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Tamil Nadu Board of Secondary EducationHSC Science Class 12

Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 12 TN Board chapter 3 - p-Block Elements - II [Latest edition]

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Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 12 TN Board chapter 3 - p-Block Elements - II - Shaalaa.com
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Solutions for Chapter 3: p-Block Elements - II

Below listed, you can find solutions for Chapter 3 of Tamil Nadu Board of Secondary Education Samacheer Kalvi for Chemistry - Volume 1 and 2 [English] Class 12 TN Board.


Evaluation
Evaluation [Pages 96 - 99]

Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 12 TN Board 3 p-Block Elements - II Evaluation [Pages 96 - 99]

Choose the best answer:

Evaluation | Q 1. | Page 96

In which of the following, NH3 is not used?

  • Nessler’s reagent

  • Reagent for the analysis of IV group basic radical

  • Reagent for the analysis of III group basic radical

  • Tollen’s reagent

Evaluation | Q 2. | Page 96

Which is true regarding nitrogen?

  • least electronegative element

  • has low ionisation enthalpy than oxygen

  • d-orbitals available

  • ability to form pπ − pπ bonds with itself

Evaluation | Q 3. | Page 96

An element belongs to group 15 and 3rd period of the periodic table, its electronic configuration would be

  • 1s2 2s2 2p4

  • 1s2 2s2 2p3

  • 1s2 2s2 2p6 3s2 3p2

  • 1s2 2s2 2p6 3s2 3p3

Evaluation | Q 4. | Page 96

Solid (A) reacts with strong aqueous NaOH liberating a foul smelling gas (B) which spontaneously burn in air giving smoky rings. A and B are respectively

  • P4 (red) and PH3

  • P4 (white) and PH3

  • S8 and H2S

  • P4 (white) and H2S

Evaluation | Q 5. | Page 96

On hydrolysis, PCl3 gives ____________.

  • H3PO3

  • PH3

  • H3PO4

  • POCl3

Evaluation | Q 6. | Page 96

P4O6 reacts with cold water to give ____________.

  • H3PO3

  • H4P2O7

  • HPO3

  • H3PO4

Evaluation | Q 7. | Page 96

The basicity of pyrophosphorous acid (H4P2O5) is ____________.

  • 4

  • 2

  • 3

  • 5

Evaluation | Q 8. | Page 97

The molarity of given orthophosphoric acid solution is 2M. its normality is ____________.

  • 6N

  • 4N

  • 2N

  • none of these

Evaluation | Q 9. | Page 97

Assertion: bond dissociation energy of fluorine is greater than chlorine gas

Reason: chlorine has more electronic repulsion than fluorine

  • Both assertion and reason are true and reason is the correct explanation of assertion.

  • Both assertion and reason are true but reason is not the correct explanation of assertion.

  • Assertion is true but reason is false.

  • Both assertion and reason are false.

Evaluation | Q 10. | Page 97

Among the following, which is the strongest oxidizing agent?

  • Cl2

  • F2

  • Br2

  • l2

Evaluation | Q 11. | Page 97

The correct order of the thermal stability of hydrogen halide is ____________.

  • HI > HBr > HCl > HF

  • HF > HCl > HBr > HI

  • HCl > HF > HBr > HI

  • HI > HCl > HF > HBr

Evaluation | Q 12. | Page 97

Which one of the following compounds is not formed?

  • XeOF4

  • XeO3

  • XeF2

  • NeF2

Evaluation | Q 13. | Page 97

Most easily liquefiable gas is ____________.

  • Ar

  • Ne

  • He

  • Kr

Evaluation | Q 14. | Page 97

XeF6 on complete hydrolysis produces ____________.

  • XeOF4

  • XeO2F2

  • XeO3

  • XeO2

Evaluation | Q 15. | Page 97

Which of the following is the strongest acid among all?

  • HI

  • HF

  • HBr

  • HCl

Evaluation | Q 16. | Page 98

Which one of the following orders is correct for the bond dissociation enthalpy of halogen molecules?

  • Br2 > I2 > F2 > Cl2

  • F2 > Cl2 > Br2 > l2

  • I2 > Br2 > Cl2 > F2

  • Cl2 > Br2 > F2 > I2

Evaluation | Q 17. | Page 98

Among the following the correct order of acidity is

  • HClO2 < HClO < HClO3 < HClO4

  • HClO4 < HClO2 < HClO < HClO3

  • HClO3 < HClO4 < HClO2 < HClO

  • HClO < HClO2 < HClO3 < HClO4

Evaluation | Q 18. | Page 98

When copper is heated with conc HNO3 it produces ____________.

  • Cu(NO3)2, NO and NO2

  • Cu(NO3)2 and N2O

  • Cu(NO3)2 and NO2

  • Cu(NO3)2 and NO

Answer the following questions:

Evaluation | Q 1. | Page 98

What is the inert pair effect?

Evaluation | Q 2. | Page 98

Chalcogens belongs to p-block. Give reason.

Evaluation | Q 3. | Page 98

Explain why fluorine always exhibit an oxidation state of −1?

Evaluation | Q 4. a) | Page 98

Give the oxidation state of halogen in the following.

OF2

Evaluation | Q 4. b) | Page 98

Give the oxidation state of halogen in the following.

O2F2

Evaluation | Q 4. c) | Page 98

Give the oxidation state of halogen in the following.

Cl2O3

Evaluation | Q 4. d) | Page 98

Give the oxidation state of halogen in the following.

I2O4

Evaluation | Q 5. | Page 98

What are interhalogen compounds? Give examples.

Evaluation | Q 6. | Page 98

Why fluorine is more reactive than other halogens?

Evaluation | Q 7. | Page 98

Give the uses of helium.

Evaluation | Q 8. | Page 98

What is the hybridisation of iodine in IF7? Give its structure.

Evaluation | Q 9. | Page 98

Give the balanced equation for the reaction between chlorine with cold NaOH and hot NaOH.

Evaluation | Q 10. | Page 98

How will you prepare chlorine in the laboratory?

Evaluation | Q 11. | Page 98

Give the uses of sulphuric acid.

Evaluation | Q 12. | Page 98

Give a reason to support that sulphuric acid is a dehydrating agent.

Evaluation | Q 13. | Page 98

Write the reason for the anomalous behaviour of Nitrogen.

Evaluation | Q 14. a) | Page 98

Write the molecular formula and structural formula for the following molecule.

Nitric acid

Evaluation | Q 14. b) | Page 98

Write the molecular formula and structural formula for the following molecule.

Dinitrogen pentoxide

Evaluation | Q 14. c) | Page 98

Write the molecular formula and structural formula for the following molecule.

Phosphoric acid

Evaluation | Q 14. d) | Page 98

Write the molecular formula and structural formula for the following molecule.

Phosphine

Evaluation | Q 15. | Page 99

Give the uses of argon.

Evaluation | Q 16. | Page 99

Write the valence shell electronic configuration of group-15 elements.

Evaluation | Q 17. | Page 99

Give two equations to illustrate the chemical behaviour of phosphine.

Evaluation | Q 18. | Page 99

Give a reaction between nitric acid and a basic oxide.

Evaluation | Q 19. | Page 99

What happens when PCl5 is heated?

Evaluation | Q 20. | Page 99

Suggest a reason why HF is a weak acid, whereas binary acids of all other halogens are strong acids.

Evaluation | Q 21. | Page 99

Deduce the oxidation number of oxygen in hypofluorous acid – HOF.

Evaluation | Q 22. a) | Page 99

What type of hybridisation occur in BrF5

Evaluation | Q 22. b) | Page 99

What type of hybridisation occur in BrF3

Evaluation | Q 23. 1. | Page 99

Complete the following reaction.

\[\ce{NaCl + MnO2 + H2SO4 ->}\]

Evaluation | Q 23. 2. | Page 99

Complete the following reaction.

\[\ce{NaNO2 + HCl ->}\]

Evaluation | Q 23. 3. | Page 99

Complete the following reaction.

\[\ce{P4 + NaOH + H2O ->}\]

Evaluation | Q 23. 4. | Page 99

Complete the following reaction.

\[\ce{AgNO3 + PH3 ->}\]

Evaluation | Q 23. 5. | Page 99

Complete the following reaction.

\[\ce{Mg + HNO3 ->}\]

Evaluation | Q 23. 6. | Page 99

Complete the following reaction.

\[\ce{KClO3 ->[\Delta]}\]

Evaluation | Q 23. 7. | Page 99

Complete the following reaction.

\[\ce{Cu + \underset{\text{(Hot conc)}}{H2SO4} ->}\]

Evaluation | Q 23. 8. | Page 99

Complete the following reaction.

\[\ce{Sb + Cl2 ->}\]

Evaluation | Q 23. 9. | Page 99

Complete the following reaction.

\[\ce{HBr + H2SO4 ->}\]

Evaluation | Q 23. 10. | Page 99

Complete the following reaction.

\[\ce{XeF6 + H2O ->}\]

Evaluation | Q 23. 11. | Page 99

Complete the following reaction.

\[\ce{XeO^4-_6 + Mn^2+ + H^+ ->}\]

Evaluation | Q 23. 12. | Page 99

Complete the following reaction.

\[\ce{XeOF4 + SiO2 ->}\]

Evaluation | Q 23. 13. | Page 99

Complete the following reaction.

\[\ce{Xe + F2 ->[Ni/200 atm][400°C]}\]

Solutions for 3: p-Block Elements - II

Evaluation
Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 12 TN Board chapter 3 - p-Block Elements - II - Shaalaa.com

Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 12 TN Board chapter 3 - p-Block Elements - II

Shaalaa.com has the Tamil Nadu Board of Secondary Education Mathematics Chemistry - Volume 1 and 2 [English] Class 12 TN Board Tamil Nadu Board of Secondary Education solutions in a manner that help students grasp basic concepts better and faster. The detailed, step-by-step solutions will help you understand the concepts better and clarify any confusion. Samacheer Kalvi solutions for Mathematics Chemistry - Volume 1 and 2 [English] Class 12 TN Board Tamil Nadu Board of Secondary Education 3 (p-Block Elements - II) include all questions with answers and detailed explanations. This will clear students' doubts about questions and improve their application skills while preparing for board exams.

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Concepts covered in Chemistry - Volume 1 and 2 [English] Class 12 TN Board chapter 3 p-Block Elements - II are Group 15 (Nitrogen Group) Elements, Group 16 (Oxygen Group) Elements, Oxygen, Group 17 (Halogen Group) Elements, Group 18 (Inert Gases) Elements.

Using Samacheer Kalvi Chemistry - Volume 1 and 2 [English] Class 12 TN Board solutions p-Block Elements - II exercise by students is an easy way to prepare for the exams, as they involve solutions arranged chapter-wise and also page-wise. The questions involved in Samacheer Kalvi Solutions are essential questions that can be asked in the final exam. Maximum Tamil Nadu Board of Secondary Education Chemistry - Volume 1 and 2 [English] Class 12 TN Board students prefer Samacheer Kalvi Textbook Solutions to score more in exams.

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