मराठी

Metallurgy

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Topics

  • Introduction
  • Metallurgical Process

Introduction

Metallurgy is the process used for the extraction of metals in their pure form from ores. It includes the purification of metals and the formation of alloys.

Occurrence of Metals:

  • Reactive metals (e.g., iron, aluminium, zinc) are found in combined states as oxides, carbonates, sulphides, or nitrates because they readily react with air and water.
  • Less reactive metals (e.g., copper) can be found in both combined and free states.
  • Unreactive metals (e.g., gold, silver, platinum) exist in their free state, as they do not react with air, water, or other natural elements.

Minerals, Ores, and Gangue:

  1. Minerals: naturally occurring compounds of metals found in the earth’s crust, often mixed with impurities.
  2. Ores: Minerals from which metals can be extracted economically. Not all minerals are ores, but all ores are minerals.
  3. Gangue: unwanted impurities like sand, soil, and rocky substances mixed with ores.

Metallurgical Process

1. Mining and Ore Dressing

  • Mining: Ores are extracted from the earth’s crust through mining.
  • Ore Dressing (Beneficiation): The gangue (impurities) is removed using physical separation methods like handpicking, washing, magnetic separation, or froth flotation.

2. Extraction of Metals from Ores

The extraction method depends on the nature of the metal and its ore.

a. Pyrometallurgy (Heat-Based Extraction)

  • Roasting: Sulphide ores are heated in excess air to convert them into oxides.
  • Calcination: Carbonate ores are heated in limited air to remove carbon dioxide and moisture.

b. Electrolysis: Highly reactive metals (e.g., sodium, aluminium) are extracted by passing electric current through the molten ore, separating metal ions.

c. Reduction: Less reactive metal oxides (e.g., iron) are reduced using carbon (coke) or other reducing agents.

3. Purification of Metals

Once extracted, metals are further refined using various methods:

  • Distillation: Used for volatile metals like mercury and zinc.
  • Liquation: Used for low-melting metals like tin.
  • Electrolytic Refining: It is the most common method where impure metal is purified using electrolysis.
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