Advertisements
Advertisements
प्रश्न
A source contains two species of phosphorous nuclei, \[\ce{_15^32P}\] (T1/2 = 14.3 d) and \[\ce{_15^33P}\] (T1/2 = 25.3 d). At time t = 0, 90% of the decays are from \[\ce{_15^32P}\]. How much time has to elapse for only 15% of the decays to be from \[\ce{_15^32P}\]?
उत्तर
Data: \[\ce{_15^32P}\] : T1/2 = 14.3 d
∴ `lambda_1 = 0.693/(14.3 "d") = 0.04846 "d"^-1`
\[\ce{_15^32P}\] : T1/2 = 25.3 d
∴ `lambda_2 = 0.693/(25.3 "d") = 0.02739 "d"^-1`
At time t = 0, `("N"_"O1" lambda_1)/("N"_"O2"lambda_2) = (90%)/(10%) = 9` ...(1) and
at time t, `("N"_"O1" lambda_1"e"^(-lambda_1"t"))/("N"_"O2" lambda_2"e"^(-lambda_2"t")) = (15%)/(85%) = 3/17` ...(2)
Dividing Eq. (1) by Eq. (2), we get,
`("N"_"O1" lambda_1)/("N"_"O2"lambda_2) * ("N"_"O1" lambda_1"e"^(-lambda_1"t"))/("N"_"O2" lambda_2"e"^(-lambda_2"t")) = 9/(3//17) = 153/3`
∴ `"e"^((lambda_1 - lambda_2)"t") = 153/3`
∴ `(lambda_1 - lambda_2)"t" = 2.303 log_10(153/3) = 2.303(log_10 153 - log_10 3)`
∴ (0.04846 - 0.02739) t = 2.303 (2.1847 - 0.4771)
∴ t = `((2.303)(1.7076))/0.02107` = 186.6 days
APPEARS IN
संबंधित प्रश्न
Derive the mathematical expression for law of radioactive decay for a sample of a radioactive nucleus
Obtain the relation between the decay constant and half life of a radioactive sample.
A radioactive isotope has a half-life of T years. How long will it take the activity to reduce to a) 3.125%, b) 1% of its original value?
The normal activity of living carbon-containing matter is found to be about 15 decays per minute for every gram of carbon. This activity arises from the small proportion of radioactive `""_6^14"C"` present with the stable carbon isotope `""_6^12"C"`. When the organism is dead, its interaction with the atmosphere (which maintains the above equilibrium activity) ceases and its activity begins to drop. From the known half-life (5730 years) of `""_6^14"C"` and the measured activity, the age of the specimen can be approximately estimated. This is the principle of `""_6^14"C"` dating used in archaeology. Suppose a specimen from Mohenjodaro gives an activity of 9 decays per minute per gram of carbon. Estimate the approximate age of the Indus-Valley civilisation.
Obtain the amount of `""_27^60"Co"` necessary to provide a radioactive source of 8.0 mCi strength. The half-life of `""_27^60"Co"` is 5.3 years.
The half-life of `""_38^90 "Sr"` is 28 years. What is the disintegration rate of 15 mg of this isotope?
The radionuclide 11C decays according to
\[\ce{^11_6C -> ^11_5B + e+ + \text{v}}\] : T1/2 = 20.3 min
The maximum energy of the emitted positron is 0.960 MeV.
Given the mass values: `"m"(""_6^11"C") = 11.011434 u and "m"(""_6^11"B") = 11.009305 "u"`
Calculate Q and compare it with the maximum energy of the positron emitted.
The Q value of a nuclear reaction \[\ce{A + b → C + d}\] is defined by
Q = [ mA+ mb− mC− md]c2 where the masses refer to the respective nuclei. Determine from the given data the Q-value of the following reactions and state whether the reactions are exothermic or endothermic.
\[\ce{^1_1H + ^3_1H -> ^2_1H + ^2_1H}\]
Atomic masses are given to be
`"m"(""_1^2"H")` = 2.014102 u
`"m"(""_1^3"H")` = 3.016049 u
`"m"(""_6^12"C")` = 12.000000 u
`"m"(""_10^20"Ne")` = 19.992439 u
The Q value of a nuclear reaction A + b → C + d is defined by
Q = [mA+ mb − mC − md]c2 where the masses refer to the respective nuclei. Determine from the given data the Q-value of the following reactions and state whether the reactions are exothermic or endothermic.
\[\ce{^12_6C + ^12_6C ->^20_10Ne + ^4_2He}\]
Atomic masses are given to be
`"m"(""_1^2"H")` = 2.014102 u
`"m"(""_1^3"H")` = 3.016049 u
`"m"(""_6^12C)` = 12.000000 u
`"m"(""_10^20"Ne")` = 19.992439 u
Using the equation `N = N_0e^(-lambdat)` obtain the relation between half-life (T) and decay constant (`lambda`) of a radioactive substance.
(a) Derive the relation between the decay constant and half life of a radioactive substance.
(b) A radioactive element reduces to 25% of its initial mass in 1000 years. Find its half life.
Define 'activity' of a radioactive substance ?
Why is it experimentally found difficult to detect neutrinos in this process ?
Define the activity of a given radioactive substance. Write its S.I. unit.
In a given sample, two radioisotopes, A and B, are initially present in the ration of 1 : 4. The half lives of A and B are respectively 100 years and 50 years. Find the time after which the amounts of A and B become equal.
In a radioactive decay, neither the atomic number nor the mass number changes. Which of the following particles is emitted in the decay?
Lithium (Z = 3) has two stable isotopes 6Li and 7Li. When neutrons are bombarded on lithium sample, electrons and α-particles are ejected. Write down the nuclear process taking place.
The masses of 11C and 11B are respectively 11.0114 u and 11.0093 u. Find the maximum energy a positron can have in the β*-decay of 11C to 11B.
(Use Mass of proton mp = 1.007276 u, Mass of `""_1^1"H"` atom = 1.007825 u, Mass of neutron mn = 1.008665 u, Mass of electron = 0.0005486 u ≈ 511 keV/c2,1 u = 931 MeV/c2.)
28Th emits an alpha particle to reduce to 224Ra. Calculate the kinetic energy of the alpha particle emitted in the following decay:
`""^228"Th" → ""^224"Ra"^(∗) + alpha`
`""^224"Ra"^(∗) → ""^224"Ra" + γ (217 "keV")`.
Atomic mass of 228Th is 228.028726 u, that of 224Ra is 224.020196 u and that of `""_2^4H` is 4.00260 u.
(Use Mass of proton mp = 1.007276 u, Mass of `""_1^1"H"` atom = 1.007825 u, Mass of neutron mn = 1.008665 u, Mass of electron = 0.0005486 u ≈ 511 keV/c2,1 u = 931 MeV/c2.)
The decay constant of 238U is 4.9 × 10−18 S−1. (a) What is the average-life of 238U? (b) What is the half-life of 238U? (c) By what factor does the activity of a 238U sample decrease in 9 × 109 years?
When charcoal is prepared from a living tree, it shows a disintegration rate of 15.3 disintegrations of 14C per gram per minute. A sample from an ancient piece of charcoal shows 14C activity to be 12.3 disintegrations per gram per minute. How old is this sample? Half-life of 14C is 5730 y.
A radioactive isotope is being produced at a constant rate dN/dt = R in an experiment. The isotope has a half-life t1/2. Show that after a time t >> t1/2 the number of active nuclei will become constant. Find the value of this constant.
Consider the situation of the previous problem. Suppose the production of the radioactive isotope starts at t = 0. Find the number of active nuclei at time t.
Obtain a relation between the half-life of a radioactive substance and decay constant (λ).
Identify the nature of the radioactive radiations emitted in each step of the decay process given below.
`""_Z^A X -> _Z^A _-1^-4 Y ->_Z^A _-1^-4 W`
A radioactive substance disintegrates into two types of daughter nuclei, one type with disintegration constant λ1 and the other type with disintegration constant λ2 . Determine the half-life of the radioactive substance.
The isotope \[\ce{^57Co}\] decays by electron capture to \[\ce{^57Fe}\] with a half-life of 272 d. The \[\ce{^57Fe}\] nucleus is produced in an excited state, and it almost instantaneously emits gamma rays.
(a) Find the mean lifetime and decay constant for 57Co.
(b) If the activity of a radiation source 57Co is 2.0 µCi now, how many 57Co nuclei does the source contain?
c) What will be the activity after one year?
Obtain an expression for the decay law of radioactivity. Hence show that the activity A(t) =λNO e-λt.
Two radioactive materials X1 and X2 have decay constants 10λ and λ respectively. If initially, they have the same number of nuclei, then the ratio of the number of nuclei of X1 to that of X2 will belie after a time.
Which one of the following nuclei has shorter meant life?
'Half-life' of a radioactive substance accounts for ______.
The half-life of a radioactive sample undergoing `alpha` - decay is 1.4 x 1017 s. If the number of nuclei in the sample is 2.0 x 1021, the activity of the sample is nearly ____________.
Two electrons are ejected in opposite directions from radioactive atoms in a sample of radioactive material. Let c denote the speed of light. Each electron has a speed of 0.67 c as measured by an observer in the laboratory. Their relative velocity is given by ______.
If 10% of a radioactive material decay in 5 days, then the amount of original material left after 20 days is approximately :
When a nucleus in an atom undergoes a radioactive decay, the electronic energy levels of the atom ______.
Which sample, A or B shown in figure has shorter mean-life?
Consider a radioactive nucleus A which decays to a stable nucleus C through the following sequence:
A→B→C
Here B is an intermediate nuclei which is also radioactive. Considering that there are N0 atoms of A initially, plot the graph showing the variation of number of atoms of A and B versus time.
The activity R of an unknown radioactive nuclide is measured at hourly intervals. The results found are tabulated as follows:
| t (h) | 0 | 1 | 2 | 3 | 4 |
| R (MBq) | 100 | 35.36 | 12.51 | 4.42 | 1.56 |
- Plot the graph of R versus t and calculate the half-life from the graph.
- Plot the graph of ln `(R/R_0)` versus t and obtain the value of half-life from the graph.
The radioactivity of an old sample of whisky due to tritium (half-life 12.5 years) was found to be only about 4% of that measured in a recently purchased bottle marked 10 years old. The age of a sample is ______ years.
The half-life of `""_82^210Pb` is 22.3 y. How long will it take for its activity 0 30% of the initial activity?
