}\]
For the reaction \[\ce{2A + B -> 3C + D}\], which among the following is NOT the correct rate law expression?
The correct order of raaii of F, F-, O and O2- is ______.
Write the rate law for the following reaction:
A reaction that is second order in NO and first order in Br2.
For a chemical reaction A → 7 products, the rate of reaction doubles when the concentration of A is increased by a factor 4. The order of the reaction is ______.
For the reaction A + B → P.
If [B] is doubled at constant [A], the rate of reaction doubled. If [A] is triple and [B] is doubled, the rate of reaction increases by a factor of 6. Calculate the rate law equation.