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Write the order of reactivity of alkyl halides with ammonia. - Chemistry

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प्रश्न

Write the order of reactivity of alkyl halides with ammonia.

एक पंक्ति में उत्तर

उत्तर

The order of reactivity of alkyl halides with ammonia is, R–I > R–Br > R–Cl.

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अध्याय 13: Amines - Very Short Answer Questions

संबंधित प्रश्न

How are propan-1-amine and propan-2-amine prepared from oxime?


Illustrate the following reaction giving suitable example in each case:Gabriel phthalimide synthesis


How do you convert the following: C6H5CONH2 to C6H5NH2


Accomplish the following conversion:

Nitrobenzene to benzoic acid


Accomplish the following conversions: Benzamide to toluene


Give the structures of A, B and C in the following reaction:


Give the structures of A, B and C in the following reaction:


Write the reactions of aromatic with nitrous acid.


Give plausible explanation for each of the following :

Why are amines less acidic than alcohols of comparable molecular masses?


Explain the mechanism of action of hydroiodic acid on 3-methylbutan-2-ol.


Mention 'two' uses of propan-2-one.


Identify 'A' and 'B' in the following reaction and rewrite the complete reaction :


Give the structures of A, B and C in the following reactions :


Choose the most correct option.

Which of the following compounds will dissolve in aqueous NaOH after undergoing reaction with Hinsberg reagent?


Answer in one sentence.

Predict the product of the following reaction.

\[\ce{Nitrobenzene ->[Sn/conc.HCl]?}\]


Name the process of breaking C-X bond by ammonia in preparation of amines.


Why cannot aniline be prepared by Gabriel phthalimide synthesis?


Acetamide on reduction using Na/C2H5OH gives ____________.


Identify the product obtained when benzyl chloride undergoes ammonolysis in presence of excess ammonia followed by the reaction with two moles of methyl iodide.


____________ can be prepared exclusively by Gabriel phthalimide synthesis.


What product is formed when \[\ce{R - C ≡ N}\] is hydrolysed?


Identify the INCORRECT statement regarding Hofmann bromamide reaction.


Which of the following reagents is used in Mendius reduction reaction of alkyl cyanide?


Which of the following amines cannot be prepared by Gabriel phthalimide synthesis?


Identify product B in the following reaction.

\[\ce{Aniline ->[NaNO2][HCl] A ->[KI] B}\]


Which of the following reagents is used in Hofmann's elimination reaction of amines?


Which of the following does NOT give carbylamine test?


Nitro compounds are reduced by iron scrap and hydrochloric acid to yield one of the following compounds:


Amongst the following, the strongest base in aqueous medium is ______.


Benzylamine may be alkylated as shown in the following equation:

\[\ce{C6H5CH2NH2 + R - X -> C6H5CH2NHR}\]

Which of the following alkylhalides is best suited for this reaction through SN1 mechanism?


Which of the following reagents would not be a good choice for reducing an aryl nitro compound to an amine?


In order to prepare a 1° amine from an alkyl halide with simultaneous addition of one \[\ce{CH2}\] group in the carbon chain, the reagent used as source of nitrogen is ______.


The best reagent for converting, 2-phenylpropanamide into 1- phenylethanamine is ______.


Reduction of aromatic nitro compounds using \[\ce{Fe}\] and \[\ce{HCl}\] gives ______.


Among the following amines, the strongest Brönsted base is:


The reagents that can be used to convert benzenediazonium chloride to benzene are:

(i) \[\ce{SnCl2/HCl}\]

(ii) \[\ce{CH3CH2OH}\]

(iii) \[\ce{H3PO2}\]

(iv) \[\ce{LiAlH4}\]


Under which of the following reaction conditions, aniline gives p-nitro derivative as the major product?

(i) Acetyl chloride/pyridine followed by reaction with conc.\[\ce{H2SO4 }\] + conc. \[\ce{HNO3}\].

(ii) Acetic anyhdride/pyridine followed by conc.\[\ce{H2SO4}\] + conc.\[\ce{HNO3}\].

(iii) Dil. HCl followed by reaction with conc.\[\ce{H2SO4}\] + conc.\[\ce{HNO3}\].

(iv) Reaction with conc.\[\ce{HNO3}\] + conc.\[\ce{H2 SO4}\].


What is the best reagent to convert nitrile to primary amine?


Suggest a route by which the following conversion can be accomplished.


Write following conversions:

nitrobenzene `->` acetanilide


How will you carry out the following conversions?


How will you carry out the following conversions?


Assertion: Hoffmann’s bromamide reaction is given by primary amines.

Reason: Primary amines are more basic than secondary amines.


Assertion: Aromatic 1° amines can be prepared by Gabriel Phthalimide Synthesis.

Reason: Aryl halides undergo nucleophilic substitution with anion formed by phthalimide.


The compound X is which of the following?

\[\ce{CH3CN ->[Na + C2H5OH] x}\]


C6H5CONHCH3 can be converted into C6H5CH2NHCH3 by:-


Methyl amine on reaction with chloroform in the presence of NaOH gives ______.


What is the IUPAC name of \[\ce{(CH3)2 - N - CH3}\]?


Write short note on the following:

Ammonolysis


Write the name of reduction product formed when ethyl cyanide is treated with sodium and alcohol.


Write a short note on Ammonolysis.


Write short note on the following:

Ammonolysis


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