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Graphically show the total work done in an expansion when the state of an ideal gas is changed reversibly and isothermally from (pXi,VXi) to (pXf,VXf ). With the help of a pV plot compare the - Chemistry

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Question

Graphically show the total work done in an expansion when the state of an ideal gas is changed reversibly and isothermally from \[\ce{(p_i, V_i)}\] to \[\ce{(p_f , V_f )}\]. With the help of a pV plot compare the work done in the above case with that carried out against a constant external pressure \[\ce{p_f}\].

Long Answer

Solution

(i) Reversible Work is represented by the combined areas

and

(ii) Work against constant pressure, pf is represented by the area

Work (i) > Work (ii)

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Thermodynamics Applications - Work
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Chapter 6: Thermodynamics - Multiple Choice Questions (Type - I) [Page 77]

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NCERT Exemplar Chemistry [English] Class 11
Chapter 6 Thermodynamics
Multiple Choice Questions (Type - I) | Q 62 | Page 77

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