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प्रश्न
Draw the geometrical isomers of the following complexes [Co(NH3)4Cl2]+
उत्तर
संबंधित प्रश्न
List various types of isomerism possible for coordination compounds, giving an example of each.
Answer in brief.
What are ionization isomers ? Give an example.
Write the type of isomerism exhibited by [Co(NH3)5(NO2)]2+ and [Co(NH3)5ONO]2+ pair of complex ion.
Draw structure of cis isomer of [Co(NH3)4Cl2]+
How many geometrical isomers are possible for \[\ce{[Pt(Py)(NH3)(Br)(Cl)]}\]?
Which kind of isomerism is possible for a complex [Co(NH3)4Br2]Cl?
What is linkage isomerism? Explain with an example.
The compound(s) that exhibit(s) geometrical isomerism is (are):
(I) [Pt(en)Cl2]
(II) [Pt(en)2]Cl2
(III) [Pt(en)2Cl2]
(IV) [Pt(NH3)2Cl2]
Which of the following is NOT an isomer of n-hexane?
Which of the following does NOT show optical isomerism?
The complex ions [Co(H2O)5(ONO)]2+ and [Co(H2O)5NO2]2+ are ____________.
How many donor groups are present in diethylene triamine?
What type of isomerism is present between (I) [Cr(H2O)6]Cl3 and (II) [Cr(H2O)5Cl]Cl2.H2O?
Assertion: Complexes of MX6 and MX5L type (X and L are unidentate) do not show geometrical isomerism.
Reason: Geometrical isomerism is not shown by complexes of coordination number 6.
The relationship between compound (i) and (ii) is
 |
 |
| (i) | (ii) |
Complex [COCl2(en)2]+ can
Which of the following has an optical isomer?
\[\ce{CH3CH2COO- Na+ ->[NaOH, + ?][Heat] CH3CH3 + Na2CO3}\]
Consider the above reaction and identify the missing reagent/chemical.
Which compound would exhibit optical isomers?
White precipitate of AgCl dissolves in aqueous ammonia solution due to formation of ______.
Give trans isomer of [Co(NH3)4Cl2]⊕.
Explain the ionisation isomers.
Match the pairs in column I (pairs of isomers) and column II (types of isomers)
| Column I (Pairs of isomers) |
Column II (Types of isomers) |
| (A) [Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O | (i) Ionization isomers |
| (B) [Co(en)2(NO2)2]+ and [Co(en)2(ONO2)]+ | (ii) Hydrate isomers |
| (C) [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6] | (iii) Linkage isomers |
| (D) [Pt(NH3)4Cl2] Br2 and [Pt(NH3)4Br2]Cl2 | (iv) Coordination isomers |
The co-ordination number of Co3+ ion in the complex [Co(NH3)4Cl2]⊕ is ______.
Name the type of isomerism exhibited by the following pair of compound:
\[\ce{[Cr(H2O)5Cl]Cl2H2O and [Cr(H2O)4Cl2]Cl {.} 2H2O}\]
Name the type of isomerism exhibited by the following pair of compound:
\[\ce{[Pt(NH3)4Cl2]Br2 and [Pt(NH3)4 Br2]Cl2}\]
Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.
- Write the structures of the compounds A, B and C.
- Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.
