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Question
Write the type of isomerism exhibited by [Co(NH3)5(NO2)]2+ and [Co(NH3)5ONO]2+ pair of complex ion.
Solution
The type of isomerism exhibited is linkage isomerism.
RELATED QUESTIONS
List various types of isomerism possible for coordination compounds, giving an example of each.
Answer the following in one or two sentences.
Consider the complexes \[\ce{[Cu(NH3)4][PtCl4] and [Pt(NH3)4] [CuCl4]}\]. What type of isomerism these two complexes exhibit?
Draw isomers of the following.
\[\ce{Pt(NH3)2ClNO2}\]
Answer the following question.
Draw geometric isomers and enantiomers of the following complex.
[Pt(en)2ClBr]2⊕
Draw optical isomers of [Co(en)3]3+.
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How many geometrical isomers are possible for \[\ce{[Pt(Py)(NH3)(Br)(Cl)]}\]?
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\[\ce{IUPAC}\] name of \[\ce{[Pt(NH3)2 Cl(NO2)]}\] is ______.
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Which of the following compound show optical isomerism?
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Consider the above reaction and identify the missing reagent/chemical.
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(B) SiCl4 and TiCl4
(C) NH3 and \[\ce{NO^-3}\]
(D) BCl3 and BrCl3
Which compound would exhibit optical isomers?
White precipitate of AgCl dissolves in aqueous ammonia solution due to formation of ______.
Give cis isomer of [Co(NH3)4Cl2]⊕.
Explain the ionisation isomers.
Match the pairs in column I (pairs of isomers) and column II (types of isomers)
| Column I (Pairs of isomers) |
Column II (Types of isomers) |
| (A) [Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O | (i) Ionization isomers |
| (B) [Co(en)2(NO2)2]+ and [Co(en)2(ONO2)]+ | (ii) Hydrate isomers |
| (C) [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6] | (iii) Linkage isomers |
| (D) [Pt(NH3)4Cl2] Br2 and [Pt(NH3)4Br2]Cl2 | (iv) Coordination isomers |
Give a chemical test to show that \[\ce{[Co(NH3)5Cl]SO4}\] and \[\ce{[Co(NH3)5SO4]CI}\] are ionisation isomers.
Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.
- Write the structures of the compounds A, B and C.
- Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.
