Advertisements
Advertisements
Question
What is Lanthanoid contraction?
Solution
The lanthanide series of elements is defined as a gradual reduction in atom size, known as lanthanoid contraction. This reduction occurs due to insufficient shielding of additional electrons in the 4f subshell by filled 5s and 5p orbitals. As a result, the effective nuclear charge increases, resulting in smaller atomic sizes.
APPEARS IN
RELATED QUESTIONS
Define lanthanoid contraction.
What are lanthanoids?
Which among the following pairs of elements is 'not' an example of chemical twins?
Account for the following :
Zr and Hf have almost similar atomic radii.
Name a member of the lanthanoid series which is well known to exhibit +4 oxidation state.
What are the different oxidation states exhibited by the lanthanoids?
Compare the chemistry of actinoids with that of lanthanoids with special reference to electronic configuration.
Compare the chemistry of actinoids with that of the lanthanoids with special reference to atomic and ionic sizes.
Compare the chemistry of actinoids with that of the lanthanoids with special reference to chemical reactivity.
Name the members of the lanthanoid series which exhibit +4 oxidation state and those which exhibit +2 oxidation state. Try to correlate this type of behavior with the electronic configurations of these elements.
Write the electronic configurations of the elements with the atomic numbers 61, 91, 101 and 109.
Write the different oxidation states of iron
Explain effects of lanthanoid contraction
Explain the cause of lanthanoid contraction?
Account for the following:
Zn, Cd and Hg are soft metals.
What is Lanthanoid contraction?
Explain the cause of Lanthanoids contraction.
Name an element of lanthanoid series which is well knwon to shown +4 oxidation state. Is it a strong oxidising agent or reducing agent?
The f-block elements are known as ____________.
Gadolinium belongs to 4f series. It’s atomic number is 64. Which of the following is the correct electronic configuration of gadolinium?
General electronic configuration of actinoids is `(n-2)f^(1-14)(n - 1)d^(0-2)ns^2`.Which of the following actinoids have one electron in 6d orbital?
(i) U (Atomic no. 92)
(ii) Np (Atomic no.93)
(iii) Pu (Atomic no. 94)
(iv) Am (Atomic no. 95)
Which of the following lanthanoids show +2 oxidation state besides the characteristic oxidation state +3 of lanthanoids?
(i) \[\ce{Ce}\]
(ii) \[\ce{Eu}\]
(iii) \[\ce{Yb}\]
(iv) \[\ce{Ho}\]
Although +3 is the characteristic oxidation state for lanthanoids but cerium also shows +4 oxidation state because:
(i) it has variable ionisation enthalpy
(ii) it has a tendency to attain noble gas configuration
(iii) it has a tendency to attain f 0 configuration
(iv) it resembles Pb4+
Although +3 oxidation states is the characteristic oxidation state of lanthanoids but cerium shows +4 oxidation state also. Why?
Match the statements given in Column I with the oxidation states given in Column II.
Column I | Column II | |
(i) | Oxidation state of Mn in MnO2 is | (a) + 2 |
(ii) | Most stable oxidation state of Mn is | (b) + 3 |
(iii) | Most stable oxidation state of | (c) + 4 |
Mn in oxides is | (d) + 5 | |
(iv) | Characteristic oxidation state of lanthanoids is | (e) + 7 |
On the basis of Lanthanoid contraction, explain the following:
Stability of the complexes of lanthanoids.
On the basis of Lanthanoid contraction, explain the following:
Trends in acidic character of lanthanoid oxides.
How would you account for the following:
There is a greater range of oxidation states among the actinoids than among the lanthanides.
The titanium (Z = 22) compound that does not exist is:-
In lanthanoid the last electron enters (n - 2)f subshell where n is equal to ______.
Zr (Z = 40) and Hf (Z = 72) have similar atomic and ionic radii because of _______.
Write any two consequences of Lanthanoid Contraction.
The lathanide ion that would show colour is ______.
Why is Mn2+ ion more stable than Fe2+ ion?
(Atomic numbers of Mn = 25 and Fe = 26)
Mention alloy uses.