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Balbharati solutions for Chemistry [English] 12 Standard HSC chapter 13 - Amines [Latest edition]

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Balbharati solutions for Chemistry [English] 12 Standard HSC chapter 13 - Amines - Shaalaa.com
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Solutions for Chapter 13: Amines

Below listed, you can find solutions for Chapter 13 of Maharashtra State Board Balbharati for Chemistry [English] 12 Standard HSC.


Exercises
Exercises [Pages 296 - 297]

Balbharati solutions for Chemistry [English] 12 Standard HSC 13 Amines Exercises [Pages 296 - 297]

Exercises | Q 1.01 | Page 296

Choose the most correct option.

The hybridisation of nitrogen in primary amine is ____________.

  • sp

  • sp2

  • sp3

  • sp3d

Exercises | Q 1.02 | Page 296

Isobutylamine is an example of ______.

  • 2° amine

  • 3° amine

  • 1° amine

  • quaternary ammonium salt

Exercises | Q 1.03 | Page 296

Choose the most correct option.

Which one of the following compounds has the highest boiling point?

  • n-Butylamine

  • sec-Butylamine

  • isobutylamine

  • tert-Butylamine

Exercises | Q 1.04 | Page 296

Choose the most correct option.

Which of the following has the highest basic strength?

  • Trimethylamine

  • Methylamine

  • Ammonia

  • Dimethylamine

Exercises | Q 1.05 | Page 296

Choose the most correct option.

Which type of amine does produce N2 when treated with HNO2?

  • Primary amine

  • Secondary amine

  • Tertiary amine

  • Both primary and secondary amines

Exercises | Q 1.06 | Page 296

Choose the most correct option.

Carbylamine test is given by ____________.

  • Primary amine

  • Secondary amine

  • Tertiary amine

  • Both secondary and tertiary amines

Exercises | Q 1.07 | Page 296

Which one of the following compounds does not react with acetyl chloride?

  • CH3 - CH2 - NH2

  • (CH3 - CH2)2NH

  • (CH3 - CH2)3N

  • C6H5 - NH2

Exercises | Q 1.08 | Page 296

Choose the most correct option.

Which of the following compounds will dissolve in aqueous NaOH after undergoing reaction with Hinsberg reagent?

  • Ethylamine

  • Triethylamine

  • Trimethylamine

  • Diethylamine

Exercises | Q 1.09 | Page 296

Choose the most correct option.

Identify ‘B’ in the following reactions

\[\ce{CH3 - C ≡ N ->[Na/C2H5OH] A ->[NaNO2/dilHCl]B}\]

  • CH3 - CH2 - NH2

  • CH3 - CH2 - NO2

  • CH3 - CH2N2+Cl-

  • CH3 - CH2 - OH

Exercises | Q 1.1 | Page 296

Choose the most correct option.

Which of the following compounds contains azo linkage?

  • Hydrazine

  • p-Hydroxyazobenzene

  • N-Nitrosodiethylamine

  • Ethylenediamine

Exercises | Q 2.01 | Page 296

Answer in one sentence.

Write the reaction of p-toluenesulphonyl chloride with diethylamine.

Exercises | Q 2.02 | Page 296

Answer in one sentence.

How many moles of methylbromide is required to convert ethanamine to N, N-dimethyl ethanamine?

Exercises | Q 2.03 | Page 297

Answer in one sentence.

Which amide does produce ethanamine by Hofmann bromamide degradation reaction?

Exercises | Q 2.04 | Page 297

Answer in one sentence.

Write the order of the basicity of aliphatic alkylamine in the gaseous phase.

Exercises | Q 2.05 | Page 297

Answer in one sentence.

Why are primary aliphatic amines stronger bases than ammonia?

Exercises | Q 2.06 | Page 297

Answer in one sentence.

Predict the product of the following reaction.

\[\ce{Nitrobenzene ->[Sn/conc.HCl]?}\]

Exercises | Q 2.07 | Page 297

Answer in one sentence.

Write the IUPAC name of benzylamine.

Exercises | Q 2.08 | Page 297

Answer in one sentence.

Arrange the following amines in increasing order of boiling points.

n-propylamine, ethylmethyl amine, trimethylamine.

Exercises | Q 2.09 | Page 297

Answer in one sentence.

Write the balanced chemical equations for the action of dil H2SO4 on diethylamine.

Exercises | Q 2.1 | Page 297

Answer in one sentence.

Arrange the following amines in the increasing order of their pKb values.

Aniline, Cyclohexylamine, 4-Nitroaniline

Exercises | Q 3.01 | Page 297

Answer the following

Identify A and B in the following reactions.

\[\ce{C6H5CH2Br->[alco.][KCN]A ->[Na/ethanol]B.}\]

Exercises | Q 3.02 | Page 297

Explain the basic nature of amines with a suitable example.

Exercises | Q 3.03 | Page 297

Answer the following

What is diazotisation?

Exercises | Q 3.03 | Page 297

Answer the following

Write diazotisation reaction of aniline?

Exercises | Q 3.04 | Page 297

Answer the following

Write a reaction to convert acetic acid into methylamine.

Exercises | Q 3.05 | Page 297

Write a short note on coupling reactions.

Exercises | Q 3.06 | Page 297

Answer the following

Explain Gabriel phthalimide synthesis.

Exercises | Q 3.07 | Page 297

Answer the following

Explain carbylamine reaction with suitable examples.

Exercises | Q 3.08 | Page 297

Answer the following

Write a reaction to convert methanamine into ethanamine.

Exercises | Q 3.08 | Page 297

Answer the following

Write a reaction to convert Aniline into p-bromoaniline.

Exercises | Q 3.09 | Page 297

Answer the following

Complete the following reaction :

`"C"_6"H"_5"N"_2^+"Cl"^-` + C2H5OH → 

Exercises | Q 3.09 | Page 297

Answer the following

Complete the following reaction :

\[\ce{C6H5NH2 + Br2_{(aq)} -> ?}\]

Exercises | Q 3.1 | Page 297

Answer the following

Explain the ammonolysis of alkyl halides.

Exercises | Q 3.11 | Page 297

Answer the following

Write a reaction to convert ethylamine into methylamine.

Exercises | Q 4.1 | Page 297

Answer the following.

Write the IUPAC name of the following amine :

\[\begin{array}{cc}
\ce{CH3 - CH2 - N - CH2 - CH2 - CH3}\\
|\phantom{........}\\
\ce{CH3\phantom{......}}
\end{array}\]

Exercises | Q 4.1 | Page 297

Answer the following.

Write the IUPAC name of the following amine :

\[\begin{array}{cc}\\
\ce{CH3}\phantom{...........}\\
|\phantom{..............}\\
\ce{CH3 - C - CH2 - CH2 - NH2}\\
|\phantom{..............}\\
\ce{CH3\phantom{...........}}
\end{array}\]

Exercises | Q 4.1 | Page 297

Answer the following.

Write the IUPAC name of the following amine :

\[\begin{array}{cc}\\
\ce{CH3 - CH - NH - CH2 - CH3}\\
|\phantom{...............}\\
\ce{CH3\phantom{............}}
\end{array}\]

Exercises | Q 4.2 | Page 297

What are amines?

Exercises | Q 4.2 | Page 297

How are amines classified?

Exercises | Q 4.3 | Page 297

Answer the following.

Write the IUPAC name of the following amine.

H2N-(CH2)6 - NH2

Exercises | Q 4.3 | Page 297

Answer the following.

Write the IUPAC name of the following amine.

Exercises | Q 4.3 | Page 297

Answer the following.

Write the IUPAC name of the following amine.

Exercises | Q 4.4 | Page 297

Write reactions to prepare ethanamine from Acetonitrile.

Exercises | Q 4.4 | Page 297

Answer the following.

Write a reaction to prepare ethanamine from Nitroethane

Exercises | Q 4.4 | Page 297

Answer the following.

Write a reaction to prepare ethanamine from Propionamide.

Exercises | Q 4.5 | Page 297

Answer the following.

What is the action of acetic anhydride on ethylamine?

Exercises | Q 4.5 | Page 297

Answer the following.

What is the action of acetic anhydride on diethylamine?

Exercises | Q 4.5 | Page 297

Answer the following.

What is the action of acetic anhydride on triethylamine?

Exercises | Q 4.6 | Page 297

Distinguish between ethylamine, diethylamine, and triethylamine by using Hinsberg’s reagent?

Exercises | Q 4.7 | Page 297

Answer the following.

Write a reaction to bring about the following conversions: Aniline into p-nitroaniline

Exercises | Q 4.7 | Page 297

Answer the following.

Write a reaction to bring about the following conversions: Aniline into sulphanilic acid?

Solutions for 13: Amines

Exercises
Balbharati solutions for Chemistry [English] 12 Standard HSC chapter 13 - Amines - Shaalaa.com

Balbharati solutions for Chemistry [English] 12 Standard HSC chapter 13 - Amines

Shaalaa.com has the Maharashtra State Board Mathematics Chemistry [English] 12 Standard HSC Maharashtra State Board solutions in a manner that help students grasp basic concepts better and faster. The detailed, step-by-step solutions will help you understand the concepts better and clarify any confusion. Balbharati solutions for Mathematics Chemistry [English] 12 Standard HSC Maharashtra State Board 13 (Amines) include all questions with answers and detailed explanations. This will clear students' doubts about questions and improve their application skills while preparing for board exams.

Further, we at Shaalaa.com provide such solutions so students can prepare for written exams. Balbharati textbook solutions can be a core help for self-study and provide excellent self-help guidance for students.

Concepts covered in Chemistry [English] 12 Standard HSC chapter 13 Amines are Classification of Amines, Nomenclature of Amines, Preparation of Amines, Physical Properties of Amines, Basicity of Amines, Chemical Properties of Amines, Reactions of Arene Diazonium Salts, Reaction with Arenesulfonyl Chloride, Electrophilic Aromatic Substitution in Aromatic Amines.

Using Balbharati Chemistry [English] 12 Standard HSC solutions Amines exercise by students is an easy way to prepare for the exams, as they involve solutions arranged chapter-wise and also page-wise. The questions involved in Balbharati Solutions are essential questions that can be asked in the final exam. Maximum Maharashtra State Board Chemistry [English] 12 Standard HSC students prefer Balbharati Textbook Solutions to score more in exams.

Get the free view of Chapter 13, Amines Chemistry [English] 12 Standard HSC additional questions for Mathematics Chemistry [English] 12 Standard HSC Maharashtra State Board, and you can use Shaalaa.com to keep it handy for your exam preparation.

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