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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Which of the Following Compounds is Not Prepared by the Action of Alcoholic Ni3 on Alkyl Halide - Chemistry

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प्रश्न

Which of the following compounds is NOT prepared by the action of alcoholic NI3 on alkyl halide?

(a) CH3NH2

(b) CH3- CH2- NH2

(c) CH3 - CH2 - CH2 - NH2

(d) (CH3)C- NH2

उत्तर

(CH3)3C – NH2

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2015-2016 (July)

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व्हिडिओ ट्यूटोरियलVIEW ALL [3]

संबंधित प्रश्‍न

What is metamerism? 


Explain metamerism with suitable examples of ethers


Name the following compound according to IUPAC system.

\[\begin{array}{cc}
\phantom{............}\ce{CH2OH}\\
\phantom{......}|\\
\ce{CH3 - CH2 - CH - CH - CH - CH3}\\
\phantom{......}|\phantom{............}|\phantom{.}\\
\phantom{........}\ce{CH2Cl}\phantom{......}\ce{CH3}\phantom{}
\end{array}\]


Name the following compound according to IUPAC system.

\[\begin{array}{cc}
\phantom{........................}\ce{CH2OH}\\
\phantom{..................}|\\
\ce{CH3 - CH - CH2 - CH - CH - CH3}\\
\phantom{}|\phantom{.............}|\phantom{........}\\
\phantom{..}\ce{CH3}\phantom{..........}\ce{OH}\phantom{........}
\end{array}\]


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\ce{CH3 - CH - CH - CH3}\\
|\phantom{......}|\phantom{..}\\
\ce{OH}\phantom{...}\ce{OH}\phantom{}
\end{array}\]


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\ce{HO - CH2 - CH - CH2 - OH}\\
|\phantom{..}\\
\ce{OH}
\end{array}\]


Write IUPAC name of the following compound:


Write IUPAC name of the following compound:


Write IUPAC name of the following compound:

C6H5 – O – C2H5


Write IUPAC name of the following compound:

C6H5 – O – C7H15(n−)


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\ce{CH3 - CH2 - O - CH - CH2 - CH3}\\
\phantom{...}|\\
\phantom{.....}\ce{CH3}
\end{array}\]


Write structures of the compounds whose IUPAC names are as follows:

3-Chloromethylpentan-1-ol.


  1. Draw the structures of all isomeric alcohols of molecular formula C5H12O and give their IUPAC names.
  2. Classify the isomers of alcohols in the above question as primary, secondary and tertiary alcohols.

Give IUPAC name of the following ether:

\[\begin{array}{cc}
\ce{C2H5OCH2 - CH - CH3}\\
\phantom{.....}|\\
\phantom{.......}\ce{CH3}
\end{array}\]


Give IUPAC name of the following ether:

CH3OCH2CH2Cl


Give IUPAC name of the following ether:

CH3CH2CH2OCH3


Give IUPAC name of the following ether:


Ethylidene dichloride when boiled with aqueous solution of NaOH yields _______.

(A) formaldehyde

(B) acetaldehyde

(C) acetone

(D) ethyl methyl ketone


3-Methylbutane-2-ol on heating with HI gives ______


How is phenol converted into the following?

benzene


How is phenol converted into the following?

picric acid


Write IUPAC name of the following compound (CH3)2 N − CH2CH3


Write the structures of the products when Butan-2-ol reacts with CrO3


Write the structures of the products when Butan-2-ol reacts with SOCl2


Write the IUPAC name of the following :


How do you convert the Ethanal to Propanone


Propanoic acid to ethylamine.


Write structural formulae for 3-Methoxyhexane


Write structural formulae for Pentane-1,4-diol


Write structural formulae for Cyclohex-2-en-1-ol.


Write IUPAC names of the following


Glycerol is ____________.


Isopropyl alcohol on oxidation forms:


Give IUPAC names of the following compound:


C6H5OCH2CH3 is called:


3-methylphenol is called ____________.


One of the following is not a dihydroxy derivative of benzene.


An example of a compound with functional group – O – is ____________.


Cresol has ____________.


Which of the following compounds is oxidised to prepare methyl ethyl ketone?


n-Propyl alcohol and isopropyl alcohol can be chemically distinguished by which reagent?


When ethyl alcohol reacts with acetic acid, the products formed are:


1-Propanol and 2-propanol can be best distinguished by:


Which of the following is most acidic?


The IUPAC name of the ether CH2 = CH–CH2OCH3 is:


\[\ce{HC ≡ CH ->[HgSO4][H2SO4] ->[CH3MgBr][H2O] ->[PBr3]}\]


The heating of phenyl methyl ether with HI produces:


\[\ce{Phenol ->[Zn, dust] 'X' ->[CH3Cl][Anhy. AlCl3] 'Y' ->[Alkaline][KMnO4] 'Z'}\]

The product ‘Z’ is:


The correct acidic strength order of the following is:


     (I)


    (II)


     (III)


Give IUPAC name of the compound given below.

\[\begin{array}{cc}
\phantom{}\ce{CH3 - CH - CH2 - CH2 - CH - CH3}\phantom{.}\\
\phantom{.........}|\phantom{...................}|\phantom{...........}\\
\phantom{..}\ce{Cl}\phantom{.................}\ce{OH}\phantom{..}
\end{array}\]


Which of the following compounds will react with sodium hydroxide solution in water?


Which of the following reagents can be used to oxidise primary alcohols to aldehydes?

(i) \[\ce{CrO3}\] in anhydrous medium.

(ii) \[\ce{KMnO4}\] in acidic medium.

(iii) Pyridinium chlorochromate.

(iv) Heat in the presence of Cu at 573 K.


Write the IUPAC name of the compound given below.

\[\begin{array}{cc}
\phantom{}\ce{CH3 - CH2 - C = C - OH}\\
\phantom{........}|\phantom{....}|\phantom{}\\
\phantom{..............}\ce{CH3 CH2OH}
\end{array}\]


Write steps to carry out the conversion of phenol to aspirin.


Match the structures of the compounds given in Column I with the name of the compounds given in Column II.

  Column I Column II
(i) (a) Hydroquinone
(ii) (b) Phenetole
(iii) (c) Catechol
(iv) (d) o-Cresol
(v) (e) guinone
(vi) (f) Resorcinol
    (g) Anisole

Match the starting materials given in Column I with the products formed by these (Column II) in the reaction with HI.

  Column I   Column II
(i) CH3—O—CH3 (a)
(ii) \[\begin{array}{cc}
\ce{CH3}\phantom{..................}\\
\backslash\phantom{.............}\\
\ce{CH-O-CH3}\\
/\phantom{..............}\\
\ce{CH3}\phantom{..................}
\end{array}\]
(b) \[\begin{array}{cc}
\ce{CH3}\phantom{....}\\
|\phantom{.......}\\
\ce{CH3-C-I + CH3OH}\\
|\phantom{.......}\\
\ce{CH3}\phantom{....}
\end{array}\]
(iii) \[\begin{array}{cc}
\ce{CH3}\phantom{.}\\
|\phantom{....}\\
\ce{H3C-C-O-CH3}\\
|\phantom{....}\\
\ce{CH3}\phantom{..}
\end{array}\]
(c)
(iv) (d) CH3—OH + CH3—I
    (e) \[\begin{array}{cc}
\ce{CH3}\phantom{.....................}\\
\backslash\phantom{.................}\\
\ce{CH-OH + CH3I}\\
/\phantom{.................}\\
\ce{CH3}\phantom{.....................}
\end{array}\]
    (f) \[\begin{array}{cc}
\ce{CH3}\phantom{.....................}\\
\backslash\phantom{.................}\\
\ce{CH-I + CH3OH}\\
/\phantom{.................}\\
\ce{CH3}\phantom{.....................}
\end{array}\]
    (g) \[\begin{array}{cc}
\ce{CH3}\phantom{....}\\
|\phantom{.......}\\
\ce{CH3-C-OH + CH3I}\\
|\phantom{.......}\\
\ce{CH3}\phantom{....}
\end{array}\]

Assertion: Addition reaction of water to but-1-ene in acidic medium yields butan-1-ol.

Reason: Addition of water in acidic medium proceeds through the formation of primary carbocation.


Assertion: IUPAC name of the compound

\[\begin{array}{cc}
\ce{CH3 - CH - O - CH2 - CH2 - CH3}\\  
|\phantom{....................}\\
\ce{CH3}\phantom{.................}
\end{array}\] is 2-Ethoxy-2-methylethane.

Reason: In IUPAC nomenclature, ether is regarded as hydrocarbon derivative in which a hydrogen atom is replaced by —OR or —OAr group [where R = alkyl group and Ar = aryl group]


Assertion: Like bromination of benzene, bromination of phenol is also carried out in the presence of Lewis acid.

Reason: Lewis acid polarises the bromine molecule.


Write complete reaction for the bromination of phenol in aqueous and non-aqueous medium.


How can phenol be converted to aspirin?


Write the IUPAC name of the following compound.


Write chemical reactions for the following conversion:

Acetic acid into ethyl alcohol


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{..}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]


Draw structure of the following compound.

2. 5-Diethylphenol


Draw structure of the following compound.

Prop-2-en-1-ol


Write structural formulae for:

Salicylic acid


The IUPAC name of is ______.


Write the IUPAC name of the following compound:

\[\begin{array}{cc}
\phantom{..............}\ce{CH3}\\
\phantom{............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{.....}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{.}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]


Write IUPAC names of the following compounds: 

\[\begin{array}{cc}
\phantom{...............}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3\phantom{...}OH\phantom{...}CH3}\\
\end{array}\] 


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{...}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]


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