Advertisements
Advertisements
Question
Predict all the alkenes that would be formed by dehydrohalogenation of the following halide with sodium ethoxide in ethanol and identify the major alkene:
2, 2, 3-Trimethyl-3-bromopentane
Solution
There are two different types of β-hydrogen atoms present in the halide. Hence, in the dehydrohalogenation reaction, it will form two alkenes: 3, 4, 4-trimethylpent-2-ene and 2-ethyl-3, 3-dimethylbut-1-ene. The first alkene is more stable because it is more substituted (according to Saytzeff rule). Hence, it is the major product.
APPEARS IN
RELATED QUESTIONS
Identify the product ‘D’ in the following sequence of reactions:
\[\ce{H3C - CH2 - CH2 - Cl \underset{KOH}{\overset{Alc}{->}} 'B' \overset{HBr}{->} 'C' \underset{Elther}{\overset{Na}{->}}'D'}\]
Identify ‘A’ and ‘B’ in the following reaction :
\[\ce{CH3 - CH = CH2 ->[HBr]'A' ->[alc.KOH]'B'}\]
State and explain Markownikoff's rule with suitable example
Write the main products when n-butyl chloride is treated with alcoholic KOH.
Predict all the alkenes that would be formed by dehydrohalogenation of the following halide with sodium ethoxide in ethanol and identify the major alkene:
1-Bromo-1-methylcyclohexane
Write the structure of the major organic product in the following reaction:
\[\ce{(CH3)3CBr + KOH ->[ethanol][heat]}\]
How the following conversion can be carried out?
1-Bromopropane to 2-bromopropane
How the following conversion can be carried out?
2-Chloropropane to 1-propanol
How the following conversion can be carried out?
2-Bromopropane to 1-bromopropane
Draw a neat, labelled energy profile diagram for SN1 reaction mechanism.
What are racemates?
'A' is:
Deamination of meso- di bromobutane gives mainly:-
Identify the major product formed when 2-cyclohexylchloroethane undergoes a dehydrohalogenation reaction. Name the reagent which is used to carry out the reaction.
Elimination of bromine from 2-bromobutane results in the formation of ______.
Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
\[\ce{CH3 C(CI) (C2H5)CH2CH3 }\]