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Chemistry Model set 1 by shaalaa.com 2024-2025 HSC Science (General) 12th Standard Board Exam Question Paper Solution

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Chemistry [Model set 1 by shaalaa.com]
Marks: 70 Maharashtra State Board
HSC Science (General)
HSC Science (Electronics)
HSC Science (Computer Science)

Academic Year: 2024-2025
Date: March 2025
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General Instructions: The question paper is divided into four sections. 

  1. Section A: Q.No.1 contains Ten multiple-choice types of questions carrying One mark each. Q.No.2 contains Eight very short answer type of questions carrying One mark each.
  2. Section B: Q.No.3 to Q.No.14 are Twelve short answer type questions carrying Two marks each. (Attempt any Eight).
  3. Section C: Q.No.15 to Q.No.26 are Twelve short answer type questions carrying Three marks each. (Attempt any Eight).
  4.  Section D: Q.No.27 to Q.No.31 are Five Long answer-type questions carrying Four marks each. (Attempt any Three).
  5. Use of Log table is allowed. Use of calculator is not allowed.
  6. Figures to the right indicate full marks.
  7.  For each multiple-choice type question, it is mandatory to write the correct answer along with its alphabet. e.g., (a) .............. /(b) ............... /(c) ............... /(d) ................ ,etc. No mark(s) shall be given if ONLY the correct answer or the alphabet of the correct answer is written.
    Only the first attempt will be considered for evaluation. 

SECTION - A
[10]1 | Select and write the correct answer for the following multiple-choice type of questions:
[1]1.i

Select the most appropriate option.

A gas is allowed to expand in a well-insulated container against a constant external pressure of 2.5 bar from an initial volume of 2.5 L to a final volume of 4.5 L. The change in internal energy, ΔU of the gas will be _______.

–500 J

+ 500 J

–1013 J

+ 1013 J

Concept: undefined - undefined
Chapter: [0.04] Chemical Thermodynamics
[1]1.ii

Choose the most correct option.

Formula for the compound sodium hexacynoferrate (III) is ____________.

[NaFe(CN)6]

Na2[Fe(CN)6]

Na[Fe(CN)6]

Na3[Fe(CN)6]

Concept: undefined - undefined
Chapter: [0.09] Coordination Compounds
[1]1.iii

Polonium has the half-Life of ______.

13.8 days

12 days

5 days

102 days

Concept: undefined - undefined
Chapter: [0.07] Elements of Groups 16, 17 and 18
[1]1.iv

Choose the most correct option.

The oxidation state of cobalt ion in the complex [Co(NH3)5 Br]SO4 is __________.

+2

+3

+1

+4

Concept: undefined - undefined
Chapter: [0.09] Coordination Compounds
[1]1.v

\[\ce{CH2OH-CO-(CHOH)4-CH2OH}\] is an example of ______.

Aldohexose

Aldoheptose

Ketotetrose

Ketoheptose

Concept: undefined - undefined
Chapter: [0.14] Biomolecules
[1]1.vi

Choose the most correct answer:

Which of the Na following is a buffer solution?

CH3COONa + NaCl in water

CH3COOH + HCl in water

CH3COOH + CH3COONa in water

HCl + NH4Cl in water

Concept: undefined - undefined
Chapter: [0.03] Ionic Equilibria
[1]1.vii

Which cells is used as a source of power in flashlights?

Dry cell

Fuel cell

Hydrogen cell

None of them

Concept: undefined - undefined
Chapter: [0.05] Electrochemistry
[1]1.viii

Choose the correct option.

Which of the following is the least acidic compound?

Concept: undefined - undefined
Chapter: [0.11] Alcohols, Phenols and Ethers
[1]1.ix

The boiling point of HCl is ______.

189 K

200 K

210 K

220 K

Concept: undefined - undefined
Chapter: [7.03] Group 17 Elements
[1]1.x

Choose the correct option.

Which of the following substrate will give ionic organic products on reaction?

CH3 – CH2 – OH + Na

CH3 – CH2 – OH + SOCl2

CH3 – CH2 – OH + PCl5

CH3 – CH2 – OH + H2SO4

Concept: undefined - undefined
Chapter: [0.11] Alcohols, Phenols and Ethers
[8]2 | Answer the following questions:
[1]2.i

Answer the following in one or two sentences.

Comment on the statement:

no work is involved in an expansion of gas in a vacuum.

Concept: undefined - undefined
Chapter: [0.04] Chemical Thermodynamics
[1]2.ii

Name one amphoteric solvent.

Concept: undefined - undefined
Chapter: [0.03] Ionic Equilibria
[1]2.iii

Presence of disulphide link gives rise to which structure of protein?

Concept: undefined - undefined
Chapter: [14.02] Proteins
[1]2.iv

Answer the following in one sentence.

Name some chain-growth polymers.

Concept: undefined - undefined
Chapter: [0.15] Introduction to Polymer Chemistry
[1]2.v

Give names of the purines.

Concept: undefined - undefined
Chapter: [0.14] Biomolecules
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[1]2.vi

Answer the following in one or two sentences.

What is standard cell potential for the reaction

\[\ce{3Ni_{(s)} + 2Al^{3+} (1M) → 3Ni^{2+} (1M) + 2Al(s)}\], if `E_"Ni"^circ` = –0.25 V and  `"E"_("Al")^circ` = –1.66 V?

Concept: undefined - undefined
Chapter: [0.05] Electrochemistry
[1]2.vii

Answer the following.

Name two gases which deplete ozone layer.

Concept: undefined - undefined
Chapter: [0.07] Elements of Groups 16, 17 and 18
[1]2.viii

Answer the following.

What is the action of bromine on magnesium metal?

Concept: undefined - undefined
Chapter: [0.07] Elements of Groups 16, 17 and 18
SECTION - B
[2]3 | Attempt any EIGHT of the following questions:

Answer the following in one sentence.

Write reaction showing conversion of benzonitrile into benzoic acid.

Concept: undefined - undefined
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids
[2]4

Solve

The half-life of a first-order reaction is 1.7 hours. How long will it take for 20% of the reactant to react?

Concept: undefined - undefined
Chapter: [0.06] Chemical Kinetics
[2]5

Write structural formulae for Pentane-1,4-diol

Concept: undefined - undefined
Chapter: [0.11] Alcohols, Phenols and Ethers [11.01] Alcohols [11.02] Phenols [11.03] Ethers

Write structural formulae for Cyclohex-2-en-1-ol.

Concept: undefined - undefined
Chapter: [0.11] Alcohols, Phenols and Ethers [11.01] Alcohols [11.02] Phenols [11.03] Ethers
[2]6

Answer the following

Which nanomaterial is used in sunscreen lotion? Write its use.

Concept: undefined - undefined
Chapter: [0.16] Green Chemistry and Nanochemistry
[2]7

Write two points of difference between the properties of phenol and ethyl alcohol.

Concept: undefined - undefined
Chapter: [0.11] Alcohols, Phenols and Ethers
[2]8

Give reason:

Reactions involving Grignard reagent must be carried out under anhydrous condition.

Concept: undefined - undefined
Chapter: [0.1] Halogen Derivatives
[2]9

Write the reaction of conc. H2SO4 with sugar. What is the role of H2SO4 in this reaction?

Concept: undefined - undefined
Chapter: [7.02] Group 16 Elements
[2]10

Answer the following

What is diazotisation?

Concept: undefined - undefined
Chapter: [0.13] Amines

Answer the following

Write diazotisation reaction of aniline?

Concept: undefined - undefined
Chapter: [0.13] Amines
[2]11

Answer the following in one or two sentences.

Why all collisions between reactant molecules do not lead to a chemical reaction?

Concept: undefined - undefined
Chapter: [0.06] Chemical Kinetics
[2]12

Answer the following in one sentence.

Write reaction showing conversion of ethanenitrile into ethanol.

Concept: undefined - undefined
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids [12.01] Aldehydes and Ketones
[2]13

In NaOH solution [OH] is 2.87 × 104. Calculate the pH of the solution.

Concept: undefined - undefined
Chapter: [0.03] Ionic Equilibria
[2]14

Give scientific reasons:

On complete hydrolysis DNA gives equimolar quantities of adenine and thymine.

Concept: undefined - undefined
Chapter: [0.14] Biomolecules
SECTION - C
[3]15 | Attempt any EIGHT of the following questions:

Answer the following in brief.

Obtain the relationship between the rate constant and half-life of a first-order reaction.

Concept: undefined - undefined
Chapter: [0.06] Chemical Kinetics
[3]16

Answer the following question.

Draw geometric isomers and enantiomers of the following complex.

[Pt(en)3]4⊕

Concept: undefined - undefined
Chapter: [0.09] Coordination Compounds

Answer the following question.

Draw geometric isomers and enantiomers of the following complex.

[Pt(en)2ClBr]2⊕

Concept: undefined - undefined
Chapter: [0.09] Coordination Compounds

Draw geometric isomers of the following complex.

Geometrical isomers of Pt(NH3)2Cl2

Concept: undefined - undefined
Chapter: [0.09] Coordination Compounds
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[3]17

Answer the following.

Write structure of natural rubber and neoprene rubber along with the name and structure of their monomers.

Concept: undefined - undefined
Chapter: [0.15] Introduction to Polymer Chemistry [0.15] Polymers
[3]18

Obtain the relationship between ΔH and ΔU for gas phase reactions.

Concept: undefined - undefined
Chapter: [0.04] Chemical Thermodynamics
[3]19

Answer the following in brief.

It is impossible to measure the potential of a single electrode. Comment.

Concept: undefined - undefined
Chapter: [0.05] Electrochemistry
[3]20

Distinguish between SN1 and SN2 mechanism of substitution reaction.

Concept: undefined - undefined
Chapter: [0.1] Halogen Derivatives
[3]21

Answer the following in brief.

Explain graphically the effect of temperature on the rate of reaction.

Concept: undefined - undefined
Chapter: [0.06] Chemical Kinetics
[3]22

An element has a bee structure with unit cell edge length of 288 pm. How many unit cells and number of atoms are present in 200 g of the element?

Concept: undefined - undefined
Chapter: [0.01] Solid State
[3]23
[1]23.i

Answer in brief.

What is the action of hydrazine on cyclopentanone in presence of KOH in ethylene glycol?

Concept: undefined - undefined
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids
[2]23.ii

How ketones are prepared from nitriles?

Concept: undefined - undefined
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids [12.01] Aldehydes and Ketones
[3]24

Answer the following:

What are anode and cathode for Leclanche' dry cell?

Concept: undefined - undefined
Chapter: [0.05] Electrochemistry

Write electrode reactions and overall cell reaction when Leclanche's dry cell generates electricity.

Concept: undefined - undefined
Chapter: [0.05] Electrochemistry
[3]25

Answer in brief.

Write reaction showing conversion of Acetaldehyde into acetaldehyde dimethyl acetal.

Concept: undefined - undefined
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids
[3]26
[1]26.i

A solution of citric acid C6H8O7 in 50 g of acetic acid has a boiling point elevation of 1.76 K. If Kb for acetic acid is 3.07 K kg mol-1, what is the molality of solution?

Concept: undefined - undefined
Chapter: [0.02] Solutions
[2]26.ii

0.01 m aqueous formic acid solution freezes at – 0.021°C. Calculate its degree of dissociation, Kf = 1.86 K kg mol–1.

Concept: undefined - undefined
Chapter: [0.02] Solutions
SECTION - D
[4]27 | Attempt any THREE of the following questions:

Answer the following

What are the differences between cast iron, wrought iron, and steel?

Concept: undefined - undefined
Chapter: [0.08] Transition and Inner Transition Elements
[4]28

Answer the following :

Explain the relation between ionic product and solubility product to predict whether a precipitate will form when two solutions are mixed?

Concept: undefined - undefined
Chapter: [0.03] Ionic Equilibria
[4]29

Write reaction showing conversion of p-bromoisopropylbenzene into p-isopropylbenzoic acid (3 steps).

Concept: undefined - undefined
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids
[4]30

Answer the following

Explain trends in ionisation enthalpies of d-block elements.

Concept: undefined - undefined
Chapter: [0.08] Transition and Inner Transition Elements
[4]31

Answer the following question.

What are cationic, anionic, and neutral complexes? Give one example of each.

Concept: undefined - undefined
Chapter: [0.09] Coordination Compounds

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