Advertisements
Advertisements
प्रश्न
Explain the anomalous behaviour of chromium.
उत्तर
- Chromium (Cr) has atomic number 24.
- Its expected electronic configuration is 1s2 2s2 2p6 3s2 3p6 4s2 3d4.
- The 3d orbital is less stable as it is not half-filled.
- Due to inter electronic repulsion forces, one 4s electron enters into 3d orbital. This makes 4s and 3d orbitals half-filled which gives extra stability and the electronic configuration of Cr becomes 1s2 2s2 2p6 3s2 3p6 4s1 3d5.
APPEARS IN
संबंधित प्रश्न
Using s, p, d notations, describe the orbital with the following quantum numbers n = 4; l =3.
State Heisenberg uncertainty principle.
Explain the anomalous behaviour of copper.
Write orbital notations for the electron in orbitals with the following quantum numbers.
n = 2, l = 1
Write orbital notations for the electron in orbitals with the following quantum numbers.
n = 4, l = 2
Write orbital notations for the electron in orbitals with the following quantum numbers.
n = 3, l = 2
Write electronic configurations of \[\ce{Fe, Fe2+, Fe3+}\].
Write condensed orbital notation of electronic configuration of the following element:
Oxygen (Z = 8)
Write condensed orbital notation of electronic configuration of the following element:
Calcium (Z = 20)
Explain in brief, the significance of the azimuthal quantum number.
Indicate the number of unpaired electron in:
Cr (Z = 24)
Which mineral among the following contains vanadium in it?
Which one of the following orders is CORRECT in case of energy of the given subshells?
P: n = 4; l = 3
Q: n = 5; I = 1
R: n = 5; l = 0
S: n = 4; l = 2
How many electrons in 19K have n = 3, l = 1?
How many electrons can fit in the orbital for which n = 4 and l = 2?
Which of the following has a greater number of electrons than neutrons?
(Mass number of Mg, C, O and Na is 24, 12, 16 and 23 respectively).
Which of the following options does not represent ground state electronic configuration of an atom?
Which of the following properties of atom could be explained correctly by Thomson Model of atom?
Which of the following orbitals are degenerate?
3dxy, 4dxy 3dz2, 3dyz, 4dyz, 4dz2
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, arrange the following orbitals in the increasing order of energy.
1s, 2s, 3s, 2p
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, arrange the following orbitals in the increasing order of energy.
4s, 3s, 3p, 4d
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, arrange the following orbitals in the increasing order of energy.
5f, 6d, 7s, 7p
Match the following species with their corresponding ground state electronic configuration.
| Atom / Ion | Electronic configuration |
| (i) \[\ce{Cu}\] | (a) 1s2 2s2 2p6 3s2 3p6 3d10 |
| (ii) \[\ce{Cu^{2+}}\] | (b) 1s2 2s2 2p6 3s2 3p6 3d10 4s2 |
| (iii) \[\ce{Zn^{2+}}\] | (c) 1s2 2s2 2p6 3s2 3p6 3d10 4s1 |
| (iv) \[\ce{Cr^{3+}}\] | (d) 1s2 2s2 2p6 3s2 3p6 3d9 |
| (e) 1s2 2s2 2p6 3s2 3p6 3d3 |
Match the quantum numbers with the information provided by these.
| Quantum number | Information provided |
| (i) Principal quantum number | (a) orientation of the orbital |
| (ii) Azimuthal quantum number | (b) energy and size of orbital |
| (iii) Magnetic quantum number | (c) spin of electron |
| (iv) Spin quantum number | (d) shape of the orbital |
Choose the INCORRECT statement
In assigning R - S configuration, which among the following groups has highest priority?
