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State Heisenberg uncertainty principle. - Chemistry

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प्रश्न

State Heisenberg uncertainty principle.

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उत्तर

Heisenberg's uncertainty principle states that “It is impossible to determine simultaneously, the exact position and exact momentum (or velocity) of an electron”.

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अध्याय 4: Structure of Atom - Exercises [पृष्ठ ५४]

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बालभारती Chemistry [English] 11 Standard
अध्याय 4 Structure of Atom
Exercises | Q 5. (C) | पृष्ठ ५४

संबंधित प्रश्न

Using s, p, d notations, describe the orbital with the following quantum numbers n = 1, l = 0.


Using s, p, d notations, describe the orbital with the following quantum numbers n = 4; l = 2.


Choose the correct option.

“No two electrons in the same atoms can have identical set of four quantum numbers”. This statement is known as -


Choose the correct option.

Principal Quantum number describes -


Define the term Electronic configuration


State and explain Pauli’s exclusion principle.


Explain the anomalous behaviour of chromium.


Write orbital notations for the electron in orbitals with the following quantum numbers.

n = 3, l = 2


Write condensed orbital notation of electronic configuration of the following element:

Oxygen (Z = 8)


Write condensed orbital notation of electronic configuration of the following element:

Silicon (Z = 14)


Draw shapes of 2p orbitals.


How many electrons in 19K have n = 3, l = 1?


Which of the following has a greater number of electrons than neutrons?

(Mass number of Mg, C, O and Na is 24, 12, 16 and 23 respectively).


Which one of the following is NOT possible?


The probability density plots of 1s and 2s orbitals are given in Figure:


The density of dots in a region represents the probability density of finding electrons in the region.

On the basis of above diagram which of the following statements is incorrect?


The number of radial nodes for 3p orbital is ______.


The pair of ions having same electronic configuration is ______.


In which of the following pairs, the ions are iso-electronic?

(i) \[\ce{Na^{+}, Mg^{2+}}\]

(ii) \[\ce{Al3^{+}, O-}\]

(iii) \[\ce{Na+ , O2-}\]

(iv) \[\ce{N3-, Cl-}\]


Which of the following statements concerning the quantum numbers are correct?

(i) Angular quantum number determines the three dimensional shape of the orbital.

(ii) The principal quantum number determines the orientation and energy of the orbital.

(iii) Magnetic quantum number determines the size of the orbital.

(iv) Spin quantum number of an electron determines the orientation of the spin of electron relative to the chosen axis.


The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.

Based upon the above information, arrange the following orbitals in the increasing order of energy.

4s, 3s, 3p, 4d


Match the following species with their corresponding ground state electronic configuration.

Atom / Ion Electronic configuration
(i) \[\ce{Cu}\] (a) 1s2 2s2 2p6 3s2 3p6 3d10
(ii) \[\ce{Cu^{2+}}\] (b) 1s2 2s2 2p6 3s2 3p6 3d10 4s2
(iii) \[\ce{Zn^{2+}}\] (c) 1s2 2s2 2p6 3s2 3p6 3d10 4s1
(iv) \[\ce{Cr^{3+}}\] (d) 1s2 2s2 2p6 3s2 3p6 3d9
  (e) 1s2 2s2 2p6 3s2 3p6 3d3

Match the quantum numbers with the information provided by these.

Quantum number Information provided
(i) Principal quantum number (a) orientation of the orbital
(ii) Azimuthal quantum number (b) energy and size of orbital
(iii) Magnetic quantum number (c) spin of electron
(iv) Spin quantum number (d) shape of the orbital

Match species given in Column I with the electronic configuration given in Column II.

Column I Column II
(i) \[\ce{Cr}\] (a) [Ar]3d84s0
(ii) \[\ce{Fe^{2+}}\] (b) [Ar]3d104s1
(iii) \[\ce{Ni^{2+}}\] (c) [Ar]3d64s0
(iv) \[\ce{Cu}\] (d) [Ar] 3d54s1
  (e) [Ar]3d64s2

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