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Draw the geometrical isomers of the following complexes [Co(NH3)4Cl2]+ - Chemistry

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Draw the geometrical isomers of the following complexes [Co(NH3)4Cl2]+

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पाठ 9: Coordination Compounds - Short Answer Questions (Type-II)

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एससीईआरटी महाराष्ट्र Chemistry [English] 12 Standard HSC
पाठ 9 Coordination Compounds
Short Answer Questions (Type-II) | Q 4.2

संबंधित प्रश्‍न

List various types of isomerism possible for coordination compounds, giving an example of each.


 Out of    and  , which one is optically active and why ?


Choose the most correct option.

Which of the following complexes exist as cis and trans isomers?

1. [Cr(NH3)2Cl4]-

2. [Co(NH3)5Br]2⊕

3. [PtCl2Br2]2- (square planar)

4. [FeCl2(NCS)2]2- (tetrahedral)


Answer the following in one or two sentences.

Consider the complexes \[\ce{[Cu(NH3)4][PtCl4] and [Pt(NH3)4] [CuCl4]}\]. What type of isomerism these two complexes exhibit?


Answer in brief.

What are ionization isomers ? Give an example.


Draw isomers of the following.

\[\ce{Pt(NH3)2ClNO2}\]


Write the type of isomerism exhibited by [Co(NH3)5(NO2)]2+ and [Co(NH3)5ONO]2+ pair of complex ion.


Draw optical isomers of [Co(en)3]3+.


Which one of the following will give a pair of enantiomorphs?


Fac-mer isomerism is shown by


The complex ions [Co(H2O)5(ONO)]2+ and [Co(H2O)5NO2]2+ are ____________.


The formula of two complexes X and Y of chromium are given below:

\[\ce{\underset{(X)}{[Cr(H2O)6]Cl3}}\] and \[\ce{\underset{(Y)}{[Cr(H2O)5Cl]Cl2.H2O}}\]

X and Y are examples of ____________ isomers.


Which of the following has zero dipole moment?


What is the number of moles of silver chloride precipitated when excess of aqueous silver nitrate is treated with [Co(NH3)4Cl2]Cl?


Complex [COCl2(en)2]+ can 


Which of the following has an optical isomer?


Which of the following shows maximum number of isomers?


\[\ce{CH3CH2COO- Na+ ->[NaOH, + ?][Heat] CH3CH3 + Na2CO3}\]

Consider the above reaction and identify the missing reagent/chemical.


Which among the following solid is a non-polar solid?


Give cis isomer of [Co(NH3)4Cl2].


Indicate the type of isomerism exhibited by the following complex and draw the structures for this isomer:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


Explain the geometrical isomerism of the octahedral complex of the type [M(AA)2B2]with a suitable example.


Which one of the following complex ions has geometrical isomers?


Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.

  1. Write the structures of the compounds A, B and C.
  2. Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.

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