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Chapters
2: Quantum Mechanical Model of Atom
▶ 3: Periodic Classification Of Elements
4: Hydrogen
5: Alkali and Alkaline Earth Metals
6: Gaseous State
7: Thermodynamics
8: Physical and Chemical Equilibrium
9: Solutions
10: Chemical bonding
11: Fundamentals of Organic Chemistry
12: Basic concept of organic reactions
13: Hydrocarbons
14: Haloalkanes and Haloarenes
15: Environmental Chemistry
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Solutions for Chapter 3: Periodic Classification Of Elements
Below listed, you can find solutions for Chapter 3 of Tamil Nadu Board of Secondary Education Samacheer Kalvi for Chemistry - Volume 1 and 2 [English] Class 11 TN Board.
Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 11 TN Board 3 Periodic Classification Of Elements Evaluation [Pages 93 - 97]
Choose the best Answer
What would be the IUPAC name for an element with the atomic number 222?
bibibiium
bididium
didibium
bibibium
The electronic configuration of the elements A and B are 1s2, 2s2, 2p6, 3s2 and 1s2, 2s2, 2p5 respectively. The formula of the ionic compound that can be formed between these elements is
AB
AB2
A2B
none of the above
The group of elements in which the differentiating electron enters the anti penultimate shell of atoms are called ________.
p-block elements
d-block elements
s-block elements
f-block elements
In which of the following options the order of arrangement does not agree with the variation of the property indicated against it?
I < Br < Cl < F (increasing electron gain enthalpy)
Li < Na < K < Rb (increasing metallic radius)
Al3+ < Mg2+ < Na+ < F− (increasing ionic size)
B < C < O < N (increasing first ionisation enthalpy)
Which of the following elements will have the highest electronegativity?
Chlorine
Nitrogen
Cesium
Fluorine
Various successive ionisation enthalpies (in kJ mol-1) of an element are given below.
IE1 | IE2 | IE3 | IE4 | IE5 |
577.5 | 1,810 | 2,750 | 11,580 | 14,820 |
The element is
phosphorus
Sodium
Aluminium
Silicon
In the third period the first ionization potential is of the order.
Na > Al > Mg > Si > P
Na < Al < Mg < Si < P
Mg > Na > Si > P > Al
Na < Al < Mg < P < Si
Identify the wrong statement.
Amongst the isoelectronic species, smaller the positive charge on cation, smaller is the ionic radius.
Amongst isoelectric species greater the negative charge on the anion, larger is the ionic radius.
Atomic radius of the elements increases as one moves down the first group of the periodic table.
Atomic radius of the elements decreases as one moves across from left to right in the 2nd period of the periodic table.
Which one of the following arrangements represent the correct order of least negative to most negative electron gain enthalpy
Al < O < C < Ca < F
Al < Ca < O < C < F
C < F < O < Al < Ca
Ca < Al < C < O < F
The correct order of electron gain enthalpy with negative sign of F, Cl, Br and I having atomic number 9, 17, 35 and 53 respectively is
I > Br > Cl > F
F > Cl > Br > I
Cl > F > Br > I
Br > I > Cl > F
Which one of the following is the least electronegative element?
Bromine
Chlorine
Iodine
Hydrogen
The element with positive electron gain enthalpy is
Hydrogen
Sodium
Argon
Fluorine
The correct order of decreasing electronegativity values among the elements X, Y, Z and A with atomic numbers 4, 8, 7 and 12 respectively
Y > Z > X > A
Z > A > Y > X
X > Y > Z > A
X > Y > A > Z
Assertion: Helium has the highest value of ionisation energy among all the elements known
Reason: Helium has the highest value of electron affinity among all the elements known
Both assertion and reason are true and reason is correct explanation for the assertion
Both assertion and reason are true but the reason is not the correct explanation for the assertion
Assertion is true and the reason is false
Both assertion and the reason are false
The electronic configuration of the atom having maximum difference in first and second ionisation energies is
1s2, 2s2, 2p6, 3s1
1s2, 2s2, 2p6, 3s2
1s2, 2s2, 2p6, 3s2, 3s2, 3p6, 4s1
1s2, 2s2, 2p6, 3s2, 3p1
Which of the following is the second most electronegative element?
Chlorine
Fluorine
Oxygen
Sulphur
IE1 and IE2 of Mg are 179 and 348 kcal mol−1 respectively. The energy required for the reaction \[\ce{Mg -> Mg^2+ + 2e^-}\] is
+ 169 kcal mol−1
− 169 kcal mol−1
+ 527 kcal mol−1
− 527 kcal mol−1
In a given shell the order of screening effect is
s > p > d > f
s > p > f > d
f > d > p > s
f > p > s > d
Which of the following orders of ionic radii is correct?
H− > H+ > H
Na+ > F− > O2−
F > O2− > Na+
None of these
The First ionisation potential of Na, Mg and Si are 496, 737 and 786 kJ mol-1 respectively. The ionisation potential of Al will be closer to
760 kJ mol-1
575 kJ mol-1
801 kJ mol-1
419 kJ mol-1
Which one of the following is true about metallic character when we move from left to right in a period and top to bottom in a group?
Decreases in a period and increases along the group
Increases in a period and decreases in a group
Increases both in the period and the group
Decreases both in the period and in the group
How does electron affinity change when we move from left to right in a period in the periodic table?
Generally increases
Generally decreases
Remains unchanged
First increases and then decreases
Which of the following pairs of elements exhibit diagonal relationship?
Be and Mg
Li and Be
Be and B
Be and Al
Write brief answer to the following questions
Define modern periodic law.
What are isoelectronic ions? Give examples.
What is the effective nuclear charge?
Is the definition given below for ionisation enthalpy is correct?
"Ionisation enthalpy is defined as the energy required to remove the most loosely bound electron from the valence shell of an atom"
Magnesium loses electrons successively to form Mg+, Mg2+ and Mg3+ ions. Which step will have the highest ionisation energy and why?
Define electronegativity.
How would you explain the fact that the second ionisation potential is always higher than the first ionisation potential?
Energy of an electron in the ground state of the hydrogen atom is −2.18 × 10−18 J. Calculate the ionisation enthalpy of atomic hydrogen in terms of kJ mol−1.
The electronic configuration of atom is one of the important factor which affects the value of ionisation potential and electron gain enthalpy. Explain
In what period and group will an element with Z = 118 will be present?
Justify that the fifth period of the periodic table should have 18 elements on the basis of quantum numbers.
Elements a, b, c and d have the following electronic configurations:
- a: 1s2, 2s2, 2p6
- b: 1s2, 2s2, 2p6, 3s2, 3p1
- c: 1s2, 2s2, 2p6, 3s2, 3p6
- d: 1s2, 2s2, 2p1
Which elements among these will belong to the same group of the periodic table
Give the general electronic configuration of lanthanides and actinides?
Why do halogens act as oxidising agents?
Mention any two anomalous properties of second period elements.
Explain the Pauling method for the determination of ionic radius.
Explain the periodic trend of ionisation potential.
Explain the diagonal relationship.
Why the first ionisation enthalpy of sodium is lower than that of magnesium while its second ionisation enthalpy is higher than that of magnesium?
By using Pauling's method calculate the ionic radii of K+ and Cl− ions in the potassium chloride crystal. Given that `"d"_("K"^+) - "Cl"^-` = 3.14 Å
Explain the following, give an appropriate reason.
Ionisation potential of N is greater than that of O
Explain the following, give an appropriate reason.
First ionisation potential of the C-atom is greater than that of the B atom, whereas the reverse is true is for the second ionisation potential.
Explain the following, give an appropriate reason.
The electron affinity values of Be and Mg are almost zero and those of N (0.02 eV) and P (0.80 eV) are very low.
Explain the following, give an appropriate reason.
The formation of \[\ce{F^-_{(g)}}\] from \[\ce{F_{(g)}}\] is exothermic while that of \[\ce{O^2-_{(g)}}\] from \[\ce{O_{(g)}}\] is endothermic.
What is the screening effect?
Briefly give the basis for Pauling's scale of electronegativity.
State the trends in the variation of electronegativity in groups and periods.
Solutions for 3: Periodic Classification Of Elements
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Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 11 TN Board chapter 3 - Periodic Classification Of Elements
Shaalaa.com has the Tamil Nadu Board of Secondary Education Mathematics Chemistry - Volume 1 and 2 [English] Class 11 TN Board Tamil Nadu Board of Secondary Education solutions in a manner that help students grasp basic concepts better and faster. The detailed, step-by-step solutions will help you understand the concepts better and clarify any confusion. Samacheer Kalvi solutions for Mathematics Chemistry - Volume 1 and 2 [English] Class 11 TN Board Tamil Nadu Board of Secondary Education 3 (Periodic Classification Of Elements) include all questions with answers and detailed explanations. This will clear students' doubts about questions and improve their application skills while preparing for board exams.
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Concepts covered in Chemistry - Volume 1 and 2 [English] Class 11 TN Board chapter 3 Periodic Classification Of Elements are Introduction to Periodic Classification of Elements, Classification of Elements, Moseley's Work and Modern Periodic Law, Nomenclature of Elements with Atomic Number Greater than 100, Grouping of Elements Based on Electronic Configurations, Periodic Trends in Properties, Periodic Trends in Chemical Properties.
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