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Expansion of Substances (Thermal Expansion) - Expansion of Solids

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Topics

  • Introduction
  • Linear Expansion
  • Areal Expansion
  • Volumetric Expansion

Introduction:

When solids are heated, their particles gain energy, vibrate more vigorously, and move slightly apart. This results in thermal expansion, which occurs in three forms:

  1. Linear expansion
  2. Areal expansion
  3. Volumetric expansion

Linear Expansion:

Linear expansion refers to the increase in the length of a solid object (e.g., rod or wire) when its temperature increases. If the initial length of the rod is l1, and its length increases to l2 after a temperature increase from T1 to T2, the change in length (l2−l1) is proportional to the original length (l1) and the temperature change (ΔT=T2−T1):

l2l1=λl1ΔT

l2=l1(1+λΔT)

Here:

  • λ: coefficient of linear expansion (a constant specific to the material).
  • Unit of λ: 1/°C.

Coefficient of Linear Expansion (λ),

Represents the change in length of a unit length of the material for every 1°C increase in temperature.

`lamda = (l_2-l_1) / (l_1DeltaT)`

Different materials have different λ values. Materials with higher λ expand more for the same temperature increase.

The expansion coefficients of some substances are given in the following table:

Solid Coefficient of Linear Expansion × 10⁶ (1/°C) Liquid Coefficient of Volume Expansion × 10³ (1/°C) Gas Expansion Coefficient × 10³ (1/°C)
Copper 17 Alcohol 1.0 Hydrogen 3.66
Aluminium 23.1 Water 0.2 Helium 3.66
Iron 11.5 Mercury 0.2 Nitrogen 3.67
Silver 18 Chloroform 1.3 Sulphur dioxide 3.90

 

Areal Expansion:

Areal expansion refers to the increase in the area of a flat sheet of solid material when its temperature increases.

If the initial area is A1 and it increases to A2 after heating: A2 = A1(1+σΔT)

Here:

  • σ: coefficient of areal expansion (specific to the material).
  • ΔT: change in temperature.

Similar to linear expansion, but applies to two-dimensional surfaces. Areal expansion is approximately twice the linear expansion coefficient for most solids. σ2λ

Volumetric Expansion:

Volumetric expansion refers to the increase in the volume of a solid object when its temperature rises.

If the initial volume is V and it increases to V2 after heating: V2 = V1(1+βΔT)

Here:

  • β: Coefficient of volumetric expansion (specific to the material).
  • ΔT: Change in temperature.

Volumetric expansion applies to three-dimensional objects. β is approximately three times the linear expansion coefficient for most solids. β≈3λ

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