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Tamil Nadu Board of Secondary EducationHSC Science Class 12

Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 12 TN Board chapter 10 - Surface Chemistry [Latest edition]

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Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 12 TN Board chapter 10 - Surface Chemistry - Shaalaa.com
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Solutions for Chapter 10: Surface Chemistry

Below listed, you can find solutions for Chapter 10 of Tamil Nadu Board of Secondary Education Samacheer Kalvi for Chemistry - Volume 1 and 2 [English] Class 12 TN Board.


Evaluation
Evaluation [Pages 100 - 103]

Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 12 TN Board 10 Surface Chemistry Evaluation [Pages 100 - 103]

Choose the correct answer:

Evaluation | Q 1. | Page 100

For Freundlich isotherm a graph of log `"x"/"m"` is plotted against log p. The slope of the line and its y-axis intercept respectively corresponds to ____________.

  • `1/"n", "k"`

  • `log  1/"n", "k"`

  • `1/"n", log "k"`

  • `log  1/"n", log "k"`

Evaluation | Q 2. | Page 100

Which of the following is incorrect for physisorption?

  • reversible

  • increases with increase in temperature

  • low heat of adsorption

  • increases with increase in surface area

Evaluation | Q 3. | Page 100

Which one of the following characteristics are associated with adsorption?

  • ΔG and ΔH are negative but ΔS is positive.

  • ΔG and ∆S are negative but ∆H is positive.

  • ∆G is negative but ∆H and ∆S are positive.

  • ∆G, ∆H and ∆S all are negative.

Evaluation | Q 4. | Page 100

Fog is colloidal solution of ____________.

  • solid in gas

  • gas in gas

  • liquid in gas

  • gas in liquid

Evaluation | Q 5. | Page 100

Assertion: Coagulation power of Al3+ is more than Na+.

Reason: greater the valency of the flocculating ion added, greater is its power to cause precipitation.

  • if both assertion and reason are true and reason is the correct explanation of assertion.

  • if both assertion and reason are true but reason is not the correct explanation of assertion.

  • assertion is true but reason is false.

  • both assertion and reason are false.

Evaluation | Q 6. | Page 100

Statement: To stop bleeding from an injury, ferric chloride can be applied. Which comment about the statement is justified?

  • It is not true, ferric chloride is a poison.

  • It is true, Fe3+ ions coagulate blood which is a negatively charged sol.

  • It is not true; ferric chloride is ionic and gets into the blood stream.

  • It is true, coagulation takes place because of formation of negatively charged sol with Cl.

Evaluation | Q 7. | Page 101

Hair cream is ____________.

  • gel

  • emulsion

  • solid sol

  • sol

Evaluation | Q 8. | Page 101

Which one of the following is correctly matched?

  • Emulsion - Smoke

  • Gel - Butter

  • Foam - Mist

  • Whipped cream - Sol

Evaluation | Q 9. | Page 101

The most effective electrolyte for the coagulation of As2S3 Sol is ____________.

  • NaCl

  • Ba(NO3)2

  • K3[Fe(CN)6]

  • AI3+

Evaluation | Q 10. | Page 101

Which one of the is not a surfactant?

  • \[\ce{CH3 - (CH2)15 - \overset{+}{N} - (CH3)2 CH2Br}\]

  • \[\ce{CH3 - (CH2)15 - NH2}\]

  • \[\ce{CH3 - (CH2)16 - CH2 OSO^-_2 Na^+}\]

  • \[\ce{OHC - (CH2)14 - CH2 - COO^- Na^+}\]

Evaluation | Q 11. | Page 101

The phenomenon observed when a beam of light is passed through a colloidal solution is ____________.

  • Cataphoresis

  • Electrophoresis

  • Coagulation

  • Tyndall effect

Evaluation | Q 12. | Page 101

In an electrical field, the particles of a colloidal system move towards the cathode. The coagulation of the same sol is studied using

I. K2SO4

II. Na3PO4

III. K4[Fe(CN)6]

IV. NaCI

Their coagulating power should be

  • II > I > IV > III

  • III > II > I > IV

  • I > II > III > IV

  • none of these

Evaluation | Q 13. | Page 101

Collodion is a 4% solution of which one of the following compounds in the alcohol-ether mixture?

  • Nitroglycerine

  • Cellulose acetate

  • Glycoldinitrate

  • Nitrocellulose

Evaluation | Q 14. | Page 101

Which one of the following is an example for homogeneous catalysis?

  • Manufacture of ammonia by Haber’s process

  • Manufacture of sulphuric acid by contact process

  • Hydrogenation of oil

  • Hydrolysis of sucrose in presence of dil HCl

Evaluation | Q 15. | Page 102

Match the following.

Column I Column II
A) V2O5 (i) High density polyethylene
B) Ziegler – Natta (ii) PAN
C) Peroxide (iii) NH3
D) Finely divided – Fe (iv) H2SO4
  • A B C D
    (iv) (i) (ii) (iii)
  • A B C D
    (i) (ii) (iv) (iii)
  • A B C D
    (ii) (iii) (iv) (i)
  • A B C D
    (iii) (iv) (ii) (i)
Evaluation | Q 16. | Page 102

The coagulation values in millimoles per litre of the electrolytes used for the coagulation of As2S3 are given below

(I) (NaCl) = 52

(II) (BaCl2) = 0.69

(III) (MgSO4) = 0.22

The correct order of their coagulating power is:

  • III > II > I

  • I > II > III

  • I > III > II

  • II > III > I

Evaluation | Q 17. | Page 102

Adsorption of a gas on solid metal surface is spontaneous and exothermic, then ____________.

  • ∆H increases

  • ∆S increases

  • ∆G increases

  • ∆S decreases

Evaluation | Q 18. | Page 102

If x is the amount of adsorbate and m is the amount of adsorbent, which of the following relations is not related to adsorption process?

  • `"x"/"m"` = f(P) at constant T

  • `"x"/"m"` = f(T) at constant P

  • P = f(T) at constant `"x"/"m"`

  • `"x"/"m"` = PT

Evaluation | Q 19. | Page 102

On which of the following properties does the coagulating power of an ion depend?

  • Both magnitude and sign of the charge on the ion.

  • Size of the ion alone.

  • The magnitude of the charge on the ion alone.

  • The sign of charge on the ion alone.

Evaluation | Q 20. | Page 102

Match the following.

Column I Column II
A) Pure nitrogen (i) Chlorine
B) Haber process (ii) Sulphuric acid
C) Contact process (iii) Ammonia
D) Deacons Process (iv) sodium azide (or) Barium azide

Which of the following is the correct option?

  • A B C D
    (i) (ii) (iii) (iv)
  • A B C D
    (ii) (iv) (i) (iii)
  • A B C D
    (iii) (iv) (ii) (i)
  • A B C D
    (iv) (iii) (ii) (i)

Short Answer:

Evaluation | Q 1. | Page 103

Give two important characteristics of physisorption.

Evaluation | Q 2. | Page 103

Differentiate physisorption and chemisorption.

Evaluation | Q 3. | Page 103

In case of chemisorption, why adsorption first increases and then decreases with temperature?

Evaluation | Q 4. | Page 103

Which will be adsorbed more readily on the surface of charcoal and why? NH3 or O2?

Evaluation | Q 5. | Page 103

Heat of adsorption is greater for chemisorptions than physisorption. Why?

Evaluation | Q 6. | Page 103

Peptising agent is added to convert precipitate into colloidal solution. Explain with an example.

Evaluation | Q 7. | Page 103

What happens when a colloidal sol of Fe(OH)3 and As2S3 are mixed?

Evaluation | Q 8. | Page 103

What is the difference between sol and gel?

Evaluation | Q 9. | Page 103

Why are lyophillic colloidal sols are more stable than lyophobic colloidal sol?

Evaluation | Q 10. | Page 103

Addition of Alum purifies water. Why?

Evaluation | Q 11. | Page 103

What are the factors which influence the adsorption of a gas on a solid?

Evaluation | Q 12. | Page 103

What are enzymes?

Evaluation | Q 12. | Page 103

Write a brief note on the mechanism of enzyme catalysis.

Evaluation | Q 13. | Page 103

What do you mean by activity and selectivity of catalyst?

Evaluation | Q 14. | Page 103

Describe some features of catalysis by Zeolites.

Evaluation | Q 15. | Page 103

Give three uses of emulsions.

Evaluation | Q 16. | Page 103

Why does the bleeding stop by rubbing moist alum?

Evaluation | Q 17. | Page 103

Why is desorption important for a substance to act as a good catalyst?

Evaluation | Q 18. | Page 103

Comment on the statement:

Colloid is not a substance but it is a state of substance.

Evaluation | Q 19. | Page 103

Explain any one method for coagulation.

Evaluation | Q 20. | Page 103

Write a note on electro osmosis.

Evaluation | Q 21. | Page 103

Write a note on catalytic poison.

Evaluation | Q 22. | Page 103

Explain the intermediate compound formation theory of catalysis with an example.

Evaluation | Q 23. | Page 103

What is the difference between homogeneous and heterogeneous catalysis?

Evaluation | Q 24. | Page 103

Describe the adsorption theory of catalysis.

Solutions for 10: Surface Chemistry

Evaluation
Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 12 TN Board chapter 10 - Surface Chemistry - Shaalaa.com

Samacheer Kalvi solutions for Chemistry - Volume 1 and 2 [English] Class 12 TN Board chapter 10 - Surface Chemistry

Shaalaa.com has the Tamil Nadu Board of Secondary Education Mathematics Chemistry - Volume 1 and 2 [English] Class 12 TN Board Tamil Nadu Board of Secondary Education solutions in a manner that help students grasp basic concepts better and faster. The detailed, step-by-step solutions will help you understand the concepts better and clarify any confusion. Samacheer Kalvi solutions for Mathematics Chemistry - Volume 1 and 2 [English] Class 12 TN Board Tamil Nadu Board of Secondary Education 10 (Surface Chemistry) include all questions with answers and detailed explanations. This will clear students' doubts about questions and improve their application skills while preparing for board exams.

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Concepts covered in Chemistry - Volume 1 and 2 [English] Class 12 TN Board chapter 10 Surface Chemistry are Adsorption and Absorption, Catalysis, Zeolite Catalysis, Colloid, Dispersion Phase and Dispersion Medium, Emulsions, Various Application of Colloids, Enzyme Catalysis.

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