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Tamil Nadu Board of Secondary EducationHSC Science Class 11

Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 11 TN Board chapter 3 - Periodic Classification Of Elements [Latest edition]

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Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 11 TN Board chapter 3 - Periodic Classification Of Elements - Shaalaa.com
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Solutions for Chapter 3: Periodic Classification Of Elements

Below listed, you can find solutions for Chapter 3 of Tamil Nadu Board of Secondary Education Samacheer Kalvi for Chemistry - Volume 1 and 2 [English] Class 11 TN Board.


Evaluation
Evaluation [Pages 93 - 97]

Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 11 TN Board 3 Periodic Classification Of Elements Evaluation [Pages 93 - 97]

Choose the best Answer

Evaluation | Q I. 1. | Page 93

What would be the IUPAC name for an element with the atomic number 222?

  • bibibiium

  • bididium

  • didibium

  • bibibium

Evaluation | Q I. 2. | Page 93

The electronic configuration of the elements A and B are 1s2, 2s2, 2p6, 3s2 and 1s2, 2s2, 2p5 respectively. The formula of the ionic compound that can be formed between these elements is

  • AB

  • AB2

  • A2B

  • none of the above

Evaluation | Q I. 3. | Page 93

The group of elements in which the differentiating electron enters the anti penultimate shell of atoms are called ________.

  • p-block elements

  • d-block elements

  • s-block elements

  • f-block elements

Evaluation | Q I. 4. | Page 93

In which of the following options the order of arrangement does not agree with the variation of the property indicated against it?

  • I < Br < Cl < F (increasing electron gain enthalpy)

  • Li < Na < K < Rb (increasing metallic radius)

  • Al3+ < Mg2+ < Na+ < F (increasing ionic size)

  • B < C < O < N (increasing first ionisation enthalpy)

Evaluation | Q I. 5. | Page 93

Which of the following elements will have the highest electronegativity?

  • Chlorine

  • Nitrogen

  • Cesium

  • Fluorine

Evaluation | Q I. 6. | Page 93

Various successive ionisation enthalpies (in kJ mol-1) of an element are given below.

IE1 IE2 IE3 IE4 IE5
577.5 1,810 2,750 11,580 14,820

The element is

  • phosphorus

  • Sodium

  • Aluminium

  • Silicon

Evaluation | Q I. 7. | Page 94

In the third period the first ionization potential is of the order.

  • Na > Al > Mg > Si > P

  • Na < Al < Mg < Si < P

  • Mg > Na > Si > P > Al

  • Na < Al < Mg < P < Si

Evaluation | Q I. 8. | Page 94

Identify the wrong statement.

  • Amongst the isoelectronic species, smaller the positive charge on cation, smaller is the ionic radius.

  • Amongst isoelectric species greater the negative charge on the anion, larger is the ionic radius.

  • Atomic radius of the elements increases as one moves down the first group of the periodic table.

  • Atomic radius of the elements decreases as one moves across from left to right in the 2nd period of the periodic table.

Evaluation | Q I. 9. | Page 94

Which one of the following arrangements represent the correct order of least negative to most negative electron gain enthalpy

  • Al < O < C < Ca < F

  • Al < Ca < O < C < F

  • C < F < O < Al < Ca

  • Ca < Al < C < O < F

Evaluation | Q I. 10. | Page 94

The correct order of electron gain enthalpy with negative sign of F, Cl, Br and I having atomic number 9, 17, 35 and 53 respectively is

  • I > Br > Cl > F

  • F > Cl > Br > I

  • Cl > F > Br > I

  • Br > I > Cl > F

Evaluation | Q I. 11. | Page 94

Which one of the following is the least electronegative element?

  • Bromine

  • Chlorine

  • Iodine

  • Hydrogen

Evaluation | Q I. 12. | Page 94

The element with positive electron gain enthalpy is

  • Hydrogen

  • Sodium

  • Argon

  • Fluorine

Evaluation | Q I. 13. | Page 94

The correct order of decreasing electronegativity values among the elements X, Y, Z and A with atomic numbers 4, 8, 7 and 12 respectively

  • Y > Z > X > A

  • Z > A > Y > X

  • X > Y > Z > A

  • X > Y > A > Z

Evaluation | Q I. 14. | Page 95

Assertion: Helium has the highest value of ionisation energy among all the elements known

Reason: Helium has the highest value of electron affinity among all the elements known

  • Both assertion and reason are true and reason is correct explanation for the assertion

  • Both assertion and reason are true but the reason is not the correct explanation for the assertion

  • Assertion is true and the reason is false

  • Both assertion and the reason are false

Evaluation | Q I. 15. | Page 95

The electronic configuration of the atom having maximum difference in first and second ionisation energies is

  • 1s2, 2s2, 2p6, 3s1

  • 1s2, 2s2, 2p6, 3s2

  • 1s2, 2s2, 2p6, 3s2, 3s2, 3p6, 4s1

  • 1s2, 2s2, 2p6, 3s2, 3p1

Evaluation | Q I. 16. | Page 95

Which of the following is the second most electronegative element?

  • Chlorine

  • Fluorine

  • Oxygen

  • Sulphur

Evaluation | Q I. 17. | Page 95

IE1 and IE2 of Mg are 179 and 348 kcal mol−1 respectively. The energy required for the reaction \[\ce{Mg -> Mg^2+ + 2e^-}\] is

  • + 169 kcal mol−1

  • − 169 kcal mol−1

  • + 527 kcal mol−1

  • − 527 kcal mol−1

Evaluation | Q I. 18. | Page 95

In a given shell the order of screening effect is

  • s > p > d > f

  • s > p > f > d

  • f > d > p > s

  • f > p > s > d

Evaluation | Q I. 19. | Page 95

Which of the following orders of ionic radii is correct?

  • H > H+ > H

  • Na+ > F > O2−

  • F > O2− > Na+

  • None of these

Evaluation | Q I. 20. | Page 95

The First ionisation potential of Na, Mg and Si are 496, 737 and 786 kJ mol-1 respectively. The ionisation potential of Al will be closer to

  • 760 kJ mol-1

  • 575 kJ mol-1

  • 801 kJ mol-1

  • 419 kJ mol-1

Evaluation | Q I. 21. | Page 96

Which one of the following is true about metallic character when we move from left to right in a period and top to bottom in a group?

  • Decreases in a period and increases along the group

  • Increases in a period and decreases in a group

  • Increases both in the period and the group

  • Decreases both in the period and in the group

Evaluation | Q I. 22. | Page 96

How does electron affinity change when we move from left to right in a period in the periodic table?

  • Generally increases

  • Generally decreases

  • Remains unchanged

  • First increases and then decreases

Evaluation | Q I. 23. | Page 96

Which of the following pairs of elements exhibit diagonal relationship?

  • Be and Mg

  • Li and Be

  • Be and B

  • Be and Al

Write brief answer to the following questions

Evaluation | Q II. 1. | Page 96

Define modern periodic law.

Evaluation | Q II. 2. | Page 96

What are isoelectronic ions? Give examples.

Evaluation | Q II. 3. | Page 96

What is the effective nuclear charge?

Evaluation | Q II. 4. | Page 96

Is the definition given below for ionisation enthalpy is correct?

"Ionisation enthalpy is defined as the energy required to remove the most loosely bound electron from the valence shell of an atom"

Evaluation | Q II. 5. | Page 96

Magnesium loses electrons successively to form Mg+, Mg2+ and Mg3+ ions. Which step will have the highest ionisation energy and why?

Evaluation | Q II. 6. | Page 96

Define electronegativity.

Evaluation | Q II. 7. | Page 96

How would you explain the fact that the second ionisation potential is always higher than the first ionisation potential?

Evaluation | Q II. 8. | Page 96

Energy of an electron in the ground state of the hydrogen atom is −2.18 × 10−18 J. Calculate the ionisation enthalpy of atomic hydrogen in terms of kJ mol−1.

Evaluation | Q II. 9. | Page 96

The electronic configuration of atom is one of the important factor which affects the value of ionisation potential and electron gain enthalpy. Explain

Evaluation | Q II. 10. | Page 96

In what period and group will an element with Z = 118 will be present?

Evaluation | Q II. 11. | Page 97

Justify that the fifth period of the periodic table should have 18 elements on the basis of quantum numbers.

Evaluation | Q II. 12. | Page 97

Elements a, b, c and d have the following electronic configurations:

  • a: 1s2, 2s2, 2p6
  • b: 1s2, 2s2, 2p6, 3s2, 3p1
  • c: 1s2, 2s2, 2p6, 3s2, 3p6
  • d: 1s2, 2s2, 2p1

Which elements among these will belong to the same group of the periodic table

Evaluation | Q II. 13. | Page 97

Give the general electronic configuration of lanthanides and actinides?

Evaluation | Q II. 14. | Page 97

Why do halogens act as oxidising agents?

Evaluation | Q II. 15. | Page 97

Mention any two anomalous properties of second period elements.

Evaluation | Q II. 16. | Page 97

Explain the Pauling method for the determination of ionic radius.

Evaluation | Q II. 17. | Page 97

Explain the periodic trend of ionisation potential.

Evaluation | Q II. 18. | Page 97

Explain the diagonal relationship.

Evaluation | Q II. 19. | Page 97

Why the first ionisation enthalpy of sodium is lower than that of magnesium while its second ionisation enthalpy is higher than that of magnesium?

Evaluation | Q II. 20. | Page 97

By using Pauling's method calculate the ionic radii of K+ and Cl ions in the potassium chloride crystal. Given that `"d"_("K"^+) - "Cl"^-` = 3.14 Å

Evaluation | Q II. 21. (i) | Page 97

Explain the following, give an appropriate reason.

Ionisation potential of N is greater than that of O

Evaluation | Q II. 21. (ii) | Page 97

Explain the following, give an appropriate reason.

First ionisation potential of the C-atom is greater than that of the B atom, whereas the reverse is true is for the second ionisation potential.

Evaluation | Q II. 21. (iii) | Page 97

Explain the following, give an appropriate reason.

The electron affinity values of Be and Mg are almost zero and those of N (0.02 eV) and P (0.80 eV) are very low.

Evaluation | Q II. 21. (iv) | Page 97

Explain the following, give an appropriate reason.

The formation of \[\ce{F^-_{(g)}}\] from \[\ce{F_{(g)}}\] is exothermic while that of \[\ce{O^2-_{(g)}}\] from \[\ce{O_{(g)}}\] is endothermic.

Evaluation | Q II. 22. | Page 97

What is the screening effect?

Evaluation | Q II. 23. | Page 97

Briefly give the basis for Pauling's scale of electronegativity.

Evaluation | Q II. 24. | Page 97

State the trends in the variation of electronegativity in groups and periods.

Solutions for 3: Periodic Classification Of Elements

Evaluation
Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 11 TN Board chapter 3 - Periodic Classification Of Elements - Shaalaa.com

Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 11 TN Board chapter 3 - Periodic Classification Of Elements

Shaalaa.com has the Tamil Nadu Board of Secondary Education Mathematics Chemistry - Volume 1 and 2 [English] Class 11 TN Board Tamil Nadu Board of Secondary Education solutions in a manner that help students grasp basic concepts better and faster. The detailed, step-by-step solutions will help you understand the concepts better and clarify any confusion. Samacheer Kalvi solutions for Mathematics Chemistry - Volume 1 and 2 [English] Class 11 TN Board Tamil Nadu Board of Secondary Education 3 (Periodic Classification Of Elements) include all questions with answers and detailed explanations. This will clear students' doubts about questions and improve their application skills while preparing for board exams.

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Concepts covered in Chemistry - Volume 1 and 2 [English] Class 11 TN Board chapter 3 Periodic Classification Of Elements are Introduction to Periodic Classification of Elements, Classification of Elements, Moseley's Work and Modern Periodic Law, Nomenclature of Elements with Atomic Number Greater than 100, Grouping of Elements Based on Electronic Configurations, Periodic Trends in Properties, Periodic Trends in Chemical Properties.

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