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State Hund’s rule of maximum multiplicity with a suitable example. - Chemistry

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प्रश्न

State Hund’s rule of maximum multiplicity with a suitable example.

थोडक्यात उत्तर

उत्तर

Hund’s rule of maximum multiplicity:

  1. Statement: “Pairing of electrons in the orbitals belonging to the same subshell does not occur unless each orbital belonging to that subshell has got one electron each.”
  2. For example, according to Hund’s rule, each of the three-degenerate p-orbitals must get one electron of parallel spin before anyone of them receives the second electron of opposite spin. Therefore, the configuration of four electrons occupying p-orbitals is represented as
    ↑↓
    and not as  
    ↑↓ ↑↓  
  3. As a result of Hund’s rule, the atom with fully filled and half-filled set of degenerate orbitals has extra stability.
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पाठ 4: Structure of Atom - Exercises [पृष्ठ ५४]

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बालभारती Chemistry [English] 11 Standard
पाठ 4 Structure of Atom
Exercises | Q 6. (D) | पृष्ठ ५४

संबंधित प्रश्‍न

Using s, p, d notations, describe the orbital with the following quantum numbers n = 3; l =1.


Using s, p, d notations, describe the orbital with the following quantum numbers n = 4; l =3.


Choose the correct option.

“No two electrons in the same atoms can have identical set of four quantum numbers”. This statement is known as -


Choose the correct option.

Principal Quantum number describes -


Write orbital notations for the electron in orbitals with the following quantum numbers.

n = 4, l = 2


Write condensed orbital notation of electronic configuration of the following element:

Oxygen (Z = 8)


Write condensed orbital notation of electronic configuration of the following element:

Silicon (Z = 14)


Write condensed orbital notation of electronic configuration of the following element:

Chlorine (Z = 17)


Draw shapes of 2p orbitals.


Explain in brief, the significance of the azimuthal quantum number.


The electronic configuration of oxygen is written as 1s2 2s2 \[\ce{2p^2_{{x}}}\] \[\ce{2p^1_{{y}}}\] \[\ce{2p^1_{{z}}}\] and not as 1s2 2s2 \[\ce{2p^2_{{x}}}\], \[\ce{2p^2_{{y}}}\] \[\ce{2p^0_{{z}}}\], Explain.


Using the concept of quantum numbers, calculate the maximum numbers of electrons present in the ‘M’ shell. Give their distribution in shells, subshells, and orbitals.


Which mineral among the following contains vanadium in it?


How many electrons can fit in the orbital for which n = 4 and l = 2?


Which of the following has a greater number of electrons than neutrons?

(Mass number of Mg, C, O and Na is 24, 12, 16 and 23 respectively).


The probability density plots of 1s and 2s orbitals are given in Figure:


The density of dots in a region represents the probability density of finding electrons in the region.

On the basis of above diagram which of the following statements is incorrect?


Which of the following properties of atom could be explained correctly by Thomson Model of atom?


Nickel atom can lose two electrons to form \[\ce{Ni^{2+}}\] ion. The atomic number of nickel is 28. From which orbital will nickel lose two electrons.


The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.

Based upon the above information, arrange the following orbitals in the increasing order of energy.

4s, 3s, 3p, 4d


The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.

Based upon the above information, solve the questions given below:

Which of the following orbitals has the lowest energy?

5p, 5d, 5f, 6s, 6p


What is the difference between the terms orbit and orbital?


Choose the INCORRECT statement


In the case of R, S configuration the group having the highest priority is ______.


Which of the following element do not follow Aufbau principle?


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