Advertisements
Advertisements
Question
Choose the most correct option.
Slope of the graph ln[A]t versus t for first-order reaction is _________.
Options
-k
k
`"k"/2.303`
`"-k"/2.303`
Solution
The slope of the graph ln[A]t versus t for the first-order reaction is -k.
APPEARS IN
RELATED QUESTIONS
Choose the most correct option.
The order of the reaction for which the units of the rate constant are mol dm-3 s-1 is _______.
What is the half life of a first order reaction if time required to decrease concentration of reactant from 0.8 M to 0.2 M is 12 h?
Choose the most correct option.
The reaction, \[\ce{3ClO- -> ClO^-3 + 2Cl-}\] occurs in two steps,
(i) \[\ce{2ClO- -> ClO^-2}\]
(ii) \[\ce{ClO^-2 + ClO- -> ClO^-_3 + Cl-}\]
The reaction intermediate is _______.
Choose the most correct option.
The elementary reaction \[\ce{O3_{(g)} + O_{(g)} -> 2O2_{(g)}}\] is ___________.
Answer the following in one or two sentences.
For the reaction, \[\ce{CH3Br_{(aq)} + OH^{-}_{(aq)} -> CH3OH^{\ominus}_{(aq)} + Br^{\ominus}_{(aq)}}\], rate law is rate = \[\ce{k[CH3Br][OH^\ominus]}\]
How does reaction rate changes if \[\ce{[OH^\ominus]}\] is decreased by a factor of 5?
A First order reaction is 50% complete in 69.3 minutes. Time required for 90% completion for the same reaction is _______.
Define order of reaction with suitable examples.
A reaction occurs in the following steps:
Step 1: \[\ce{NO_{2(g)} + F_2 -> NO2F_{(g)} + F_{(g)}}\] (slow)
Step 2: \[\ce{F_{(g)} + NO_{2(g)} -> NO_2F}\] (Fast)
- Write the equation of overall reaction.
- Write the rate law.
- Identify reaction intermediate.
In a first-order reaction A → B, 60% of a given sample of a compound decomposes in 45 mins. What is the half-life of reaction? Also, write the rate law equation for the above first-order reaction.
The rate constant of a first order reaction whose half-life is 480 seconds, is ____________.
For the non-stoichiometric reaction
\[\ce{2A + B -> C + D}\], the following kinetic data were obtained in three separate experiments, all at 298 K.
| Initial concentration (A) |
Initial concentration (B) |
Initial rate of formation of C (mol dm−3 s−1) |
| 0.1 M | 0.1 M | 1.2 × 10−3 |
| 0.1 M | 0.2 M | 1.2 × 10−3 |
| 0.2 M | 0.1 M | 2.4 × 10−3 |
The rate law for the formation of C is:
For the reaction, \[\ce{N2(g) + 3H2(g) -> 2NH3(g); \Delta H}\] is equal to ______.
A gaseous hypothetical chemical equation \[\ce{2A ⇌ 4B + C}\] is carried out in a closed vessel. The concentration of B is found to increase by 5 × 10−3 mol dm−3 in 10 second. The rate of ____________.
For a hypothetical reaction \[\ce{A + B -> C}\], it is found that doubling the concentration of A increases the rate by 8 times and doubling the concentration of B increases the rate by 4 times. The overall order of the reaction is ____________.
Select the rate law that corresponds to the data shown for the following reaction:
| Exp. | [A] mol dm−3 |
[B] mol dm−3 |
Initial Rate mol dm−3 |
| 1. | 0.012 | 0.035 | 0.10 |
| 2. | 0.024 | 0.070 | 0.80 |
| 3. | 0.024 | 0.035 | 0.10 |
| 4. | 0.012 | 0.070 | 0.80 |
The order of the reaction occurring by following mechanism should be:
(i) \[\ce{A2 + B2 -> AB2 + A (slow)}\]
(ii) \[\ce{A + B2 -> AB2 (fast)}\]
Consider the reaction \[\ce{2A + 2B -> C + 2D}\], if concentration of A is doubled at constant [B], rate increases by a factor 4. If concentration B is doubled at constant [A] the rate is doubled. Rate law of the reaction is ____________.
The reaction \[\ce{A + B -> P}\], is second order in A and first order in B. What is the rate law for the reaction?
In the reaction, \[\ce{N2 + 3H2 -> 2NH3}\], the rate of disappearance of H2 is 0.02 Mis. The rate of appearance of NH3 is ______.
For the reaction \[\ce{2A + B -> 3C + D}\], which among the following is NOT the correct rate law expression?
For the reaction \[\ce{4NH3 + 5O2 -> 4NO + 6H2O}\], the rate of disappearance of NH3 is 3.6 × 10-3 M/s. What is the rate of formation of water?
Which of the following unit is used to express the rate of a reaction?
The correct order of raaii of F, F-, O and O2- is ______.
For a chemical reaction A → 7 products, the rate of reaction doubles when the concentration of A is increased by a factor 4. The order of the reaction is ______.
