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Question
Identify A, B and C.
\[\ce{CH3 - NO2 ->[LiAlH4] A ->[2CH3CH2Br] B ->[H2SO4] C}\]
Solution
\[\begin{array}{cc}
\ce{\underset{(Nitro methane)}{CH3NO2} ->[LiAlH4][6(H)/-2H2O] \underset{\underset{(A)}{(Methylamine)}}{CH3NH2} ->[2CH3CH2Br][-2HBr] \underset{\underset{(B)}{(N, N-diethyl methylamine)}}{(CH3CH2)2NCH3} ->[H2SO4] [(CH3CH2)2NH^+] HSO^-_4}\\
\phantom{..........................................................................}|\\
\phantom{.............................................................................}\ce{\underset{\underset{(C)}{(Quarternary salt)}}{CH3}}
\end{array}\]
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RELATED QUESTIONS
Classify the following amine as primary, secondary or tertiary:
(C2H5)2NH
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\[\begin{array}{cc}
\ce{O}\phantom{.........}\\
||\phantom{.........}\\
\ce{H - \underset{(A)}{C} - NH - CH3}
\end{array}\]
and
\[\begin{array}{cc}
\ce{O}\\
||\\
\ce{CH3 - \underset{(B)}{C} - NH2}
\end{array}\]
are which type of isomers?
Write short note on the following.
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Account for the following:
Aniline does not undergo Friedel-Crafts reaction.
