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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

How Many Moles of Acetic Anhydride Will Be Required to Form Glucose Pentaacetate from 2m of Glucose? - Chemistry

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प्रश्न

How many moles of acetic anhydride will be required to form glucose pentaacetate from 2M of glucose?

(a) 2

(b) 5

(c) 10

(d) 2.5

उत्तर

(c) 10

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2013-2014 (March)

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संबंधित प्रश्‍न

Write the reaction that indicates the presence of -CHO group in glucose


Draw the simple Fisher projection formulae of D - (+) - glucose and D - (-) - fructose


Enumerate the reactions of D-glucose which cannot be explained by its open chain structure.


Enlist the properties of glucose that can not be explained on the basis of open chain structure of it


Glucose on reaction with HI gives n-hexane. What does it suggest about the structure of glucose?

 

 

Fill in the blanks by choosing the appropriate word/words from those given in the brackets:  

(iodoform, acetaldehyde, positive, greater, acidic, acetone, disaccharide, negative, increases, glucose, decreases, chloroform, polysaccharide, lactose, lesser, basic, cationic hydrolysis, anionic hydrolysis)

Sucrose is a _________ and yields upon hydrolysis, a mixture of ________ and fructose.


Answer the following question.
What is the basic structural difference between glucose and fructose?


Write the reactions involved when D-glucose is treated with the following reagent:
H2N-OH


What is the most abundant organic compound on earth?


Glucose does not give Schiff’s test because of the formation of cyclic ____________.


Which of the following statements is incorrect regarding glucose?


When glucose reacts with bromine water, the main product is ____________.


Reduction of glucose by HI suggest that ____________.


The reaction of glucose with red P + HI is called ____________.


Which of the following reactions of glucose can be explained only by its cyclic structure?


Which is the least stable form of glucose?


Choose the correct relationship for glucose and fructose:


Which one is correct?


In the following reaction, identify A and B:

\[\begin{array}{cc}
\ce{C6H12O6 ->[Acetic anhydride] A}\\
\downarrow \text{Conc. nitric acid}\phantom{...}\\
\ce{B}\phantom{.................}\end{array}\]


How will you distinguish 1° and 2° hydroxyl groups present in glucose? Explain with reactions.


Assertion: D (+) – Glucose is dextrorotatory in nature.

Reason: ‘D’ represents its dextrorotatory nature.


Write the reactions of D-glucose which can’t be explained by its open-chain structure. How can cyclic structure of glucose explain these reactions?


On the basis of which evidences D-glucose was assigned the following structure?

\[\begin{array}{cc}
\ce{CHO}\\
|\phantom{....}\\
\phantom{..}\ce{(CHOH)4}\\
|\phantom{....}\\
\phantom{..}\ce{CH2OH}
\end{array}\]


Account for the following:

What happens when D – glucose is treated with the following reagents

HNO3


Consider the following reactions:

(i) \[\ce{Glucose + R-OH ->[Conc. HNO3] [A] ->[X eq of][(CH3CO)2O] Acetyl derivative}\]

(ii) \[\ce{Glucose ->[Ni/H2] [A] ->[Y eq of][(CH3CO)2O] Acetyl derivative}\]

(iii) \[\ce{Glucose ->[Z eq of][(CH3CO)2O] Acetyl derivative}\]

'X, 'Y' and 'Z' in these reactions are respectively:


Glucose with excess of phenyl hydrazine forms ______.


When D-glucose reacts with HI, it forms ______.


Give the reaction of glucose with hydrogen cyanide. Presence of which group is confirmed by this reaction?


Give a reason for the following observations:

Penta-acetate of glucose does not react with hydroxylamine.


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