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Karnataka Board PUCPUC Science 2nd PUC Class 12

Predict all the alkenes that would be formed by dehydrohalogenation of the following halide with sodium ethoxide in ethanol and identify the major alkene: 2, 2, 3-Trimethyl-3-bromopentane - Chemistry

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Question

Predict all the alkenes that would be formed by dehydrohalogenation of the following halide with sodium ethoxide in ethanol and identify the major alkene:

2, 2, 3-Trimethyl-3-bromopentane

Chemical Equations/Structures
Short Answer

Solution

There are two different types of β-hydrogen atoms present in the halide. Hence, in the dehydrohalogenation reaction, it will form two alkenes: 3, 4, 4-trimethylpent-2-ene and 2-ethyl-3, 3-dimethylbut-1-ene. The first alkene is more stable because it is more substituted (according to Saytzeff rule). Hence, it is the major product.

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Chapter 10: Haloalkanes and Haloarenes - Exercises [Page 311]

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NCERT Chemistry [English] Class 12
Chapter 10 Haloalkanes and Haloarenes
Exercises | Q 10.3 | Page 311

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