Advertisements
Advertisements
Question
The speed of sound in hydrogen at 0°C is 1280 m s−1. The density of hydrogen at STP is 0.089 kg m−3. Calculate the molar heat capacities Cp and Cv of hydrogen.
Solution
Given:
Velocity of sound in hydrogen, V = 1280 m/s
Temperature, T = 0°C = 273 K
Density of H2 = 0.089 kg/m3
R = 8.3 J/mol-K
At STP,
P = 105 Pa
We know:
`"V"_"sound" = (sqrt (gamma"p")/ρ )`
1280 = `sqrt ((gamma xx10 ^5)/0.089)`
Or `gamma = (1280 xx 1280 xx 0.089)/10^5`
= 1.46
`"C"_"p"/ "C"_"v" = gamma or "C"_"p" -"C"_"v" = "R" `
`"C"_"v" = "R"/(gamma-1) = 8.3 /(1.46-1)`
= 18.0J /mol -K
Cp = γ Cv =1.46 × 18.0
= 26.28 ≈ 26.3 / mol -K
APPEARS IN
RELATED QUESTIONS
Given below are densities of some solids and liquids. Give rough estimates of the size of their atoms:
| Substance | Atomic Mass (u) | Density (103 Kg m-3) |
| Carbon (diamond) | 12.01 | 2.22 |
| Gold | 197.00 | 19.32 |
| Nitrogen (liquid) | 14.01 | 1.00 |
| Lithium | 6.94 | 0.53 |
| Fluorine (liquid) | 19.00 | 1.14 |
[Hint: Assume the atoms to be ‘tightly packed’ in a solid or liquid phase, and use the known value of Avogadro’s number. You should, however, not take the actual numbers you obtain for various atomic sizes too literally. Because of the crudeness of the tight packing approximation, the results only indicate that atomic sizes are in the range of a few Å].
The specific heat capacity of water is
Does a gas have just two specific heat capacities or more than two? Is the number of specific heat capacities of a gas countable?
Can we define specific heat capacity at constant temperature?
Can we define specific heat capacity for an adiabatic process?
Does a solid also have two kinds of molar heat capacities Cp and Cv? If yes, is Cp > Cv? Or is Cp − Cv = R?
Can a process on an ideal gas be both adiabatic and isothermal?
Show that the slope of the p−V diagram is greater for an adiabatic process compared to an isothermal process.
Can two states of an ideal gas be connected by an isothermal process as well as an adiabatic process?
In an isothermal process on an ideal gas, the pressure increases by 0.5%. The volume decreases by about
Three identical adiabatic containers A, B and C contain helium, neon and oxygen, respectively, at equal pressure. The gases are pushed to half their original volumes.
(a) The final temperatures in the three containers will be the same.
(b) The final pressures in the three containers will be the same.
(c) The pressures of helium and neon will be the same but that of oxygen will be different.
(d) The temperatures of helium and neon will be the same but that of oxygen will be different.
A sample of air weighing 1.18 g occupies 1.0 × 103 cm3 when kept at 300 K and 1.0 × 105 Pa. When 2.0 cal of heat is added to it at constant volume, its temperature increases by 1°C. Calculate the amount of heat needed to increase the temperature of air by 1°C at constant pressure if the mechanical equivalent of heat is 4.2 × 107 erg cal−1. Assume that air behaves as an ideal gas.
The figure shows two vessels with adiabatic walls, one containing 0.1 g of helium (γ = 1.67, M = 4 g mol−1) and the other containing some amount of hydrogen (γ = 1.4, M = 2 g mol−1). Initially, the temperatures of the two gases are equal. The gases are electrically heated for some time during which equal amounts of heat are given to the two gases. It is found that the temperatures rise through the same amount in the two vessels. Calculate the mass of hydrogen.
Standing waves of frequency 5.0 kHz are produced in a tube filled with oxygen at 300 K. The separation between the consecutive nodes is 3.3 cm. Calculate the specific heat capacities Cp and Cv of the gas.
Molar specific heat of water is C = 74.7 J/mol K, its value in cal/g K is ______.
An engine takes in 5 moles of air at 20°C and 1 atm, and compresses it adiabatically to `1/10^"th"` of the original volume. Assuming air to be a diatomic ideal gas made up of rigid molecules, the change in its internal energy during this process comes out to be X kJ. The value of X to the nearest integer is ______.
If at same temperature and pressure, the densities for two diatomic gases are respectively d1 and d2 then the ratio of velocities of sound in these gases will be ______.
