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H3po3 Can Be Represented by Structures 1 and 2 Shown Below. Can These Two Structures Be Taken as the Canonical Forms of the Resonance Hybrid Representing H3po3? If Not, Give Reasons for the Same. - Chemistry

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Question

H3PO3 can be represented by structures 1 and 2 shown below. Can these two structures be taken as the canonical forms of the resonance hybrid representing H3PO3? If not, give reasons for the same.

(1) (2)
Short Note

Solution 1

The given structures cannot be taken as the canonical forms of the resonance hybrid of H3PO3 because the positions of the atoms have changed.

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Solution 2

No, these cannot be taken as canonical forms because the positions of atoms have been changed.

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Chapter 4: Chemical Bonding and Molecular Structure - EXERCISES [Page 134]

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NCERT Chemistry - Part 1 and 2 [English] Class 11
Chapter 4 Chemical Bonding and Molecular Structure
EXERCISES | Q 4.12 | Page 134

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The acceptable resonating structures of the following molecule are:

\[\begin{array}{cc}
\ce{CH3 - CH = C - \overset{\bullet\bullet}{\underset{\bullet\bullet}{O}} - CH2 - CH3}\\
|\phantom{......}\\
\ce{:N}\phantom{.......}\\
\phantom{}/\phantom{...}\backslash\phantom{......}\\
\phantom{}\ce{H3C}\phantom{.....}\ce{CH3}\phantom{......}
\end{array}\]

(x) \[\begin{array}{cc}
\ce{CH3 - \overset{\overset{Θ}{\bullet\bullet}}{C}H - C -  \overset{\bullet\bullet}{\underset{\bullet\bullet}{O}} - CH2 - CH3}\\
||\phantom{......}\\
\ce{N^⊕}\phantom{.....}\\
\phantom{}/\phantom{...}\backslash\phantom{......}\\
\phantom{}\ce{H3C}\phantom{.....}\ce{CH3}\phantom{......}
\end{array}\]
(y) \[\begin{array}{cc}
\ce{CH3 - \overset{\overset{Θ}{\bullet\bullet}}{C}H - C =  \overset{⊕}{\underset{\bullet\bullet}{O}} - CH2 - CH3}\\
|\phantom{......}\\
\ce{:N}\phantom{.......}\\
\phantom{}/\phantom{...}\backslash\phantom{......}\\
\phantom{}\ce{H3C}\phantom{.....}\ce{CH3}\phantom{......}
\end{array}\]
(z) \[\begin{array}{cc}
\ce{CH3 - \overset{⊕}{C}H - C -  \overset{\bullet\bullet}{\underset{\bullet\bullet}{O}} - CH2 - CH3}\\
||\phantom{......}\\
\ce{N^Θ}\phantom{.....}\\
\phantom{}/\phantom{...}\backslash\phantom{......}\\
\phantom{}\ce{H3C}\phantom{.....}\ce{CH3}\phantom{......}
\end{array}\]
(w) \[\begin{array}{cc}
\ce{CH3 - \overset{⊕}{C}H - C =  \overset{Θ}{O} - CH2 - CH3}\\
|\phantom{......}\\
\ce{:N}\phantom{.......}\\
\phantom{}/\phantom{...}\backslash\phantom{......}\\
\phantom{}\ce{H3C}\phantom{.....}\ce{CH3}\phantom{......}
\end{array}\]

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