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Science (English Medium) Class 12 - CBSE Question Bank Solutions for Chemistry

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Chemistry
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Among the hydrides of Group-15 elements, which have the maximum basic character?

[0.07] P - Block Elements
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Among the hydrides of Group-15 elements, which have the highest bond angle?

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Among the hydrides of Group-15 elements, which have the maximum reducing character?

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Give reasons H3PO3 undergoes disproportionation reaction but H3PO4 does not.

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Give reasons When Cl2 reacts with the excess of F2, ClF3 is formed and not FCl3.

[0.07] P - Block Elements
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Although chlorine is an electron withdrawing group, yet it is ortho-, para- directing in electrophilic aromatic substitution reactions. Why?

[0.02] Electrochemistry
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What is 'copper matte' ?

[0.06] General Principles and Processes of Isolation of Elements
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Account for the following :

Reducing character decreases from SO2 to TeO2

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Account for the following :

BiH3 is the strongest reducing agent amongst all the hydrides of group 15.

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Which of the following is a more stable complex and why ?

\[\left[ Co \left( {NH}_3 \right)_6 \right]^{3 +} and \left[ Co \left( en \right)_3 \right]^{3 +}\]
[0.05] Coordination Compounds
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Write the structural difference between white phosphorus and red phosphorus.

 
[0.07] P - Block Elements
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Account for the following 

The enthalpy of atomisation is lowest for Zn in 3d series of the transition elements.

[0.07] P - Block Elements
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Write the principle behind the following methods of refining:

Hydraulic washing

[0.03] Chemical Kinetics
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Define the following terms:

Pseudo first-order reaction

[0.03] Chemical Kinetics
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Define the following terms:

Half-life period of reaction (t1/2).

[0.03] Chemical Kinetics
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Account for the following

Bi(V) is a stronger oxidizing agent than Sb(V).

[0.07] P - Block Elements
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Account for the following :

N − N single bond is weaker than P − P single bond.

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Account for the following :

Noble gases have very low boiling points.

[0.07] P - Block Elements
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Account for the following :

Sulphur in vapour form exhibits paramagnetic behaviour.

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Why is CH2 = CH - CH2 - Cl more easily hydrolysed than CH3 - CH2 - CH2 - Cl ?

[0.06] Haloalkanes and Haloarenes
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