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Chapters
2: p-Block Elements - I
3: p-Block Elements - II
4: Transition and Inner Transition Elements
▶ 5: Coordination Chemistry
6: Solid State
7: Chemical Kinetics
8: Ionic Equilibrium
9: Electro Chemistry
10: Surface Chemistry
11: Hydroxy Compounds and Ethers
12: Carbonyl Compounds and Carboxylic Acids
13: Organic Nitrogen Compounds
14: Biomolecules
15: Chemistry in Everyday Life
![Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 12 TN Board chapter 5 - Coordination Chemistry - Shaalaa.com](/images/chemistry-volume-1-and-2-english-class-12-tn-board_6:5f2b1b2038084cf381bfa42c826a928c.jpg "Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 12 TN Board chapter 5 - Coordination Chemistry")
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Solutions for Chapter 5: Coordination Chemistry
Below listed, you can find solutions for Chapter 5 of Tamil Nadu Board of Secondary Education Samacheer Kalvi for Chemistry - Volume 1 and 2 [English] Class 12 TN Board.
Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 12 TN Board 5 Coordination Chemistry Evaluation [Pages 169 - 173]
Choose the correct answer:
The sum of primary valence and secondary valence of the metal M in the complex [M(en)2(Ox)]Cl is ____________.
3
6
−3
9
An excess of silver nitrate is added to 100 ml of a 0.01 M solution of pentaaquachloridochromium (III) chloride. The number of moles of AgCl precipitated would be
0.02
0.002
0.01
0.2
A complex has a molecular formula \[\ce{MSO4Cl.6H2O}\] The aqueous solution of it gives white precipitate with Barium chloride solution and no precipitate is obtained when it is treated with silver nitrate solution. If the secondary valence of the metal is six, which one of the following correctly represents the complex?
\[\ce{[M(H2O)4Cl]SO4.2H2O}\]
\[\ce{[M(H2O)6]SO4}\]
\[\ce{[M(H2O)5Cl]SO4.H2O}\]
\[\ce{[M(H2O)3Cl]SO4.3H2O}\]
Oxidation state of Iron and the charge on the ligand NO in [Fe(H2O)5NO]SO4 are ____________.
+2 and 0 respectively
+3 and 0 respectively
+3 and −1 respectively
+1 and +1 respectively
As per IUPAC guidelines, the name of the complex [Co(en)2(ONO)Cl]Cl is
chlorobisethylenediaminenitritocobalt (III) chloride
chloridobis (ethane-1, 2-diamine) nitro κ-Ocobaltate (III) chloride
chloridobis (ethane-1, 2-diammine) nitrito κ-Ocobalt (II) chloride
chloridobis (ethane-1, 2-diammine) nitrito κ-Ocobalt (III) chloride
IUPAC name of the complex K3[Al(C2O4)3] is ____________.
potassiumtrioxalatoaluminium (III)
potassiumtrioxalatoaluminate (II)
potassiumtrisoxalatoaluminate (III)
potassiumtrioxalatoaluminate (III)
A magnetic moment of 1.73 BM will be shown by one among the following
\[\ce{TiCl4}\]
\[\ce{[CoCl_{6-}]^{4-}}\]
\[\ce{[Cu(NH3)4]^2+}\]
\[\ce{[Ni(CN)4]^2-}\]
Crystal field stabilization energy for high spin d5 octahedral complex is ____________.
−0.6Δ0
0
2(P − Δ0)
2(P + Δ0)
In which of the following coordination entities the magnitude of Δ0 will be maximum?
\[\ce{[Co(CN)6]^3-}\]
\[\ce{[Co(C2O4)3]^3-}\]
\[\ce{[Co(H2O)6]^3+}\]
\[\ce{[Co(NH3)6]^3+}\]
Which one of the following will give a pair of enantiomorphs?
\[\ce{[Cr(NH3)6] [Co(CN)6]}\]
\[\ce{[Co(en)2Cl2]Cl}\]
\[\ce{[Pt(NH3)4] [PtCl4]}\]
\[\ce{[Co(NH3)4Cl2]NO2}\]
Which type of isomerism is exhibited by [Pt(NH3)2Cl2]?
Coordination isomerism
Linkage isomerism
Optical isomerism
Geometrical isomerism
How many geometrical isomers are possible for \[\ce{[Pt(Py)(NH3)(Br)(Cl)]}\]?
3
4
0
15
Which one of the following pairs represents linkage isomers?
\[\ce{[Cu(NH3)4] [PtCl4]}\] and \[\ce{[Pt(NH3)4] [CuCl4]}\]
\[\ce{[Co(NH3)5 (NO3)]SO4}\] and \[\ce{[Co(NH3)5 (ONO)]}\]
\[\ce{[Co(NH3)4 (NCS)2]Cl}\] and \[\ce{[Co(NH3)4 (SCN)2]Cl}\]
both \[\ce{[Co(NH3)5 (NO3)]SO4}\] and \[\ce{[Co(NH3)5 (ONO)]}\] and \[\ce{[Co(NH3)4 (NCS)2]Cl}\] and \[\ce{[Co(NH3)4 (SCN)2]Cl}\]
Which kind of isomerism is possible for a complex [Co(NH3)4Br2]Cl?
geometrical and ionization
geometrical and optical
optical and ionization
geometrical only
Which one of the following complexes is not expected to exhibit isomerism?
\[\ce{[Ni(NH3)4 (H2O)2]^2+}\]
\[\ce{[Pt(NH3)2 Cl2]}\]
\[\ce{[Co(NH3)5 SO4]Cl}\]
\[\ce{[FeCl6]^3-}\]
A complex in which the oxidation number of the metal is zero is ____________.
K4[Fe(CN)6]
[Fe(CN)3(NH3)3]
[Fe(CO)5]
both [Fe(CN)3(NH3)3] and [Fe(CO)5]
Formula of tris (ethane-1, 2-diamine) iron (II) phosphate
\[\ce{[Fe(CH3-CH(NH2)2)3] (PO4)3}\]
\[\ce{[Fe(H2N-CH2-CH2-NH2)3] (PO4)}\]
\[\ce{[Fe(H2N-CH2-CH2-NH2)3] (PO4)2}\]
\[\ce{[Fe(H2N-CH2-CH2-NH2)3]3 (PO4)2}\]
Which of the following is paramagnetic in nature?
\[\ce{[Zn(NH3)4]^2+}\]
\[\ce{[Co(NH3)6]^3+}\]
\[\ce{[Ni(H2O)6]^2+}\]
\[\ce{[Ni(CN)4]^2-}\]
Fac-mer isomerism is shown by
\[\ce{[Co(en)3]^3+}\]
\[\ce{[Co(NH3)4 (Cl)2]^+}\]
\[\ce{[Co(NH3)3 (Cl)3]}\]
\[\ce{[Co(NH3)5 Cl]SO4}\]
Choose the correct statement.
Square planar complexes are more stable than octahedral complexes
The spin only magnetic moment of \[\ce{[Cu(Cl)4]^2-}\] is 1.732 BM and it has square planar structure.
Crystal field splitting energy (Δ0) of \[\ce{[FeF6]^4-}\] is higher than the (Δ0) of \[\ce{[Fe(CN)6]^4-}\]
Crystal field stabilization energy of \[\ce{[V(H2O)6]^2+}\] is higher than the crystal field stabilization of \[\ce{[Ti(H2O)6]^2+}\]
Answer the following questions:
Write the IUPAC name for the following complex.
\[\ce{Na2[Ni(EDTA)]}\]
Write the IUPAC name for the following complex.
\[\ce{[Ag(CN)2]^-}\]
Write the IUPAC name for the following complex.
\[\ce{[Co(en)3]2 (SO4)3}\]
Write the IUPAC name for the following complex.
\[\ce{[Co(ONO) (NH3)5]^2+}\]
Write the IUPAC name for the following complex.
\[\ce{[Pt(NH3)2 Cl(NO2)]}\]
Write the formula for the following coordination compound.
potassiumhexacyanidoferrate (II)
Write the formula for the following coordination compound.
pentacarbonyl iron (0)
Write the formula for the following coordination compound.
pentaamminenitrito-κNcobalt (III) ion
Write the formula for the following coordination compound.
hexaamminecobalt (III) sulphate
Write the formula for the following coordination compound.
sodiumtetrafluoridodihydroxidochromate (III)
Arrange the following in order of increasing molar conductivity.
i) \[\ce{Mg[Cr(NH3) (Cl)5]}\]
ii) \[\ce{[Cr(NH3)5 Cl]3 [CoF6]2}\]
iii) \[\ce{[Cr(NH3)3 Cl3]}\]
Give an example of coordination compound used in medicine and two examples of biologically important coordination compounds.
Based on VB theory explain why \[\ce{[Cr(NH3)6]^3+}\] is paramagnetic, while \[\ce{[Ni(CN)4]^2-}\] is diamagnetic.
Draw all possible geometrical isomers of the complex \[\ce{[Co(en)2Cl2]^+}\] and identify the optically active isomer.
[Ti(H2O)6]3+ is coloured, while [Sc(H2O)6]3+ is colourless – explain.
Give an example for a complex of the type [Ma2b2c2] where a, b, c are monodentate ligands and give the possible isomers.
Give one test to differentiate \[\ce{[Co(NH3)5Cl]SO4}\] and \[\ce{[Co(NH3)5SO4]Cl}\].
In an octahedral crystal field, draw the figure to show the splitting of d orbitals.
What is linkage isomerism? Explain with an example.
Classify the following ligand based on the number of donor atoms.
NH3
Classify the following ligand based on the number of donor atoms.
en
Classify the following ligand based on the number of donor atoms.
ox2−
Classify the following ligand based on the number of donor atoms.
pyridine
Give the difference between double salts and coordination compounds.
Write the postulates of Werner’s theory.
Why tetrahedral complexes do not exhibit geometrical isomerism.
Explain optical isomerism in coordination compounds with an example.
What are hydrate isomers? Explain with an example.
What is crystal field splitting energy?
What is crystal field stabilization energy (CFSE)?
A solution of \[\ce{[Ni(H2O)6]^2+}\] is green, whereas a solution of \[\ce{[Ni(CN)4]^2-}\] is colorless – Explain.
Discuss briefly the nature of bonding in metal carbonyls.
What is the coordination entity formed when excess of liquid ammonia is added to an aqueous solution of copper sulphate?
On the basis of VB theory explain the nature of bonding in \[\ce{[Co(C2O4)3]^3-}\].
What are the limitations of VB theory?
Write the oxidation state, coordination number, nature of ligand, magnetic property and electronic configuration in octahedral crystal field for the complex \[\ce{K4[Mn(CN)6]}\].
Solutions for 5: Coordination Chemistry
Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 12 TN Board chapter 5 - Coordination Chemistry
Shaalaa.com has the Tamil Nadu Board of Secondary Education Mathematics Chemistry - Volume 1 and 2 [English] Class 12 TN Board Tamil Nadu Board of Secondary Education solutions in a manner that help students grasp basic concepts better and faster. The detailed, step-by-step solutions will help you understand the concepts better and clarify any confusion. Samacheer Kalvi solutions for Mathematics Chemistry - Volume 1 and 2 [English] Class 12 TN Board Tamil Nadu Board of Secondary Education 5 (Coordination Chemistry) include all questions with answers and detailed explanations. This will clear students' doubts about questions and improve their application skills while preparing for board exams.
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Concepts covered in Chemistry - Volume 1 and 2 [English] Class 12 TN Board chapter 5 Coordination Chemistry are Coordination Compounds and Double Salts, Definition of Important Terms Pertaining to Co-ordination Compounds, Nomenclature of Coordination Compounds, Isomerism in Coordination Compounds, Theories of Coordination Compound, Stability of Metal Complexes, Importance and Applications of Coordination Complexes, Werner’s Theory of Coordination Compounds.
Using Samacheer Kalvi Chemistry - Volume 1 and 2 [English] Class 12 TN Board solutions Coordination Chemistry exercise by students is an easy way to prepare for the exams, as they involve solutions arranged chapter-wise and also page-wise. The questions involved in Samacheer Kalvi Solutions are essential questions that can be asked in the final exam. Maximum Tamil Nadu Board of Secondary Education Chemistry - Volume 1 and 2 [English] Class 12 TN Board students prefer Samacheer Kalvi Textbook Solutions to score more in exams.
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