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Question
Give one chemical test as an evidence to show that [Co (NH3)5Cl] are ionisation isomers.
Solution
The ionisation isomers dissolve in water to yield different ions and thus react differently to various reagents.
[Co (NH3)5] SO4 ] Cl + Ba2+ → No reactions
[Co (NH3)5Cl]SO4 + Ag+ → No reactions
[Co (NH3)5SO4]Cl + Ag+ → AgCl (s) (white solid)
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\[\ce{Pt(NH3)2ClNO2}\]
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