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Chapters
2: Quantum Mechanical Model of Atom
3: Periodic Classification Of Elements
4: Hydrogen
5: Alkali and Alkaline Earth Metals
6: Gaseous State
7: Thermodynamics
8: Physical and Chemical Equilibrium
9: Solutions
▶ 10: Chemical bonding
11: Fundamentals of Organic Chemistry
12: Basic concept of organic reactions
13: Hydrocarbons
14: Haloalkanes and Haloarenes
15: Environmental Chemistry
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Solutions for Chapter 10: Chemical bonding
Below listed, you can find solutions for Chapter 10 of Tamil Nadu Board of Secondary Education Samacheer Kalvi for Chemistry - Volume 1 and 2 [English] Class 11 TN Board.
Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 11 TN Board 10 Chemical bonding Evaluation [Pages 104 - 107]
Choose the best answer
In which of the following Compounds does the central atom obey the octet rule?
XeF4
AlCl3
SF6
SCl2
In the molecule OA = C = OB, the formal charge on OA, C and OB are respectively.
-1, 0, +1
+1, 0, -1
-2, 0, +2
0, 0, 0
Which of the following is electron deficient?
PH3
(CH3)2
BH3
NH3
Which of the following molecule contain no л bond?
SO2
SO2
CO2
H2O
The ratio of number of sigma (σ) and pi (л) bonds in 2- butynal is ______.
`8/3`
`5/3`
`8/2`
`9/2`
Which one of the following is the likely bond angles of sulphur tetrafluoride molecule?
120°, 80°
109°28’
90°
89°, 117°
Assertion: Oxygen molecule is paramagnetic.
Reason: It has two unpaired electron in its bonding molecular orbital.
Both assertion and reason are true and reason is the correct explanation of assertion
Both assertion and reason are true but reason is not the correct explanation of assertion
Assertion is true but reason is false
Both assertion and reason are false
According to Valence bond theory, a bond between two atoms is formed when ______.
fully filled atomic orbitals overlap
half-filled atomic orbitals overlap
non – bonding atomic orbitals overlap
empty atomic orbitals overlap
In ClF3, NF3 and BF3 molecules the chlorine, nitrogen and boron atoms are ______.
sp3 hybridised
sp3, sp3 and sp2 respectively
sp3 hybridised
sp3d, sp3 and sp hybridised respectively
When ones and three p orbitals hybridise,
four equivalent orbitals at 90° to each other will be formed
four equivalent orbitals at 109°28’ to each other will be formed
four equivalent orbitals, that are lying the same plane will be formed
none of these
Which of these represents the correct order of their increasing bond order.
C2+ < C22- < O22- < O2
C22- < C2+ < O2 < O22-
O22- < O2 < C22- < C2+
O22- < C2+ < O2 < C22-
Hybridisation of central atom in PCl5 involves the mixing of orbitals.
s, Px, Py, dx2, `"d"_("x"^2 – "y"^2)`
s, px, py, pxy, `"d"_("x"^2 – "y"^2)`
s, px, py, pz, `"d"_("x"^2 – "y"^2)`
s, px, Py, dxy, `"d"_("x"^2 – "y"^2)`
The correct order of O – O bond length in hydrogen peroxide, ozone and oxygen is
H2O2 > O3 > O2
O2 > O3 > H2O2
O2 > H2O2 > O3
O3 > O2 > H2O2
Which one of the following is diamagnetic?
O2
O22-
O2+
None of these
Bond order of a species is 2.5 and the number of electons in its bonding molecular orbital is formd to be 8 The no. of electons in its antibonding molecular orbital is
three
four
Zero
can not be calculated from the given information.
Shape and hybridisation of IF5 are ______.
Trigonal bipyramidal, sp3d2
Trigonal bipyramidal, sp3d
Square pyramidal, sp3d2
Octahedral, sp3d2
Pick out the incorrect statement from the following:
sp3 hybrid orbitals are equivalent and are at an angle of 109°28’ with each other
dsp2 hybrid orbitals are equivalent and bond angle between any two of them is 90°
All five sp3d hybrid orbitals are not equivalent out of these five sp3d hybrid orbitals, three are at an angle of 120° remaining two are perpendicular to the plane containing the other three
none of these
The molecules having same hybridisation, shape and number of lone pairs of electons are ______.
SeF4, XeO2F2
SF4, XeF2
XeOF4, TeF4
SeCl4, XeF4
In which of the following molecules / ions BF3, NO2– H20 the central atom is sp2 hybridised?
NH2– and H2O
NO2– and H2O
BF3 and NO2–
BF3 and NH2–
Some of the following properties of two species, NO3– and H3O+ are described below. Which one of them is correct?
dissimilar in hybridization for the central atom with different structure.
isostructural with same hybridisation for the central atom.
different hybridisation for the central atom with same structure.
none of these
The types of hybridiration on the five carbon atom from right to left in the, 2,3 pentadiene.
sp3, sp2, sp, sp2, sp3
sp3, sp, sp, sp, sp3
sp2, sp, sp2, sp2, sp3
sp3, sp3, sp2, sp3, sp3
XeF2 is isostructural with ______.
SbCl2
BaCl2
TeF2
ICl2–
The percentage of s-character of the hybrid orbitals in methane, ethane, ethene and ethyne are respectively.
25, 25, 33.3, 50
50, 50, 33.3, 25
50, 25, 33.3, 50
50, 25, 25, 50
Of the following molecules, which have shape similar to carbon dioxide?
SnCl2
NO2
C2H2
All of these
According to VSEPR theory, the repulsion between different parts of electrons obey the order.
l.p – l.p > b.p–b.p> l.p–b.p
b.p–b.p> b.p–l.p> l.p–b.p
l.p–l.p> b.p–l.p > b.p–b.p
b.p–b.p> l.p–l.p> b.p–l.p
Shape of ClF3 is ______.
Planar triangular
Pyramidal
"T” Shaped
none of these
Non – Zero dipole moment is shown by ______.
CO2
p – dichlorobenzene
carbon tetrachloride
water
Which of the following conditions is not correct for resonating structures?
the contributing structure must have the same number of unpaired electrons
the contributing structures should have similar energies
the resonance hybrid should have higher energy than any of the contributing structure.
none of these
Among the following, the compound that contains, ionic, covalent and Coordinate linkage is ______.
NH4Cl
NH3
NaCl
none of these
CaO and NaCl have the same crystal structure and approximately the same radii. If U is the lattice energy of NaCl, the approximate lattice energy of CaO is ______.
U
2U
`"U"/2`
4U
Write brief answer to the following questions.
Define bond order.
Define Hybridisation.
Define σ – bond.
What is a pi - bond?
In CH4, NH3, and H2O, the central atom undergoes sp3 hybridization – yet their bond angles are different. Why?
Explain Sp2 hybridization in BF3.
Draw the M.O diagram for oxygen molecule calculate its bond order and show that O2 is paramagnetic.
Draw MO diagram of CO and calculate its bond order.
What do you understand by Linear combination of atomic orbitals in MO theory?
Discuss the formation of N2 molecule using MO Theory.
What is dipole moment?
Linear form of carbondioxide molecule has two polar bonds. Yet the molecule has Zero dipole moment. Why?
Draw the Lewis structure for the following species.
\[\ce{NO^-3}\]
Draw the Lewis structure for the following species.
\[\ce{SO^{2-}4}\]
Draw the Lewis structure for the following species.
HNO3
Draw the Lewis structure for the following species.
O3
Explain the bond formation if BeCl2 and MgCl2.
Which bond is stronger σ or π? Why?
Define bond energy.
Hydrogen gas is diatomic whereas inert gases are monoatomic – Explain on the basis of MO theory.
What is the Polar Covalent bond?
Explain an example of a Polar Covalent bond.
Considering x-axis as the molecular axis which out of the following will form a sigma bond.
1s and 2py
Considering x-axis as the molecular axis which out of the following will form a sigma bond.
2px and 2py
Considering x-axis as the molecular axis which out of the following will form a sigma bond.
2px and 2pz
Considering x-axis as the molecular axis which out of the following will form a sigma bond.
1s and 2pz
Explain resonance with reference to a carbonate ion.
Explain the bond formation in ethylene.
Explain the bond formation in acetylene.
What type of hybridisation is possible in the following geometeries?
octahedral
What type of hybridisation is possible in the following geometeries?
tetrahedral
What type of hybridisation is possible in the following geometeries?
square planer
Explain VSEPR theory. Applying this theory to predict the shapes of IF7 and SF6.
CO2 and H2O both are triatomic molecule but their dipole moment values are different. Why?
Which one of the following has the highest bond order?
- N2
- N2+
- N2–
Explain the covalent character in ionic bond.
Describe Fajan’s rule.
Solutions for 10: Chemical bonding
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Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 11 TN Board chapter 10 - Chemical bonding
Shaalaa.com has the Tamil Nadu Board of Secondary Education Mathematics Chemistry - Volume 1 and 2 [English] Class 11 TN Board Tamil Nadu Board of Secondary Education solutions in a manner that help students grasp basic concepts better and faster. The detailed, step-by-step solutions will help you understand the concepts better and clarify any confusion. Samacheer Kalvi solutions for Mathematics Chemistry - Volume 1 and 2 [English] Class 11 TN Board Tamil Nadu Board of Secondary Education 10 (Chemical bonding) include all questions with answers and detailed explanations. This will clear students' doubts about questions and improve their application skills while preparing for board exams.
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Concepts covered in Chemistry - Volume 1 and 2 [English] Class 11 TN Board chapter 10 Chemical bonding are Introduction of Chemical Bonding, Types of Chemical Bonds, Ionic or Electrovalent Bond, Coordinate Covalent Bond, Bond Parameters, Valence Shell Electron Pair Repulsion Theory (VSEPR), Valence Bond Theory, Valence Bond Theory - Orbital Overlap Concept, Hybridisation - Introduction, Molecular Orbital Theory.
Using Samacheer Kalvi Chemistry - Volume 1 and 2 [English] Class 11 TN Board solutions Chemical bonding exercise by students is an easy way to prepare for the exams, as they involve solutions arranged chapter-wise and also page-wise. The questions involved in Samacheer Kalvi Solutions are essential questions that can be asked in the final exam. Maximum Tamil Nadu Board of Secondary Education Chemistry - Volume 1 and 2 [English] Class 11 TN Board students prefer Samacheer Kalvi Textbook Solutions to score more in exams.
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