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Justify that the following reaction is redox reaction; identify the species oxidized/reduced, which acts as an oxidant and which acts as a reductant. 2CuX2OX(S)+CuX2SX(S)⟶6CuX(S)+SOX2X(g) - Chemistry

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प्रश्न

Justify that the following reaction is redox reaction; identify the species oxidized/reduced, which acts as an oxidant and which acts as a reductant.

\[\ce{2Cu2O_{(S)} + Cu2S_{(S)}->6Cu_{(S)} + SO2_{(g)}}\]

थोडक्यात उत्तर

उत्तर

\[\ce{2Cu2O_{(S)} + Cu2S_{(S)}->6Cu_{(S)} + SO2_{(g)}}\]

  1. Write an oxidation number of all the atoms of reactants and products.
  2. Identify the species that undergoes a change in oxidation number.
  3. The oxidation number of S increases from –2 to +4 and that of Cu decreases from +1 to 0. Because the oxidation number of one species increases and that of the other decreases, the reaction is a redox reaction.
  4. The oxidation number of S increases by loss of electrons and therefore, S is a reducing agent and it itself is oxidised. On the other hand, the oxidation number of Cu decreases by the gain of electrons, and therefore, Cu is an oxidising agent and itself is reduced.

Result:

  1. The given reaction is a redox reaction.
  2. Oxidant/oxidising agents (Reduced species): Cu2O/ Cu2S
  3. Reductant/reducing agent (Oxidised species): Cu2S
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Balancing Redox Reactions in Terms of Loss and Gain of Electrons
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पाठ 6: Redox Reactions - Exercises [पृष्ठ ९२]

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बालभारती Chemistry [English] 11 Standard
पाठ 6 Redox Reactions
Exercises | Q 3. (D)(a) | पृष्ठ ९२

संबंधित प्रश्‍न

Consider the reaction:

\[\ce{O3(g) + H2O2(l) → H2O(l) + 2O2(g)}\]

Why it is more appropriate to write these reaction as:

\[\ce{O3(g) + H2O2 (l) → H2O(l) + O2(g) + O2(g)}\]

Also, suggest a technique to investigate the path of the redox reactions.


The compound AgF2 is an unstable compound. However, if formed, the compound acts as a very strong oxidizing agent. Why?


Whenever a reaction between an oxidising agent and a reducing agent is carried out, a compound of lower oxidation state is formed if the reducing agent is in excess and a compound of higher oxidation state is formed if the oxidising agent is in excess. Justify this statement giving three illustrations.


How do you count for the following observations?

Though alkaline potassium permanganate and acidic potassium permanganate both are used as oxidants, yet in the manufacture of benzoic acid from toluene we use alcoholic potassium permanganate as an oxidant. Why? Write a balanced redox equation for the reaction.


Balance the following redox reactions by ion-electron method:

  1. \[\ce{MnO-_4 (aq) + I– (aq) → MnO2 (s) + I2(s) (in basic medium)}\]
  2. \[\ce{MnO-_4 (aq) + SO2 (g) → Mn^{2+} (aq) + HSO-_4  (aq) (in acidic solution)}\]
  3. \[\ce{H2O2 (aq) + Fe^{2+} (aq) → Fe^{3+} (aq) + H2O (l) (in acidic solution)}\]
  4. \[\ce{Cr_2O^{2-}_7 + SO2(g) → Cr^{3+} (aq) + SO^{2-}_4 (aq) (in acidic solution)}\]

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\[\ce{Cr2O^2-_{7(aq)} + SO^2-_{3(aq)}->Cr^3+_{ (aq)} + SO^2-_{4(aq)}(acidic)}\]


Balance the following reaction by oxidation number method.

\[\ce{MnO^-_{4(aq)} + Br^-_{ (aq)}->MnO2_{ (s)} + BrO^-_{3(aq)}(basic)}\]


Balance the following reaction by oxidation number method.

\[\ce{Bi(OH)_{3(s)} + Sn(OH)^-_{3(aq)}->Bi_{(s)}  + Sn(OH)^2-_{6(aq)}(basic)}\]


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\[\ce{H2C2O_{4(aq)} + MnO^-_{4(aq)}->CO2_{(g)} + Mn^2+_{( aq)}(acidic)}\]


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\[\ce{Bi(OH)_{3(s)} + SnO^2-_{2(aq)}->SnO^2-_{3(aq)} + Bi^_{(s)}(basic)}\]


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\[\ce{2Zn_{(s)} + O2_{(g)} -> 2ZnO_{(s)}}\]


Which of the following is a redox reaction?


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\[\ce{MnO^-_{4(aq)} + SO^{2-}_{3(aq)} -> MnO^{2-}_{4(aq)} + SO^{2-}_{4(aq)}}\]


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\[\ce{CH4_{(g)} + 2O2_{(g)} -> CO2_{(g)} + 2H2O_{(l)}}\]


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\[\ce{6 CO2(g) + 6H2O(l) → C6 H12O6(aq) + 6O2(g)}\]

Why it is more appropriate to write these reaction as:

\[\ce{6CO2(g) + 12H2O(l) → C6 H12O6(aq) + 6H2O(l) + 6O2(g)}\]

Also, suggest a technique to investigate the path of the redox reactions.


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\[\ce{I2 + NO^{-}3 -> NO2 + IO^{-}3}\]


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\[\ce{HgCl2 (aq) + 2KI (aq) -> HgI2 (s) + 2KCl (aq)}\]


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\[\ce{Cr2O^{2-}7 + Fe^{2+} + H+ -> Cr^{3+} + Fe^{3+} + H2O}\]


Balance the following ionic equations.

\[\ce{MnO^{-}4 + SO^{2-}3 + H^{+} -> Mn^{2+} + SO^{2-}4 + H2O}\]


Balance the following ionic equations.

\[\ce{MnO^{-}4 + H^{+} + Br^{-} -> Mn^{2+} + Br2 + H2O}\]


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Consider the following reaction:

\[\ce{xMnO^-_4 + yC2O^{2-}_4 + zH^+ -> xMn^{2+} + 2{y}CO2 + z/2H2O}\]

The values of x, y, and z in the reaction are, respectively:


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