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NEET (UG) Chemistry Syllabus 2024 PDF Download

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NEET (UG) Chemistry Syllabus 2024

The NEET (UG) Chemistry Syllabus for the NEET (UG) 2024 is available by the CBSE. The NEET (UG) Chemistry Syllabus is available for review from the link below. The NEET (UG) 2024 Chemistry syllabus defines and describes each unit covered on the NEET (UG) 2024 Chemistry exam.

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Syllabus

Medical Entrance Exam Chemistry Syllabus for Chapter 1: Class 11

1 Some Basic Concepts of Chemistry
  • Chemistry  
  • Development of Chemistry  
  • Importance and Scope of Chemistry  
  • States of Matter  
  • Classification of Matter  
    1. Pure Substances: Elements and Compounds
    2. Mixture: Homogeneous and Heterogeneous mixture
  • Need for Measurement  
    • Physical quantities
    • Some physical quantities
    • Types of Physical quantities
      (i) Fundamental quantities
      (ii) Derived quantities
    • Measurement
  • Properties of Matter and Their Measurement  
    • Properties and Measurement of Matter
    • SI Units and Base Quantities
  • Unit and Its Types  
    • Units
    • Types of units : Fundamental and Derived units
  • Unit Systems  
    • Introduction
    • Types of Unit System
  • International System of Units (Si System)  
  • Unit Prefixes  
  • Uncertainty in Measurement  
    • Scientific Notation  
      • Scientific notation
      • Mathematical operations on numbers expressed in scientific notations - Multiplication, Division, Addition, Subtraction
    • Dimensional Analysis  
  • Accuracy, Precision and Uncertainty in Measurement  
  • Significant Figures  
    • Order of magnitude
    • Significant figures
    • Addition and subtraction of significant figures
    • Multiplication and division of significant figures
    • Rules for limiting the result to the required number of significant figures
    • Rules for arithmetic operations with significant figures
    • Rounding-off in the measurement
  • Laws of Chemical Combination  
    • Introduction
    • Experiment
    • Law of Conservation of Mass  
    • Law of Constant Proportions (Law of Definite Proportions)  
      • Introduction
      • Antoine Lavoisier: The Father of Modern Chemistry
      • Verification of The Law of Constant Proportion
    • Law of Multiple Proportions  
    • Law of Reciprocal Proportions  
    • Avogadro's Law  
  • Fundamental Laws of Gases  
    • Gay Lussac’s Law of Combining Volumes  
      • Gay-Lussac’s law
      • Numericals based on Gay-Lussac's Law
  • Dalton's Atomic Theory  
  • Elements  
    • Experiment 
    • Elements
  • Classification of Elements  
    • Mendeleev's Classification
    • Anomalies of Mendeleev’s Periodic Table
  • Compound  
    • Introduction
    • Experiment 1
    • Experiment 2
  • Atoms: Building Blocks of Matter  
    • Introduction of Atom
    • Discovery of Charged Particles and the Structure of an Atom
  • Molecules  
    • Molecule
    • Properties of molecule
  • Atomic Mass  
    • Introduction of Atomic Mass
    • Properties of Mass Number
    • Determination of Relative Atomic Mass
  • Molecular Mass  
  • Atomic and Molecular Masses  
    • Atomic Mass
    • Average Atomic Mass
    • Molecular Mass
    • Formula Mass
    • Formula Mass  
  • Mole Concept  
    • Concept of Mole
    • Quantities Related on Mole Concept and Their Formula
    • Experiment
  • Percentage Composition, Empirical and Molecular Formula  
    • Percentage composition
    • Chemical formula
      1) Empirical formula
      2) Molecular formula
    • Steps involved in determining the empirical formula
    • Steps for determination of the molecular formula of a compound
  • Stoichiometry and Stoichiometric Calculations - Introduction  
    • Chemical reactions: Reactants, Products, Chemical equation
    • Stoichiometry
    • Steps for writing balanced chemical equation
    • Mass relationship
    • Calculations based on stoichiometry
      1) Mole to mole relationships
      2) Mass-mass relationships
      3) Mass-volume relationship
      4) Volume-volume relationship
    • Limiting reactant
    • Excess reactant
  • Concentration of a Solution  
    • Reactions in solutions
    1. Mass percentage
    2. Mole fraction
    3. Molarity
    4. Molality
    5. Volume percentage
2 Structure of Atom
3 Classification of Elements and Periodicity in Properties
  • Significance of Classification of Elements  
  • Genesis of Periodic Classification  
    • Unitary theory (1815)
    • Law of Triads (1817)
    • Cooke's Homologous series (1854)
    • Law of octaves (1865)
    • Contribution of the German chemist, Lothar Meyer (1869)
    • Mendeleev's periodic law (1869)
  • Mendeleev’s Periodic Table  
    • Introduction
    • Structure and Property
  • Merits and Demerits of Mendeleev’s Periodic Table  
    • Merits
    • Demerits
  • Modern Periodic Law and the Present Form of the Periodic Table  
    • Modern periodic law (1913)
    • Development of modern periodic law
    • Modern periodic table (Long form of the periodic table)
      i) Periods
      ii) Groups
  • Nomenclature of Elements with Atomic Number Greater than 100  
    • Notation for IUPAC Nomenclature of Elements
  • Electronic Configurations and Types of Elements  
    • The s-Block Elements  
    • The p-Block Elements  
    • The d-Block Elements (Transition Elements)  
    • The f-Block Elements (Inner-transition Elements)  
      • Electronic configuration of Lanthanoids
      • Oxidation state of lanthanoids
      • Cause of lanthanoid contraction
      • Oxidation state of actinoids
      • Differences between lanthanoids and actinoids
  • Structure of the Modern Periodic Table  
  • Study of Specific Groups in Periodic Table  
  • Physical Properties  
    • Nature of intermolecular forces
    • Boiling point
    • Solubility
    • Ionic Radius  
      • Ionic radius
        i) Across a period
        ii) Down a group
      • Cationic and anionic radius
      • Variation ofsize (radius) in isoelectronic species
    • Ionization Enthalpy or Ionization Energy (IE) or Ionization Potential (IP)  
      • Ionization enthalpy or ionization energy (IE) or ionization potential (IP)
      • Trends in ionization enthalpy (IE)
        i) Across a period
        ii) Down a group
    • Electron Gain Enthalpy  
      • Electron gain enthalpy (ΔegH)
      • Trends in electron gain enthalpy
        i) Across a period
        ii) Down a group
    • Electronegativity  
      • Electronegativity
      • Factors affecting electronegativity
        i) Atomic size (radius)
        ii) Nuclear charge
        iii) Shielding effect or Screening effect
      • Trends in electronegativity
        i) Across a period
        ii) Down a group
      • Electronegativity values (on Pauling scale) across the periods
      • Electronegativity values (on Pauling scale) down a group
  • Periodic Properties  
    • Atomic Radius Or Atomic Size  
      • Introduction
      • Periodic Trends in Atomic Size
  • Periodic Trends in Chemical Properties  
    • Periodicity of Valence or Oxidation States  
      • Valence or valency
      • Trends in valence
        i) Across a period
        ii) Down a group
      • Valency of second period elements
      • Oxidation states
    • Anomalous Properties of Second Period Elements  
      • Diagonal relationship
  • Periodic Trends and Chemical Reactivity  
    • Chemical reactivity
    • Nature of oxides
4 Chemical Bonding and Molecular Structure
  • Introduction of Chemical Bonding  
    • Chemical bond
    • Causes of chemical combination
      i) Tendency to acquire stability
      ii) Tendency to acquire noble gas configuration
  • Periodic Properties  
    • Valency  
      • Valency Rules and Formula Formation
      • Valency and Electronic Configuration
      • Types and Trends in Valency
      • Methods to Determine the Valency of an Element
  • Kossel and Lewis Approach to Chemical Bonding  
    • Kossel and Lewis theory
    • Lewis symbols
    • Significance of Lewis symbols
    • Lewis symbols and valence of elements
  • Kossel-lewis Approach to Chemical Bonding - Octet Rule  
  • Kossel-lewis Approach to Chemical Bonding - Covalent Bond  
    • Covalent bond
      a) Formation of chlorine molecule
      b) Formation of water molecule
    • Types of covalent bonds: Single, Double and Triple bond
    • Conditions for formation of covalent bond
      i) Number of valence electrons
      ii) Electronegativity difference
      iii) Small decrease in energy
  • Lewis Structures (Lewis Representation of Simple Molecules)  
  • Kossel-lewis Approach to Chemical Bonding - Formal Charge  
    • Formal charge (F.C.)
    • Assigning formal charge
  • Kossel-lewis Approach to Chemical Bonding - Limitations of the Octet Rule  
    • Limitations of the octet rule
    1. The incomplete octet of the central atom
    2. The expanded octet
    3. Odd-electron molecules
    4. Shape and geometry of a molecule
    5. Other drawbacks of the octet theory
  • Ionic or Electrovalent Bond  
    • Ionic bond or Electrovalent bond
    • Mechanism of formation of ionic bond
    • Lattice enthalpy
    • Factors affecting the formation of an ionic bond
      i) Low ionization enthalpy
      ii) High negative electron gain enthalpy
      iii) Large lattice enthalpy
    • Characteristics of ionic or electrovalent compounds
    • Difference between ionic bond and covalent bond
    • Covalent character in ionic bond
    • Fajan's rules
  • Bond Parameters  
    • Bond Parameters
    • Bond length
    • Bond order
    • Bond angle
    • Bond enthalpy
    • Resonance
    • Bond Length  
      • Bond length
      • Factors affecting bond length
      • Types of atomic radii
        i) Covalent radius
        ii) van der Waals radius
      • Average bond length for some single, double and triple bonds
    • Bond Enthalpy  
      • Bond enthalpy (Bond dissociation energy)
      • Bond enthalpy for polyatomic molecules
      • Factors affecting bond enthalpy
    • Bond Angle  
      • Bond angle
      • Factors affecting the bond angle
    • Bond Order  
    • Resonance Structures  
      • Resonance
      • Resonating structures
      • Resonance energy
    • Polarity of Bonds  
      • Polar covalent bond
      • Dipole moment
      • Dipole moments in NH3 and NF3
  • Valence Shell Electron Pair Repulsion Theory (VSEPR)  
    • VSEPR theory
    • Main postulates of VSEPR theory
    • Geometry of some molecules
    • Geometry of some molecules
    • Steps to predict the molecular geometry using VSEPR theory
  • Valence Bond Theory  
    • Postulates of Valence Bond Theory
    • Interacting forces during covalent bond formation
      i) Force of repulsion
      ii) Force of attraction
    • Formation of hydrogen molecule on the basis of valence bond theory (VBT)
    • Overlap of atomic orbitals
    • Limitation of VBT
  • Valence Bond Theory - Orbital Overlap Concept  
    • Sigma and Pi bonds
    • Formation of hydrogen (H2) Molecule 
    1. Formation of fl uorine molecule (F2)
    2. Formation of HF molecule
    3. Formation of oxygen molecule (O2)
  • Valence Bond Theory - Directional Properties of Bonds  
  • Valence Bond Theory - Overlapping of Atomic Orbitals  
  • Valence Bond Theory - Types of Overlapping and Nature of Covalent Bonds  
    • Types of overlap of atomic orbitals
    1. Axial overlap: s-s overlap, s-p overlap, p-p overlap 
    2. Lateral overlap: p-p overlap
  • Valence Bond Theory - Strength of Sigma (σ) bond and pi (π) bond  
    • Difference between sigma (σ) bond and pi (π) bond
  • Hybridisation  
    • Hybridisation - Introduction  
      • Salient features of hybridisation, Important conditions for hybridisation
      • Types of hybridisation and geometry of molecules
      • Bonding in Ethylene
      • Formation of sigma bond
      • Formation of Pi (π ) bond
      • Bonding in acetylene
    • Types of Hybridisation  
      • sp, sp2, sp3, dsp2, sp3d, dsp3, sp3d2 or d2sp3
    • Hybridisation of Elements Involving d Orbitals  
      • SO2 molecule
      • PCl5 molecule
      • Formation of SF6 (sp3d2 hybridisation)
  • Molecular Orbital Theory - Introduction  
  • Molecular Orbital Theory  
    • Formation of molecular orbitals
    • Conditions for the combination of Atomic Orbitals
    • Types of molecular orbitals
    • Energy levels and electronic configuration
    • Key ideas of MO theory
    • MO description of simple diatomic Molecules
    • Formation of Molecular Orbitals - Linear Combination of Atomic Orbitals (LCAO)  
      • Formation of Bonding and Antibonding molecular orbitals (LCAO Method)
      • Difference between Bonding and Antibonding Molecular Orbitals
    • Conditions for the Combination of Atomic Orbitals  
      • Conditions for Atomic orbital (AO) to form Molecular orbital (MO)
      • Difference between AO and MO
    • Types of Molecular Orbitals  
    • Energy Level Diagram for Molecular Orbitals  
      • Relative energies of M.O. and filling of electrons
    • Electronic Configuration and Molecular Behaviour  
      • Stability of Molecules
        i) Stability of molecules in terms of bonding and antibonding electrons
        ii) Stability of molecules in terms of bond order
      • Bond order
      • Nature of the bond
      • Bond-length
      • Magnetic nature
  • Bonding in Some Homonuclear Diatomic Molecules  
    • Homonuclear diatomic molecules
    • Electronic configuration, bond order, and magnetic nature of some diatomic molecules
    1. Hydrogen molecule (H2)
    2. Helium molecule (He2)
    3. Lithium molecule (Li2)
    4. Carbon molecule (C2)
    5. Oxygen molecule (O2)
    • Heteronuclear diatomic molecules
    • Bond Energy
  • Hydrogen Bonding  
    • Cause of Formation of Hydrogen Bond  
    • Types of Hydrogen Bonding  
      • Types of hydrogen bonding
      1. Intermolecular hydrogen bond
      2. lntramolecular hydrogen bond (Chelation)
  • Effects of Hydrogen Bonding  
    • Effects of hydrogen bonding
    1. Dissociation
    2. Association: High melting and boiling point, examples
    3. Solubility
    4. Volatility
    5. Viscosity and surface tension
    6. Density of water
  • Metallic Bond  
5 States of Matter: Gases and Liquids
  • Matter (Substance)  
    • Experiment 1
    • Experiment 2
    • Experiment 3
    • Experiment 4
    • Substance (Matter)
    • Physical Nature of matter
    • Chemical properties
  • States of Matter  
    • The Solid State  
      • The Solid State of Matter
      • Characteristics of Solids
    • The Liquid State  
      • The Liquid State of Matter
      • Characteristics of Liquids
    • The Gaseous State  
      • The Gaseous State of Matter
      • Characteristics of Gases
  • Intermolecular Forces  
    • Types of Intermolecular Forces
    1. Dipole-dipole interactions
    2. Ion-dipole interactions
    3. Dipole-Induced dipole interaction
    4. London Dispersion Force
    5. Hydrogen Bonding
    • Intermolecular Forces and Thermal energy
    • Dipole - Dipole Forces  
    • Dipole-induced Dipole Forces  
    • Dispersion Forces Or London Forces  
    • Hydrogen Bond  
  • Intermolecular Forces Vs. Thermal Interactions  
  • Melting and Boiling Points  
  • The Gaseous State  
    • Measurable properties of gases
    1. Mass
    2. Volume
    3. Pressure
    4. Temperature
    5. Density
    6. Diffusion
  • The Gas Laws  
    • The Gas Laws
    • Standard variables for gas laws
    1. The volume (V)
    2. The pressure (P)
    3. The temperature (T)
    • Boyle’s Law (Pressure - Volume Relationship)  
    • Charles’ Law (Temperature - Volume Relationship)  
    • Gay Lussac’s Law (Pressure- Temperature Relationship)  
  • Laws of Chemical Combination  
    • Avogadro's Law  
  • Ideal Gas Equation  
    • Ideal behaviour of gases
    • Gases law: Boyle's law, Charles' law, Gay Lussac's law, Avogadro's law
    • Universal gas constant
    • Ideal gas equation
    • Ideal gas
    • Nature of universal gas constant 'R'
    • Values of universal gas constant 'R' in different units
    • Combined gas equation
    • Relation between density (d), molar mass (M), and pressure (P) of a gas
    • Expression for Molar mass
    • Dalton’s Law of Partial Pressures  
      • Dalton’s law of partial pressure
      • Graham's law of diffusion
  • Kinetic Molecular Theory of Gases  
    • Kinetic molecular theory of gases
    • Postulates of kinetic molecular theory
    • Kinetic gas equation
    • Calculation of kinetic energy (K.E.)
    • Molecular speeds
    • Types of speed
      a) Most probable speed (ump)
      b) Average speed (uav)
      c) Root mean square speed (ur.m.s.)
    • Relation between molecular speeds, temperature, and molecular mass
  • Behaviour of Real Gases: Deviation from Ideal Gas Behaviour  
    • Real gases
    • Reasons for deviations
    • van der Waals equation for real gases
    • Effect of pressure
    • Compressibility factor (Z)
    • Effect of temperature
    • Compressibility factor for real gases
    • Pressure-Volume isotherms of Carbon dioxide
    • Difference between Ideal gas and real gas
  • Liquefaction of Gases  
    • Liquefaction of gases
    • Critical constants
      i) Critical temperature
      ii) Critical pressure
      iii) Critical volume
    • Isotherms of CO2
  • Liquid State  
    1. Vapour Pressure
    2. Surface Tension
    3. Viscosity
    • Vapour Pressure  
    • Viscosity  
    • Surface Tension  
6 Thermodynamics
  • Introduction of Thermodynamics  
  • Thermodynamic Terms  
    • The System and the Surroundings
    • Types of the system
    1. Open System
    2. Closed system
    3. Isolated System
    4. Homogeneous system
    5. Heterogeneous system
    6. Macroscopic system
    • Macroscopic properties of the system
    1. Intensive properties
    2. Extensive properties
  • The State of the System  
    • The state of a system
    • State variables or state functions or thermodynamic parameters
    • State function: Initial and final states of the system
    • Path functions
    • Thermodynamic equilibrium and its types
    1. Chemical equilibrium
    2. Mechanical equilibrium
    3. Thermal equilibrium
    • Thermodynamic process and its types
    1. Isothermal process
    2. Adiabatic process
    3. Isobaric process
    4. Isochoric process
    5. Cyclic process
    6. Reversible process
    7. Irreversible process
    • Difference between reversible and irreversible process
  • Internal Energy and Change in Internal Energy  
    • Internal energy (U)
    • Characteristics of internal energy
    • Change in internal energy (ΔU)
    • Heat (q) and work (w)
    • Units of heat and work
    • Sign conventions for heat and work
    • Zeroth law of thermodynamics
  • First Law of Thermodynamics  
    • First law of thermodynamics
    • Formulation of first law of thermodynamics
    • First law of thermodynamics for various processes
    1. Isothermal process
    2. Adiabatic process
    3. Isochoric process
    4. Isobaric process
    • Justification
    • Mathematical expression
    • Some useful conclusions are drawn from the law
    • Limitations
    • Expressions for the work done by an ideal gas under different conditions
  • Enthalpy (H)  
    • Enthalpy
    • Relationship between ∆H and ∆U for chemical reactions
    • Work done in chemical reaction
  • Thermodynamics Applications  
    • Enthalpy, H - Heat Capacity  
    • Enthalpy, H - The Relationship Between Cp and Cv for an Ideal Gas  
  • Measurement of ∆U and ∆H Calorimetry - ∆U Measurements  
  • Measurement of ∆U and ∆H Calorimetry - ∆H Measurements  
  • Enthalpies for Different Types of Reactions  
    • Bond Enthalpy  
      • Bond dissociation enthalpy
      • Diatomic Molecules
      • Polyatomic Molecules
      • Mean bond enthalpy of C - H bond
    • Standard Enthalpy of Combustion  
    • Enthalpy of Atomization  
    • Enthalpy of Solution  
    • Lattice Enthalpy  
      • Born-Haber Cycle
      • Enthalpy of ionization
    • Enthalpy of Dilution  
    • Enthalpy of neutralization  
  • Enthalpy Change, ∆_rH of a Reaction - Reaction Enthalpy  
    • Standard Enthalpy of Formation  
    • Standard Enthalpy of Reactions  
    • Enthalpy Changes During Phase Transformations  
      • Enthalpy of fusion
      • Enthalpy of vaporization
      • Enthalpy of sublimation
  • Chemical Thermodynamics and Energetic  
    • Hess’ Law of Constant Heat Summation  
      • Hess's law
      • Experimental verification of Hess's law
      • Applications of Hess's law
      • Born-Haber cycle and Hess's law
  • Spontaneity  
    • Is Decrease in Enthalpy a Criterion for Spontaneity  
    • Entropy and Spontaneity  
    • Gibbs Energy and Spontaneity  
  • Gibbs Energy Change and Equilibrium  
    • Relation between standard Gibbs energy change and equilibrium constant
  • Second Law of Thermodynamics  
    • Clausius' Statement
    • Kelvin Planck's Statement
    • Entropy
  • Third Law of Thermodynamics  
7 Equilibrium
  • Chemical Reaction  
    • Introduction
    • Types of Chemical Reaction
    • Experiment
  • Types of Chemical Change or Chemical Reaction  
  • Concept of Equilibrium  
    • Equilibrium
    • Equilibrium state
    • Equilibrium mixture
    • Dynamic equilibrium
    • Chemical equilibrium
    • Ionic equilibrium
  • Equilibrium in Physical Processes  
    1. Liquid - Vapour equilibrium 
    2. Solid - liquid equilibrium
    3. Solid - vapour equilibrium
    • Solid-liquid Equilibrium  
    • Liquid-vapour Equilibrium  
    • Solid - Vapour Equilibrium  
    • Equilibrium Involving Dissolution of Solid in Liquids  
    • Equilibrium Involving Dissolution of Gases in Liquids  
      • Henry's law
  • Introduction of Chemical Equilibrium  
    • Chemical equilibrium
    • Two types of chemical equilibrium
      1) Homogeneous equilibrium
      2) Heterogeneous equilibrium
    • Characteristics of equilibria involving chemical processes
    • Graphical representation of chemical equilibrium
  • Equilibrium in Chemical Processes - Dynamic Equilibrium  
  • Law of Chemical Equilibrium and Equilibrium Constant  
    • Law of mass action
    • Law of chemical equilibrium
    • Characteristics of the equilibrium constant
    • Effect of temperature on equilibrium constant
    • Types of equilibrium constant
    • Relation between Kp and Kc
    • Unit of equilibrium constant
  • Applications of Equilibrium Constants  
    • Prediction of the direction of the reaction
    • To know the extent of reaction
    • To calculate equilibrium concentrations
    • Link between chemical equilibrium and chemical kinetics
    • Predicting the Extent of a Reaction  
    • Predicting the Direction of the Reaction  
    • Calculating Equilibrium Concentrations  
  • Relationship Between Equilibrium Constant K, Reaction Quotient Q and Gibbs Energy G  
    • Relationship between equilibrium constant, reaction quotient and change in Gibbs energy
  • Factors affecting equilibrium: Le Chatelier’s principle  
    • Application of Le-Chatelier's principle
    1. Applications to the chemical equilibrium
    2. Applications to the physical equilibrium
      a) Melting of ice (Ice-water system)
      b) Melting of sulphur
      c) Boiling of water (water-water vapour system)
      d) Solubility of salts
    • Change of Concentration  
      • Effect of change in concentration
    • Change of Temperature  
      • Effect of change in temperature
    • Change of Pressure  
      • Effect of change in pressure
    • Effect of change in volume  
    • Effect of Catalyst  
    • Addition of Inert Gas  
      • Effect of addition of inert gas
      1. Addition of an inert gas at constant volume
      2. Addition of an inert gas at constant pressure
  • Ionic Equilibrium in Solution  
    • Ionic equilibrium
    • Water-soluble compounds
    • Degree of ionization
    • Factors affecting degree of ionization
    • Weak and strong electrolytes
  • Concept of Acid, Base, and Salt  
    • Introduction
    • Acid
    • Base
    • Salt
  • Acids  
    • Definition
    • Introduction of Acid
    • Types of acid based on the source
    • Types of acid based on the presence of oxygen
    • Types of acid based on the strength of the acid
    • Types of acid based on its concentration
    • Types of acid based on the basicity of the acid
    • Arrhenius, Bronsted-lowry and Lewis Concept of Acids and Bases  
      • Arrhenius Concept of Acids and Bases
      • The Brönsted-Lowry Acids and Bases
      • Lewis Acids and Bases
  • Ionization of Acids and Bases  
    • Dissociation constant of weak acids and weak bases
    • Ostwald's dilution law
    • Ostwald's Dilution Law  
    • Ionization Constants of Weak Acids  
      • Degree of ionization
    • Ionization of Weak Bases  
    • Di- and Polybasic Acids and Di- and Polyacidic Bases  
      • Ionization of polybasic acids
    • The Ionization Constant of Water and Its Ionic Product  
      • Ionic product of water (Kw)
      • Value of Kw
    • Hydrolysis of Salts and the Ph of Their Solutions  
      • Hydrolysis of salt
      • Hydrolysis constant
      • Degree of hydrolysis (h)
      • Types of salts and their hydrolysis
  • Relative Strength of Acids and Bases  
    • Relative strength of inorganic acids
    1. Hydrides
    2. Oxyacids
    3. Relative strength of organic acids
    4. Relative strength of inorganic bases
    5. Relative strength of organic bases
  • The pH Scale  
    • pH of a solution
    • pH scale
    • Relationship between pH and pOH
    • Approximate pH values of some substances
    • Acidity, basicity, and neutrality of aqueous solutions
    • pK value
    • Measurement of pH of a solution
    • Indicators
    • Titration curves
  • Buffer Solutions  
    • Types of buffer solutions
    • Buffer action
    • Buffer capacity and buffer index
    • Henderson - Hasselbalch equation
    • Properties of buffer solution
    • Applications of buffer solution
    1. In biochemical system
    2. Agriculture
    3. Industry
    4. Medicine
    5. Analytical chemistry
  • Concept of Solubility Equilibria of Sparingly Soluble Salts  
    • Solubility Product Constant
    • Comparison of solubility product and ionic product
    • Different expressions for solubility product
    • Common Ion Effect on Solubility of Ionic Salts
    • Applications of solubility product
    • Common ion effect
    • Solution of weak acid and its salt
    • Solution of weak base and its salt
    • Common ion effect and solubility of a sparingly soluble salt
    • Applications of common ion effect
8 Redox Reactions
  • Redox Reaction  
    • Redox reactions
    • Half reactions
  • Classical Idea of Redox Reactions - Oxidation and Reduction Reactions  
    • Oxidation
    • Reduction
    • Oxidation and reduction in terms of electron transfer
    • Oxidizing agent
    • Reducing agent
  • Redox Reactions in Terms of Electron Transfer Reactions - Introduction  
  • Redox Reactions in Terms of Electron Transfer Reactions - Competitive Electron Transfer Reactions  
    • Metal activity series or electrochemical series
  • Oxidation Number - Introduction  
    • Oxidation number
    • Rules to assign oxidation number or oxidation states to an atom
    • Paradox of fractional oxidation number
    • Stock notations
  • Oxidation Number  
    • Types of Redox Reactions  
      • Types of Redox Reactions
      1. Combination reactions
      2. Decomposition reactions
      3. Displacement reactions
        a) Metal displacement
        b) Non-metal displacement
      4. Disproportionation reactions
    • Redox Reactions as the Basis for Titrations  
      • Oxidation number in redox reactions
    • Limitations of Concept of Oxidation Number  
  • Balancing Redox Reactions in Terms of Loss and Gain of Electrons  
    • Oxidation number method
    • Ion electron method (Half reaction method)
  • Redox Reactions and Electrode Processes  
    • Direct redox reactions
    • Daniel cell
    • Standard electrode potential
9 Hydrogen
  • Position of Hydrogen in the Periodic Table  
    • Hydrogen
    • Position of hydrogen in the periodic table
  • Dihydrogen  
    • Occurrence of dihydrogen
    • Isotopes of Hydrogen
    • Physical constants of H2, D2, and T2
  • Preparation of Dihydrogen  
    • Preparation of Dihydrogen
    • By the action of water with metals
    • By the action of water on alkali and alkaline earth metal hydrides
    • By the reaction of metals like Zn, Sn, and Al with alkalies (NaOH or KOH)
    • By the action of metals with acids
    • By the electrolysis of acidified water
    • Laboratory method
    • Preparation of pure hydrogen
    • Commercial Production of Dihydrogen
      1) From hydrocarbon or coal
      2) Bosch process
      3) Lane's process
      4) By electrolysis of water
  • Properties and Uses of Dihydrogen  
    • Physical Properties
    • Physical constants of atomic and molecular properties
    • Chemical Properties
    1. Reaction with metals
    2. Reaction with non-metals
    3. Reaction with metal ions and metal oxides
    4. Reaction with organic compounds
    • Uses of Dihydrogen
  • Hydrides  
    • Hydrides
    • Classification of hydrides
    1. Saline or ionic hydrides
    2. Molecular or covalent hydrides
      a. Electron-rich molecular hydrides
      b. Electron-precise molecular hydrides
      c. Electron-deficient molecular hydrides
    3. Metallic or non-stoichiometric (or interstitial) hydrides
  • Water  
    • Structure of Water  
    • Structure of Ice  
  • Physical Properties of Water  
    • Physical Properties of Water:
    1. Nature
    2. Boiling point
    3. The freezing point of water or melting point of ice
    4. Density
    5. Anomalous expansion of water
    6. Latent heat of fusion of ice
    7. Latent heat of vaporization of water
    8. Specific heat capacity
  • Chemical Properties of Water  
    • Chemical properties
    1. Dissociation of water
    2. Amphoteric nature
    3. Oxidising and reducing nature
    4. Hydrolytic reactions
    5. Formation of hydrates with metal salts
  • Classification of water: Soft and Hard Water  
    • Soft and Hard water
    • Types of Hard water
    1. Temporary Hardness
    2. Permanent Hardness
  • Causes of Hardness  
  • Removal of Hardness of Water  
    • Softening of water
    1. Removal of temporary hardness
      a) By boiling
      b) Clark's method
    2. Removal of permanent hardness
      a) By washing soda method
      b) lon-exchange/Permutit method
      c) Calgon method
      d) Synthetic resins method
      ⇒ Ion exchange resins are of two types
      i) Cation exchange resins
      ii) Anion exchange resins
    • Degree of hardness of water
  • Heavy Water  
    • Heavy water (D2O)
    • Preparation
    • Properties of heavy water
    • Reactions
    • Uses of heavy water
  • Preparation of Hydrogen Peroxide  
    • Hydrogen peroxide (H2O2)
    • Preparation of hydrogen peroxide (H2O2)
    1. Merck's. process (Laboratory method)
    2. By the action of sulphuric acid or phosphoric acid on hydrated barium peroxide BaO2.8H2O
    3. Industrial method
    4. By redox process
    • Preparation of Deuterium
    • Electrolysis of heavy water
    • Preparation of Tritium
  • Structure of Hydrogen Peroxide  
  • Physical Properties of Hydrogen Peroxide  
  • Chemical Properties of Hydrogen Peroxide  
    • Chemical properties of H2O2
    1. Decomposition
    2. Oxidizing and reducing nature
    3. Oxidizing character
    4. Reducing character
    5. Bleaching action
    6. Storage of H2O2
  • Uses of Hydrogen Peroxide  
  • Dihydrogen as a Fuel  
10 s-block Elements (Alkali and Alkaline Earth Metals)
  • Introduction of s-block elements  
  • Group 1 Elements - Alkali Metals  
    • Electronic configuration of group 1 elements
    • Occurrence of group 1 elements
    • Atomic and ionic radii of group 1 elements
    • Ionization Enthalpy
    • Electropositive character
    • Electronegativity
    • Hydration Enthalpy
    • Anomalous properties
    • Physical properties of group 1 elements
    1. Nature and appearance
    2. Density
    3. Conductivity
    4. Melting and boiling points
    5. Photoelectric effect
    6. Characteristic flame colour
    7. Atomic and physical properties of group 1 elements
    • Chemical Properties - Reactivity towards air, water, dihydrogen, halogens, Reducing nature, Solutions in liquid ammonia
    • Uses of alkali metals: lithium, sodium, potassium
  • General Characteristics of the Compounds of the Alkali Metals  
    • Oxides and hydroxides
    • Halides
    • Salts of Oxo-Acids
  • Anomalous Properties of Lithium  
    • Points of Difference between Lithium and other Alkali Metals
    • Anomalous behaviour of lithium
    • Lithium differs from other alkali metals
    • Diagonal relationship of Li with Mg
    • Similarities between Li and Mg
  • Some Important Compounds of Sodium  
    • Sodium Carbonate (Washing Soda), Na2CO10H2O
    • Sodium Chloride, NaCl
    • Sodium Hydroxide (Caustic Soda), NaOH
    • Sodium Hydrogencarbonate (Baking Soda), NaHCO3
  • Biological Importance of Sodium and Potassium  
  • Group 2 Elements - Alkaline Earth Metals  
    • General characteristics of alkaline earth metals
    • Electronic configuration of group 2 elements
    • Occurrence of group 2 elements
    • Atomic and ionic radii of group 2 elements
    • Ionization enthalpy of group 2 elements
    • Electropositive character
    • Electronegativity
    • Hydration enthalpy
    • Physical properties of group 2 elements
    1. Nature and appearance
    2. Density
    3. Conductivity
    4. Melting and boiling points
    5. Characteristic flame colour
    6. Atomic and physical properties of group 2 elements
    • Chemical Properties - Reactivity towards air and water, halogens, hydrogen, Reducing nature, Covalent and ionic character, Solubility.
    • Distinctive behavior of beryllium 
    • Solutions in liquid ammonia
    • Reducing nature
    • Reactivity towards acids
    • Uses: beryllium, magnesium, calcium, barium, radium
  • General Characteristics of the Compounds of the Alkaline Earth Metals  
    • General characteristics of some compounds of the alkaline earth metals
    1. Oxides and Hydroxides
    2. Halides - Structure of BeCl2
    3. Salts of Oxoacids
    • Carbonates of group 2 elements
    • Sulphates of group 2 elements
    • Nitrates of group 2 elements
  • Anomalous Behaviour of Beryllium  
    • Anomalous behaviour of beryllium
    • Be differs from other alkaline earth metals
    • Diagonal Relationship between Beryllium and Aluminium
    • Reasons for diagonal relationship
    • Similarities between Be and Al
  • Some Important Compounds of Calcium  
    • Calcium oxide or Quick Lime (CaO)
    • Uses of lime
    • Calcium Hydroxide (Slaked lime), Ca(OH)2
    • Uses of slaked lime
    • Calcium Carbonate (CaCO3) or limestone
    • Uses of limestone
    • Calcium Sulphate (Plaster of Paris), CaSO4.½ H2O
    • Uses of plaster of Paris
    • Uses of cement
  • Biological Importance of Magnesium and Calcium  
    • Role of Mg in biological system
    • Role of Ca in biological system
11 Some p-Block elements
  • Introduction to p-block Elements  
    • General introduction of p-block elements
    • Electronic configuration of p-block elements
    • General characteristics of p-block elements
    1. Oxidation states
    2. Metallic and nonmetallic character
    3. Variation in physical properties
    4. Difference in behaviour of first element of each group
  • Group 13 Elements - The Boron Family  
    • Occurrence,
    • Electronic Configuration,
    • Atomic and Ionic Radii,
    • Ionisation Enthalpy,
    • Electropositivity or metallic character,
    • Electronegativity,
    • Atomic and physical properties of group 13 elements,
    • Physical Properties and Chemical Properties,
    • Trends in chemical reactivity: Oxidation state.
  • Important Trends and Anomalous Properties of Boron  
  • Some Important Compounds of Boron  
    • Structure, properties, and uses of some important compounds of Boron
      (1) Borax or sodium tetraborate decahydrate (Na2B4O 7.10H2O) or Na2[B4O5(OH)4].8H2O
      (2) Boric acid or orthoboric acid (H3BO3)
      (3) Diborane (B2H6)
      (4) Boron trifluoride
  • Preparation and Properties of Aluminium  
    • Preparation of aluminium
    • Properties of aluminium
    • Reaction with acids
    • Reaction with alkalies
  • Uses of Boron and Aluminium and Their Compounds  
    • Uses of boron
    • Uses of aluminium
    • Some important alloys of aluminium
    • Important compounds of aluminium
    1. Aluminium chloride, AlCl3
    2. Potash alum K2SO4.Al2(SO4)3.24H2O
  • Group 14 Elements - The Carbon Family  
    • Electronic Configuration
    • Occurrence
    • Atomic and ionic radii
    • Covalent Radius
    • Ionization Enthalpy
    • Metallic character
    • Electronegativity
    • Physical Properties and Chemical Properties
    • Trends in chemical reactivity: oxidation states
  • Important Trends and Anomalous Behaviour of Carbon  
    • The tendency for catenation
  • Properties of Carbon  
    • Physical Properties of Carbon
    • Chemical Properties of Carbon
  • Allotropes of Carbon - Diamond  
  • Allotropes of Carbon - Graphite  
  • Allotropes of Carbon - Fullerenes  
  • Allotropes of Carbon - Uses of Carbon  
  • Some Important Compounds of Carbon and Silicon - Carbon Monoxide  
  • Some Important Compounds of Carbon and Silicon - Carbon Dioxide  
  • Some Important Compounds of Carbon and Silicon - Silicon Tetrachloride  
  • Some Important Compounds of Carbon and Silicon - Silicon Dioxide  
  • Some Important Compounds of Carbon and Silicon - Silicones  
  • Some Important Compounds of Carbon and Silicon - Silicates  
  • Some Important Compounds of Carbon and Silicon - Zeolites  
12 Organic Chemistry - Some Basic Principles and Techniques
  • Organic Chemistry  
    • Organic chemistry
    • Importance of organic chemistry
    • Characteristics of organic compounds
    1. Composition
    2. Type of linkage
    3. Catenation
    4. Isomerism
    5. Polymerization
    6. Solubility
    7. Melting and boiling point
    8. Odour
    9. Functional group
    10. Combustibility
    11. Homologous series
  • Introduction of Methods of Purification of Organic Compounds  
  • Purification of Solids  
    • Fractional Crystallization  
  • Methods of Separation  
    • Filtration Method  
    • Crystallisation Method  
    • Sublimation Method  
    • Simple Distillation Method  
      • Distillation Method
      • Experiment 1
      • Experiment 2
    • Fractional Distillation Method  
    • Distillation Under Reduced Pressure (Vacuum Distillation)  
    • Steam Distillation  
    • Solvent Extraction (Using a Separating Funnel Method)  
      • Introduction to Separation Using a Separating Funnel
      • Experiment 
    • Chromatography Method  
      • Introduction
      • Experiment 
  • Qualitative Analysis of Organic Compounds - Detection of Carbon and Hydrogen  
  • Qualitative Analysis of Organic Compounds - Detection of Other Elements  
    • Test for Nitrogen
    • Test for Sulphur
    • Test for Halogens
    • Test for Phosphorus
  • Quantitative Analysis of Carbon and Hydrogen  
  • Quantitative Analysis of Nitrogen  
    • Dumas method
    • Kjeldahl’s method
  • Quantitative Analysis of Halogens  
    • Carius method
  • Quantitative Analysis of Sulphur  
  • Quantitative Analysis of Phosphorus  
  • Quantitative Analysis of Oxygen  
  • Empirical Formula and Molecular Formula  
    • Determination of Empirical Formula from Elemental Analysis Data
    • Calculation of Molecular Formula from Empirical Formula
  • Tetravalence of Carbon - Shapes of Organic Compounds  
    • Tetravalency of carbon
    • The Shapes of Carbon Compounds
    • Some Characteristic Features of σ and π Bonds
  • Organic Compounds  
    • Complete, Condensed and Bond-line Structural Formulas  
      • Representation of organic molecules (2-D)
      1. Lewis structure/ dot structure
      2. Dash formula/ structural formula
      3. Condensed structural formula
      4. Bond-line formula
    • Three-dimensional Representation of Organic Molecules  
      • Three-dimensional representation of organic compounds
      1. Wedge and dash formula
      2. Fischer projection (Cross) formula
      3. Newman projection formula
      4. Sawhorse or andiron or perspective formula
    • Molecular Models  
      • Molecular models
      1. Framework model
      2. Ball and stick model
      3. Space-filling model
  • Classification of Organic Compounds  
    • Classification based on carbon skeleton
    • Classification based on functional group
    • Homologous Series
  • Homologous Series of Carbon Compound  
    • Homologous Series in Organic Chemistry
    • Examples of Homologous Series
  • Nomenclature of Organic Compounds  
    • Common Naming System
    • IUPAC Nomenclature
    • The IUPAC System of Nomenclature  
      • IUPAC Nomenclature: Structure and Components
      • Steps for IUPAC Nomenclature
    • IUPAC Nomenclature of Alkanes  
      • Rules for IUPAC nomenclature of saturated hydrocarbons (alkanes)
      • Rules for naming cyclic or alicyclic hydrocarbons
      • Rules for naming compounds containing double and triple bonds
      • Straight chain hydrocarbons
      • Branched-chain hydrocarbons,
      • Nomenclature of branched-chain alkanes
      • Cyclic Compounds
    • Nomenclature of Organic Compounds Having Functional Group(s)  
    • Nomenclature of Substituted Benzene Compounds  
  • Isomerism  
    • Structural isomerism
    1. Chain isomerism
    2. Position isomerism
    3. Functional group isomerism
    4. Metamerism
    5. Tautomerism
    • Stereoisomerism
    • Geometrical isomerism/Cis-trans isomerism
    • Optical isomerism: enantiomers, dextrorotatory, laevorotatory, diastereomers, racemic mixture/ racemate, resolution.
  • Bond Fission and Types of Organic Reactions  
    • Fundamental concepts in organic reaction mechanism
    • Bond fission
    • Types of fission
      1) Homolytic bond fission/Homolysis
      2) Heterolytic bond fission/Heterolysis
    • Reaction intermediates
    • Relative stability order of reaction intermediates
    1. Free radicals
    2. Carbocation
    3. Carbanion
    • Differences between carbocation and carbanion
  • Fundamental Concepts in Organic Reaction Mechanism  
    • Electron Displacement Effects in Covalent Bonds  
      • Electronic displacement in covalent bond
      • Significance of electronic displacement
    • Inductive Effect  
      • Inductive effect
      • Types of inductive effect
      1. Negative inductive effect
      2. Positive inductive effect
    • Resonance Effect  
      • Resonance or mesomerism
      • Features of resonating structures
      • Resonance effect or Mesomeric effect
      • Movement or flow of electrons
      • Types of resonance effect
      1. Positive Resonance Effect (+R effect)
      2. Negative Resonance Effect (- R effect)
    • Electromeric Effect (E Effect)  
      • Electromeric effect
      • Types of electromeric effect
      1. +E effect
      2. -E effect
      • Direction of the shift of electron pairs
    • Hyperconjugation  
      • Hyperconjugation
      • Hyperconjugation effect or Baker and Nathan effect
      • No-bond resonance
      • Structural requirements for hyperconjugation
      • Hyperconjugation and carbocation
    • Fission of a Covalent Bond  
      • Heterolytic cleavage
      • Homolytic cleavage
      • Free radicals
      • Carbocations, and carbanions
      • Stability of carbocations and free radicals
    • Nucleophiles and Electrophiles  
    • Types of Organic Reactions and Mechanisms  
      • Substitution reactions
      • Addition reactions
      • Elimination reactions
      • Rearrangement reactions
      • Condensation reaction
      • Isomerisation reaction
13 Hydrocarbons
  • Hydrocarbons  
    • Introduction
    • Properties of Covalent Compounds
    • Saturated Hydrocarbons
    • Unsaturated Hydrocarbons
  • Classification of Hydrocarbons  
    • Classification of hydrocarbons
    1. Saturated hydrocarbons
      a) Straight chain alkanes
      b) Branched-chain alkanes
    2. Unsaturated hydrocarbons
      a) Alkenes
      b) Alkynes
    3. Aromatic hydrocarbons
      a) Benzenoids
      b) Non-benzenoids
  • Alkanes - Introduction  
    • Alkanes (Paraffins)
    • General formula
    • Occurrence
    • Structure of alkanes
    • Classification
    • Uses of alkanes
  • Alkanes  
    • Nomenclature and Isomerism  
      • Nomenclature of alkanes
      • Common system
      • IUPAC system
      • IUPAC names of some straight-chain alkanes
      • IUPAC names of some alkyl groups
      • Common and IUPAC names of some alkanes
      • IUP AC naming of cycloalkanes
      • Isomerism of alkanes
    • Conformations (Ethane)  
      • Conformations
      • Conformations of ethane: Eclipsed and Staggered conformation 
      • Representation: Sawhorse and Newman projections
      • Relative stabilities of the conformations of ethane
    • Preparation of Alkanes from Unsaturated Hydrocarbons, Alkyl Halides and Carboxylic Acids  
      • Methods of preparation of alkanes
      • From unsaturated hydrocarbons (By catalytic hydrogenation of alkenes and alkynes)
      1. From alkenes
      2. From alkynes
      • From alkyl halides (Wurtz reaction)
      • From alkyl halides (Corey-House reaction)
      • Reduction of alkyl halides
      • By the use of Grignard reagent
      • Decarboxylation reaction
      • From carboxylic acids by electrolysis (Kolbe's electrolytic method)
      • Reduction of carboxylic acids
  • Physical Properties of Alkanes  
    • Physical properties of alkanes
    1. Nature
    2. Boiling point
    3. Melting point
    4. Solubility
    5. Density
  • Chemical Properties of Alkanes  
    • Chemical properties of alkanes
    1. Substitution reactions - Halogenation, Nitration, Sulphonation
    2. Combustion of alkanes (oxidation)
    3. Controlled oxidation
    4. Isomerisation
    5. Aromatization
    6. Reaction with steam
    7. Pyrolysis
  • Alkenes - Introduction  
    • Alkenes
    • General formula
    • Occurrence
  • Alkenes  
    • Isomerism in alkenes
    • Preparation of alkenes
    • Physical properties of alkenes
    • Chemical properties of alkenes
    • Uses of alkenes
    • Nomenclature  
      • Nomenclature of alkenes
      • Common names
      • IUPAC nomenclature
      • The common and IUPAC names of some alkenes
    • Structure of Double Bond (Ethene)  
      • Electronic structure of ethene or ethylene
    • Preparation of Alkenes from Alkynes, Alkyl Halides, Vicinal Dihalides and Alcohols by Acidic Dehydration  
      • Methods of preparation of alkenes
      1. From alkyl halides (dehydrohalogenation reaction)
      2. From dihalogen derivatives (dehalogenation of vicinal dihalide)
      3. From alkynes (catalytic hydrogenation)
      4. From alcohols (dehydration reaction)
      5. From potassium salts of dicarboxylic acids (Kolbe's reaction)
  • Isomerism  
    • Structural isomerism
    1. Chain isomerism
    2. Position isomerism
    3. Functional group isomerism
    4. Metamerism
    5. Tautomerism
    • Stereoisomerism
    • Geometrical isomerism/Cis-trans isomerism
    • Optical isomerism: enantiomers, dextrorotatory, laevorotatory, diastereomers, racemic mixture/ racemate, resolution.
  • Physical Properties of Alkenes  
  • Chemical Properties of Alkenes  
    • Chemical properties of alkenes
    1. Addition reactions: Addition of dihydrogen, Addition of hydrogen (catalytic hydrogenation), Addition of halogens, Addition of hydrogen halides, Addition reaction of HBr to symmetrical alkenes, Markovnikov's rule, Anti-Markovnikov's rule or Peroxide effect, Oxymercuration demercuration (Indirect hydration of alkenes), Addition of sulphuric acid, Addition of water, Oxidation, Addition of ozone (ozonolysis)
    2. Mechanism of electrophilic reaction
    3. Oxidation reactions: Combustion, Hydroboration-oxidation, Oxidation with potassium permanganate (alkaline), Oxidation with acidic or hot potassium permanganate or potassium dichromate, Catalytic oxidation/ Epoxidation
    4. Polymerization reaction
    5. Uses of alkenes
  • Alkynes - Introduction  
  • Alkynes  
    • Isomerism in alkynes
    • Preparation of alkynes
    • Physical properties of alkynes
    • Chemical properties of alkynes
    • Uses of acetylene
    • Nomenclature and Isomerism  
      • Nomenclature of alkynes
      • Common system
      • Derived system
      • IUPAC system
      • Common names and IUPAC names of some of the alkynes
      • Isomerism in alkynes
      • Chain isomerism
      • Position isomerism
      • Functional isomerism
      • Ring chain isomerism
    • Structure of Triple Bond  
    • Preparation of Alkynes from Calcium Carbide and Vicinal Dihalides  
      • Methods of preparation of alkynes
      1. Action of water on calcium carbide: Industrial preparation of acetylene
      2. By dehydrohalogenation of vicinal dihalides or geminal dihalides: From vicinal dihalide, From geminal dihalide, Double dehydrohalogenation
      3. By the action of zinc on tetrahalogen derivatives of alkanes (dehalogenation)
      4. Kolbe's electrolysis reaction
      5. By dehalogenation of haloform
      6. Berthelot's synthesis
      7. Synthesis of higher alkynes
  • Physical Properties of Alkynes  
    • Physical properties of alkynes
    1. Nature
    2. Solubility
    3. Melting point and Boiling point
  • Chemical Properties of Alkynes  
    • Acidic character of alkyne
    • Formation of alkali metal ethynides (acetylides)
    • Formation of heavy metal ethynides (acetylides)
    • Formation of alkynyl Grignard reagents
    • Addition reactions
    • Addition of dihydrogen
    • Addition of hydrogen (catalytic hydrogenation or reduction of alkynes)
    • Addition of halogens (anti-addition): Action of chlorine, Action of bromine
    • Addition of halogen acids (hydrogen halides)
    • Addition of water (acid-catalyzed hydration of alkynes)
    • Oxidation reactions
    • Combustion
    • Oxidation with alkaline potassium permanganate (test for unsaturation)
    • Oxidative hydroboration
    • Ozonolysis reactions
    • Polymerization reactions: Linear and Cyclic polymerization
  • Aromatic Hydrocarbons  
    • Benzene
    • Structure of benzene
    • Aromatic character (Huckel Rule)
    • Preparation of aromatic compounds
    • Physical properties of benzene
    • Chemical properties of benzene
    • Directive influence of a functional group in monosubstituted benzene
    • Carcinogenicity and Toxicity
    • Nomenclature and Isomerism  
      • Nomenclature of Aromatic hydrocarbons: IUPAC nomenclature
      • Isomerism in Aromatic hydrocarbons
    • Structure of Benzene  
      • Benzene
      • Structure of benzene
      1. Molecular formula
      2. Cyclic structure
      3. Evidence for cyclic structure
      • Resonance and stability of benzene
    • Aromaticity (Huckel Rule)  
      • Aromaticity: 
      • Huckel rule and its applications
      • Antiaromaticity
    • Preparation of Benzene  
      • Preparation of Benzene
      1. From acetylene/ethyne (trimerization)
      2. Decarboxylation of aromatic compounds (Laboratory method)
      3. Reduction of phenol
    • Electrophilic Substitution Reactions  
      • Electrophilic substitution reactions
      1. Nitration
      2. Halogenation
      3. Sulphonation
      4. Friedel-Crafts alkylation reaction
      5. Friedel-Crafts acylation reaction
    • Mechanism of Electrophilic Substitution Reactions  
      • Mechanism of electrophilic substitution reactions
      1. Generation of the eletrophile
      2. Formation of carbocation intermediate
      3. Removal of proton from the carbocation intermediate
      • Addition reactions - Combustion
    • Directive Influence of a Functional Group in Monosubstituted Benzene  
      • Directive effect
      • Activity effects
      • Ortho, para, and meta directing groups
  • Physical Properties of Aromatic Hydrocarbons  
  • Chemical Properties of Aromatic Hydrocarbons  
  • Carcinogenicity and Toxicity  
14 Environmental Chemistry
  • Introduction of Environmental Chemistry  
    • Environment
    • Elements of environment
      1) Non-living or Physical
      2) Living or Biological
    • Environmental chemistry
    • Goals of environmental chemistry
  • Environmental Pollution - Introduction  
    • Bio-degradable pollutants
    • Non bio-degradable pollutants 
    • Water Pollution
    • Air Pollution
    • Noise Pollution
  • Atmospheric Pollution  
    • Tropospheric Pollution - Gaseous Air Pollutants  
      • Air pollution
      • Types of Air pollution
        1) Tropospheric pollution
        2) Stratospheric pollution
      • Sources of air pollution
      • Types of air pollutants
        1) Primary air pollutants
        2) Secondary air pollutants
      • Major atmospheric pollutants
        1) Oxides of carbon: Carbon monoxide (CO), Carbon dioxide (CO2), Sulphur dioxide (SO2), Nitrogen oxides (NOx), Hydrocarbons
      • Global Warming and Greenhouse Effect
      • Acid rain
    • Tropospheric Pollution - Particulate Pollutants  
      • Particulate pollutants
      • Source
      1. Smoke
      2. Dust
      3. Fumes
      4. Mists
      5. Effects of air pollution
      • Smog
      • Effects of photochemical smog
      • Acid rain
      • Ozone
      • Greenhouse effect and global warming
    • Stratospheric Pollution  
      • Stratospheric Pollution
      • Formation and Breakdown of Ozone
      • The Ozone Hole
      • Effects of Depletion of the Ozone Layer
  • Smog  
    • Smog
    • Types of smog
    1. Classical or London smog
    2. Photochemical smog or Los Angeles smog
    • Effects of smog
    • Control of photochemical smog
  • Acid Rain  
    • Acid rain
    • Formation of acid rain
    • Harmful effects of acid rain
    1. Effect on vegetation
    2. Effect on aquatic life
    3. Effect on fertility of the soil
    4. Effect on buildings and monuments
    • Effect on human health
    • Effect on ecological balances
  • Greenhouse Effect and Global Warming  
    • Effects of Global Warming
    • Sources of Green House Gases Emission (Natural and Anthropogenic)
    • Strategies to deal with Global Warming
    • Ozone depletion
    • Effects of Ozone depletion
  • Industrial Waste  
    • Types of industrial waste
    1. Biodegradable wastes
    2. Non-biodegradable wastes
  • Water Pollution and Its Causes  
    • Water Pollution
    • Types of Water Pollutants
    • Causes of Water Pollution
    • Reasons of Water Pollution
    • International Standards for Drinking Water  
      • Fluoride, Lead, Sulphate, Nitrate, Other metals
  • Soil Pollution - Pesticides, Herbicides  
    • Soil pollution
    • Sources of soil pollution 
    1. Dumping of non-biodegradable waste
    2. Acid rain
    3. Radioactive substances
    4. Pesticides
    5. Herbicides
    6. Artificial fertilizers
    7. Pesticides
    8. Fungicides
    • Biomagnification
  • Strategies to Control Environmental Pollution  
    • Strategy to control environmental pollution
    1. Incineration
    2. Digestion
    3. Collection and disposal
    4. Sewage treatment
    5. Other strategies
  • Green Chemistry - Introduction  
  • Green Chemistry in Day-to-day Life  
    • Dry Cleaning of Clothes
    • Bleaching of Paper
    • Synthesis of Chemicals
    • ‘Green Solution’ to Clean Turbid Water

Medical Entrance Exam Chemistry Syllabus for Chapter 2: Class 12

15 Solid State
  • States of Matter  
  • General Characteristics of Solid State  
  • Amorphous and Crystalline Solids  
    • Classification of solids
    1. Crystalline solids
    2. Amorphous solids
    • The distinction between Crystalline and Amorphous Solids
    • Isomorphous solids and polymorphous solids
  • Classification of Crystalline Solids  
    • Classification of crystalline solids
    1. Molecular solids:
      a) Polar molecular solids
      b) Non-polar molecular solids
      c) Hydrogen-bonded molecular solids
    2. Ionic Solids
    3. Metallic solids
    4. Covalent or Network Solids
    • Structure and properties of diamond, graphite, and fullerene
  • Bragg's Law and Its Applications  
  • Crystal Lattices and Unit Cells  
    • Unit cell
    • Crystal lattice or space lattice
    • Two-dimensional lattice and unit cell
    • Three-dimensional lattice and unit cell
  • Crystal Lattices and Unit Cells - Primitive and Centred Unit Cells  
    • Primitive Unit Cells
    • Centred Unit Cells
      1) Body-Centred Unit Cells
      2) Face-Centred Unit Cells
      3) End-Centred Unit Cells
    • Bravais lattices
  • Number of Atoms in a Unit Cell  
    • Primitive Cubic Unit Cell
    • Body-Centred Cubic Unit Cell
    • Face-Centred Cubic Unit Cell
  • Close Packed Structures of Solids  
    • Packing in solids
    • Close Packing in One Dimension
      1) Coordination number
    • Close Packing in Two Dimensions
      1) Square close packing in two dimensions
      2) Hexagonal close packing of spheres in two dimensions
    • Close Packing in Three Dimensions
    • Three-dimensional close-packed structure
    • Stage I - Linear packing in one dimension
    • Stage II - Planar packing in two dimensions
      1) AAAA type, square close-packed structure
      2) ABAB type, hexagonal close-packed structure
    • Stage III - Close packing in three dimensions
      1) AAAA type, simple cubic structure
      2) ABAB type, hexagonal close-packed structure
      3) ABCABC type, cubic close-packed structure
    • Number of voids per atom in hcp and ccp structures
    • Locating tetrahedral and octahedral voids: locating tetrahedral voids, Locating octahedral voids
  • Close Packed Structures - Formula of a Compound and Number of Voids Filled  
  • Packing Efficiency  
    • Packing Efficiency in Simple Cubic Lattice  
    • Efficiency of Packing in Body-centred Cubic Structures  
    • Packing Efficiency in hcp and ccp Structures  
  • Calculations Involving Unit Cell Dimensions  
    • Calculation of density of unit cell
  • Imperfections in Solids - Introduction  

    point defects and line defects

  • Imperfections in Solids  
    • Types of Point Defects - Stoichiometric Defects  

      Vacancy Defect, Interstitial Defect, Frenkel Defect, interstitial defect, dislocation defect, Schottky Defect

    • Types of Point Defects - Non-stoichiometric Defects  

      Metal Excess Defect, Metal Deficiency Defect

    • Types of Point Defects - Impurity Defects  
  • Electrical Properties - Introduction  
  • Electrical Properties  

    Electrical properties: Conductors, semiconductors (n & p types) and insulators (Band Theory), piezoelectricity and pyroelectricity.

    • Conduction of Electricity in Metals  
    • Conduction of Electricity in Semiconductors  
      • Conduction of electricity in semiconductors
      1. Intrinsic semiconductors
      2. Extrinsic semiconductors
        a) Electron rich (or donor) impurities
        b) Electron deficient (or acceptor) impurities
    • Applications of n-type and p-type Semiconductors  
  • Magnetic Properties  
    • Magnetic properties:
    1. Magnetising field
    2. Magnetic permeability
    3. Intensity of magnetisation
    4. Magnetic induction or total magnetic field
    5. Magnetic susceptibility
    • Substances can be classified into five categories:
    1. Paramagnetic
    2. Diamagnetic
    3. Ferromagnetic
    4. Antiferromagnetic
    5. Ferrimagnetic
  • Solid State  
    • Band Theory of Metals  
16 Solutions
  • Introduction of Solution  
  • Types of Solutions  
    1. Gaseous Solutions
    2. Liquid Solutions
    3. Solid Solutions
  • Expressing Concentration of Solutions  
    • Mass percentage (w/w)
    • Volume percentage (V/V)
    • Mass by volume percentage (w/V)
    • Parts per million
    • Mole fraction
    • Molarity
    • Molality
    • Standard solutions and working standards
    • Advantages of using standard solutions
  • Introduction of Solubility  
  • Solubility  
    • Factors affecting solubility
    1. Nature of solute and solvent
    2. Effect of temperature on solubility
    3. Effect of pressure on solubility
    • Solubility of a Solid in a Liquid  
      • Effect of temperature
      • Effect of pressure
    • Solubility of a Gas in a Liquid  
      • Factors affecting the solubility of gases in liquids
        1) Nature of gas (solute) and liquid (solvent)
        2) Effect of temperature
        3) Effect of pressure
      • Limitations of Henry's law
      • Applications of Henry's law
        1) In the production of carbonated beverages
        2) In scuba diving (deep-sea diving)
        3) At high altitudes
  • Solid Solutions  
    • Solid solutions
    • Types of solid solutions
    1. Substitutional solid solutions
    2. Interstitial solid solutions
  • Vapour Pressure of Liquid Solutions - Introduction  
  • Vapour Pressure of Liquid  
    • Vapour Pressure of Liquid- Liquid Solutions  
      • Raoult's Law
    • Raoult’s Law as a Special Case of Henry’s Law  
    • Vapour Pressure of Solutions of Solids in Liquids  
  • Ideal and Non-ideal Solutions  
    • Ideal Solutions
    • Non-ideal Solutions
    • Non-ideal solutions - positive deviation from Rauolt's Law
    • Non-ideal solutions - negative deviation from Rauolt's Law
    • Factors responsible for deviation from Raoult’s law
    1. Solute-solvent interactions
    2. Dissociation of solute
    3. Association of solute
    4. Temperature
    5. Pressure
    6. Concentration
  • Colligative Properties and Determination of Molar Mass - Introduction  
  • Colligative Properties and Determination of Molar Mass  
    • Relative Lowering of Vapour Pressure  
      • Relative lowering of vapour pressure
      • Determination of molar mass of solute from relative lowering of vapour pressure
    • Elevation of Boiling Point  
      • Boiling point
      • Elevation of boiling point
      • Determination of molar mass of solute from elevation of boiling point
    • Depression of Freezing Point  
      • Freezing point
      • Depression of freezing point
      • Determination of molar mass of solute from depression of freezing point
    • Osmosis and Osmotic Pressure  
      • Osmosis
      • Semi-permeable membrane
      • Osmotic pressure
      • Types of Solution: Isotonic, hypertonic, and hypotonic solutions
      • Osmotic pressure and concentration of the solution
      • Laws of Osmotic pressure
      1. van't Hoff - Boyle's law
      2. van't Hoff- Charles' law
      3. van't Hoff general solution equation
      4. van't Hoff-Avogadro's law
      • Determination of molar mass from osmotic pressure
    • Reverse Osmosis and Water Purification  
  • Abnormal Molar Masses  
    • Abnormal molecular masses
      a) Association of solute particles
      b) Dissociation of solute particles
    • Van't Hoff Factor
    • Significance of van't Hoff factor
      a) Degree of dissociation
      b) Degree of association
17 Electrochemistry
  • Introduction to Electrochemistry  
  • Redox Reaction  
    • Redox reactions
    • Half reactions
  • Electrochemical Cells  
    • Electrochemical reactions
    • Electrodes
    • Types of electrochemical cells
    1. Galvanic cell
    2. Electrolytic cells
  • Electrodes  
    • Electrodes
    • Types of electrodes
    1. Metal-metal ions electrode
    2. Metal-sparingly soluble salt electrode
    3. Gas electrode (non metal-non metal ion electrode)
    4. Redox electrode
  • Galvanic or Voltaic Cells - Introduction  
    • Galvanic or Voltaic cells
    • Reduction half-cell
    • Oxidation half-cell
    • Joining half-cells
    • Anodic oxidation
    • Cathodic reduction
    • Completion of circuit
    • Consumption of Electrodes
    • Salt bridge
    • Cell notation or representation of a galvanic cell
    • Cell electromotive force (e.m.f.)
  • Electrode Potential and Cell Potential  
    • Electrode potential
    • Cell potential or e.m.f.
    • Difference between e.m.f. and potential difference
    • Standard electrode potential
    • Dependence of cell potential on concentration (Nernst equation)
  • Galvanic Cells - Measurement of Electrode Potential  
    • Reference electrode
    • Standard Hydrogen Electrode (SHE): Construction, Electrode reactions, Application, Limitations
    • Calomel electrode: Construction, Electrode reactions, Advantages of calomel electrode
  • Electrochemical Series (Electromotive Series)  
    • Electrochemical series
    • Convention used in the construction of electrochemical series
    • Applications of electrochemical series
  • Relation Between Gibbs Energy Change and Emf of a Cell  
    • Gibbs energy change and e.m.f. of a cell
    • Standard cell potential and equilibrium constant
  • Nernst Equation - Introduction  
    • Derivation of Nernst equation
    • Applications of Nernst equation
  • Nernst Equation  
    • Equilibrium Constant from Nernst Equation  
    • Electrochemical Cell and Gibbs Energy of the Reaction  
  • Conductance of Electrolytic Solutions - Introduction  
    • Conductors
    • Difference between Electronic and Electrolytic conduction
    • Non-electrolytes
    • Factors affecting electronic or metallic conduction
    • Factors affecting electrical conductivity of electrolytic solutions
    • Electrolytic conduction (Conductance in electrolytic solutions)
  • Conductance of Electrolytic Solutions  
    • Measurement of the Conductivity of Ionic Solutions  
      • Conductivity cell
      • Cell constant
      • Determination of cell constant
      • Determination of conductivity of the solution
    • Variation of Conductivity and Molar Conductivity with Concentration  
      • Variation of conductivity with concentration
      • Molar conductivity
      • Limiting molar conductivity 
      • Variation of molar conductivity for strong electrolytes
      • Kohlrausch's law of independent migration of ions
      • Variation of molar conductivity for weak electrolytes
      • Applications of Kohlrausch's law
  • Electrolytic Cells and Electrolysis - Introduction  
    • Electrolytic cells
    • Process of electrolysis
    • Preferential Discharge Theory
    • Some Examples of Electrolysis
    • Quantitative Aspects of Electrolysis
    • Faraday's laws of electrolysis
      1) Faraday's First Law of Electrolysis
      2) Faraday's Second Law of Electrolysis
  • Applications of Electrolysis  
    • Products of Electrolysis  
  • Batteries  
    • Primary Batteries  
      • Dry cell
      • Mercury cell
    • Secondary Batteries  
      • Lead storage battery (Lead accumulators)
      • Nickel-cadmium (NICAD) cells
  • Fuel Cells  
    • Fuel cells
    • Hydrogen-oxygen fuel cell
    • Advantage and disadvantage of fuel cell
  • Corrosion of Metals  
    • Corrosion
    • Experiment
    • Rusting Process and Corrosion Effect
    • Prevention of Corrosion  
      • Coating with a Protective Layer
      • Metal Plating (Galvanization, Tinning, Electroplating)
      • Anodization (Formation of Oxide Layer)
      • Alloying (Corrosion-Resistant Alloys)
18 Chemical Kinetics
  • Chemical Kinetics  
  • Rate of Chemical Reaction  
  • Factors Influencing Rate of a Reaction  
    • Various factors influencing the rate of a chemical reaction
    1. Concentration of reactants
    2. Pressure of gaseous reactants
    3. Temperature of the system
    4. Presence of a catalyst
    • Dependence of Rate on Concentration, temperature, catalyst
    • Rate Expression and Rate Constant/ Rate law and Specific Rate Constant
    • Order of a Reaction
    • Molecularity of a Reaction
  • Dependence of Rate on Reactant Concentrations: Rate Law and Rate Constant  
    • Rate law
    • Applications of the rate law
    • Rate constant
    • Difference between rate of reaction and rate constant
  • Order of a Reaction  
    • Order of a reaction
    • Reactions of different orders
    1. Zero order reactions
    2. First order reactions
    3. Second order reactions
    4. Third order reactions
    5. Reactions of fractional order
    • Determination of rate law using initial rates
  • Mechanism of the Reaction  
    • Units of Rate Constant  
  • Molecularity of Elementary Reactions  
    • Elementary reaction
    • Complex reactions
    • Molecularity of reaction
    • Order and molecularity of elementary reactions
    • Rate determining step
    • Reaction intermediate
    • Differences between order and molecularity
  • Integrated Rate Equations  
  • Zero Order Reactions  
    • Integrated rate law for zero order reactions
    • Units of rate constant of zero order reactions
    • Graphical representation of zero order reaction
    • Examples of zero order reactions
  • First Order Reactions  
    • Integrated rate law for first order reactions
    • Units of rate constant for the first order reaction
    • Graphical representation of first order reaction
    • Examples of first order reactions
    • Various forms of the integrated rate law for the first order reactions
  • Half Life Period of a Reaction  
    • Half life of the first order reactions (`t _(1/2)`)
    • Half life and rate constant of the first order reaction
    • Graphical representation of Half life period of first order reaction
    • Half life of zero order reactions
  • Pseudo First Order Reaction  
  • Temperature Dependence of the Rate of a Reaction  
    • Activation energy
    • Arrhenius equation
    • Most probable kinetic energy
    • Effect of Catalyst
  • Collision Theory of Chemical Reactions  
    • Collision between reactant molecules
    • Energy requirement - Activation energy
    • Orientation of reactant molecules
  • Effect of Catalyst on the Rate of Reaction  
19 Surface Chemistry
  • Surface Chemistry  
    • Surface chemistry
    • Surface or interface
  • Introduction of Adsorption  
  • Distinction Between Adsorption and Absorption  
  • Adsorption  
    • Unbalanced forces
    • Why does adsorption occur?
    • Desorption
    • Sorption
    • Mechanism of Adsorption  
    • Adsorption from Solution Phase  
  • Types of Adsorption  
    • Types of adsorption
    1. Physical adsorption (Physisorption or van der Waals' adsorption)
    2. Chemical adsorption (Chemisorption or activated adsorption)
    • Difference between physisorption and chemisorption
  • Adsorption Isotherms (Freundlich and Langmuir Adsorption Isotherm)  
    • Adsorption isotherm
    • Freundlich adsorption isotherm
    • Langmuir adsorption isotherm
  • Applications of Adsorption  
  • Factors Affecting Adsorption of Gases on Solids  
    • Factors affecting adsorption of gases on solids
    1. Nature of the gas (adsorbate)
    2. Nature of adsorbent
    3. Surface area of the adsorbent
    4. Temperature of the surface
    5. Pressure of gas
  • Catalysis  
    • Catalyst
    • Catalysis and Theories of Catalysis
    • Homogeneous Catalysis
    • Heterogeneous Catalysis
    • Inhibitors
    • Homogeneous and Heterogeneous Catalysis  
      • Classification of catalysis: homogeneous and heterogeneous catalysis
      • Examples of homogeneous catalysis
      • Examples of heterogeneous catalysis
    • Shape-selective Catalysis by Zeolites  
    • Enzyme Catalysis  
      • Enzymes
      • Characteristics of enzymes
      • Mechanism of enzyme catalysis
      • Examples of enzyme catalysed reactions
    • Catalysts in Industry  
  • Adsorption Theory of Heterogeneous Catalysis  
    • Important features of solid catalysts
    1. Catalytic activity
    2. Catalytic selectivity
    3. Shape selective catalysis by zeolites
  • Catalytic Activity and Selectivity  
    • Catalytic activity
    • Promoters
    • Poisons
    • Catalytic selectivity
    • Shape-selective catalysis
  • Colloids  
    • Examples of colloids
    • Classification of colloids
    • Preparation of Colloids
    • Purification of colloidal solution
    • Properties of colloidal dispersions
    • Methods to effect coagulation
    • Emulsions
    • Applications of colloids
    • Dispersed phase and dispersion medium
    • True solutions, colloids, and suspensions
    • Types of colloidal systems
  • Classification of Colloids  
    • Classification Based on Nature of Interaction Between Dispersed Phase and Dispersion Medium  
      • Lyophilic colloids (solvent loving or solvent attracting)
      • Lyophobic colloids (solvent hating, solvent repelling, or solvent fearing)
      • Distinction between lyophobic and lyophilic colloids
    • Classification Based on Type of Particles of the Dispersed Phase, Multimolecular, Macromolecular and Associated Colloids  
      • Multimolecular colloids,
      • Macromolecular colloids,
      • Associated colloids (Micelles),
      • Mechanism of micelle formation
      • Cleansing action of soaps
  • Preparation of Colloids  
    • Chemical methods
    • Electrical disintegration or Bredig’s Arc method
    • Peptization
  • Purification of Colloidal Solutions  
    • Dialysis
    • Electro-dialysis
    • Ultrafiltration
  • Properties of Colloidal Solutions  
    • Colligative properties
    • Tyndall effect
    • Colour
    • Brownian movement
    • Charge on colloidal particles
    • Electrophoresis
    • Coagulation of lyophilic sols
    • Coagulation or precipitation
    • Methods to effect coagulation
    • Methods to prevent coagulation of colloids (Protection of colloids)
  • Colloids Around Us  
    • Colloids in our daily life
    1. Natural phenomena
      a) Blue colour of sky and sea
      b) Fog, mist, and rain
      c) Soils
      d) Delta formation
      e) Food articles 
      f) Blood
    2. Industrial applications
      a) Electrical precipitation of smoke
      b) Purification of drinking water
      c) Colloidal medicines
      d) Photographic plates
      e) Artificial rain
      f) Rubber industry
      g) Tanning
      h) Miscellaneous
  • Emulsions  
    • Emulsion
    • Types of emulsions
      1) Oil-in-water emulsion (O/W type)
      2) Water-in-oil emulsion (W/O type)
    • Properties of emulsions
    • Deemulsification
20 General Principles and Processes of Isolation of Elements
  • General Principles and Processes of Isolation of Elements  
  • Occurrence of Metals  
    • Occurrence of metals
    • Minerals and ores
  • Metallurgy  
    • Introduction
    • Metallurgical Process
  • Types of Separation or Concentration of an Ore  
    • Pulverization
    • Concentration of an ore
    • Types of separation or concentration of an ore
    1. Hydraulic (gravity separation) method or Levigation method
    2. Magnetic separation method
    3. Froth floatation
    4. Chemical method or Leaching
    5. Wilfley table method
    • Hydraulic Washing  
    • Magnetic Separation  
    • Froth Floatation Method  
    • Leaching  
      • Leaching
      • Leaching of alumina from bauxite (Baeyer's process)
      • Leaching of the ore containing native metal (silver and gold): Mac Arthur Forest Cyanide process
  • Extraction of Crude Metal from Concentrated Ore  
    • Conversion to oxide
    1. Calcination
    2. Roasting
    • Reduction of oxide to the metal
    1. Pyrometallurgy
    2. Hydrometallurgy
    3. Electrometallurgy
  • Thermodynamic Principles of Metallurgy  
    • Ellingham diagrams
    • Significance of Ellingham diagram
    • Limitations of Ellingham diagram
    • Selection of reducing agent
  • Application of Thermodynamic Principles of Metallurgy  
    • Extraction of iron from its oxides,
    • Extraction of copper from cuprous oxide [copper(I) oxide]
    • Extraction of zinc from zinc oxide
  • Electrochemical Principles of Metallurgy  
    • Aluminium - Hall-Heroult process
    • Copper from Low Grade Ores and Scraps
  • Refining of Crude Metals  
    • Principles and methods of extraction - Refining
    1. Distillation
    2. Liquation 
    3. Electrolytic refining (electrolytic method)
    4. Zone refining
    5. Vapour phase refining
    6. Chromatographic methods
  • Metallurgy of Aluminium  
    • Aluminium
    • Physical Properties of Aluminium
    • Chemical Properties of Aluminium
    • Uses of Aluminium
  • Extraction of Aluminium  
  • Refining of Aluminium  
    • Hoope's electrolytic process
  • Metallurgy of Copper  
  • Extraction of Copper  
  • Occurrence and Principle of Extraction of Zinc from Zinc Blende  
    • Occurrence
    • Extraction of zinc
    • Refining
  • Metallurgy of Iron  
  • Extraction of Iron  
  • Uses of Aluminium, Copper, Zinc and Iron  
21 p-Block Elements
  • Concept of Group 15 Elements  
    • Occurrence
    • Electronic Configuration
    • Atomic and Ionic Radii
    • Ionisation Enthalpy
    • Electronegativity
    • Physical Properties and Chemical Properties
  • p-Block elements of Group 15 Elements  
    • Dinitrogen  
      • Preparation, Properties, Uses
    • Ammonia  
      • Preparation, Properties, Uses
    • Nitric Acid  
      • Preparation, Properties, Uses
    • Oxides of Nitrogen  
      • Oxides of Nitrogen
      • Oxoacids of nitrogen
      • Structures of Oxides of Nitrogen
    • Phosphorus - Allotropic Forms  
      • White phosphorus
      • Red phosphorus
      • Black phosphorus
    • Compounds of Phosphorus  
    • Phosphine  
      • Preparation, Properties, Uses
    • Phosphorus Halides  
      • Phosphorus Trichloride - Preparation, Properties, Uses
      • Phosphorus Pentachloride - Preparation, Properties, Uses
    • Oxoacids of Phosphorus  
  • Concept of Group 16 Elements  

    Occurrence, Electronic Configuration, Atomic and Ionic Radii, Ionisation Enthalpy, Electron Gain Enthalpy, Electronegativity, Physical Properties and Chemical Properties (Oxidation states and trends in chemical reactivity and Anomalous behaviour of oxygen)

  • P - Block Group 16 Elements  
    • Dioxygen  
      • Preparation, Properties, Uses
    • Classification of Oxides  
    • Simple Oxides  
    • Ozone  
      • Preparation, properties, structures, and uses
    • Sulphur - Allotropic Forms  
      • Rhombic sulphur (α-sulphur)
      • Monoclinic sulphur (β-sulphur)
    • Sulphur Dioxide  
      • Preparation, Properties, Uses
    • Oxoacids of Sulphur  
      • Structures of oxoacids of sulphur
    • Sulphuric Acid  
      • Preparation, properties, structures, and uses
  • Concept of Group 17 Elements  

    Occurrence, Electronic Configuration, Atomic and Ionic Radii, Ionisation Enthalpy, Electron Gain Enthalpy, Electronegativity, Physical Properties and Chemical Properties (Oxidation states and trends in chemical reactivity and Anomalous behaviour of fluorine)

  • P - Block Group 17 Elements  
    • Chlorine  
      • Preparation, Properties, Uses
    • Hydrogen Chloride  
      • Preparation, Properties, Uses
    • Oxoacids of Halogens  
      • Oxides and oxoacids of halogens
    • Interhalogen Compounds  
      • Structures of Interhalogen compounds
  • P - Block Group 18 Elements  
    • Concept of Group 18 Elements  

      Occurrence, Electronic Configuration, Ionisation Enthalpy, Atomic Radii, Electron Gain Enthalpy, Physical Properties and Chemical Properties (Xenon-fluorine compounds and Xenon-oxygen compounds)

  • Compounds of Xenon  
    • Compounds of Xenon
    1. Xenon fluorides
      a) Xenon difluoride (XeF2)
      b) Xenon tetrafluoride (XeF4)
      c) Xenon hexafluoride (XeF6)
    2. Xenon oxides
      a) Xenon trioxide (XeO3)
      b) Xenon tetraoxide (XeO4)
      c) XeOF4 and XeO2F2
  • Uses of Noble Gases  
    • Uses of Helium
    • Uses of Neon
    • Uses of Argon
    • Uses of Krypton
    • Uses of Xenon
    • Uses of Radon
22 d and f-block Elements
  • General Introduction of "D" and "F" Block Element  
  • Position in the Periodic Table - d-block Elements  
    • Occurrence and characteristics of transition metals
  • Electronic Configurations of the D-block Elements  
  • General Properties of the Transition Elements (D-block)  
    • Properties of the first-row transition metals – metallic character
    • Atomic and ionic radii
    • Metallic character
    • Melting and boiling points
    • Colour
    • Physical Properties
    • Variation in Atomic and Ionic Sizes of Transition Metals
    • Ionisation Enthalpies
    • Oxidation States
    • Standard electrode potentials
    • Trends in the M2+/M Standard Electrode Potentials
    • Trends inthe M3+/M2+ Standard Electrode Potentials
    • Trends in Stability of Higher Oxidation States
    • Chemical Reactivity and Eθ Values
    • Magnetic Properties
    • Formation of Coloured Ions
    • Formation of Complex Compounds
    • Catalytic Properties
    • Complex formation
    • Formation of Interstitial Compounds
    • Alloy Formation
    • Oxides and oxoanions of transition metals
  • Some Important Compounds of Transition Elements - Oxides and Oxoanions of Metals  
    • Potassium dichromate K2Cr2O7
    • Potassium permanganate KMnO4
  • F-block Elements  
    • The Lanthanoids  

      Electronic Configurations, Atomic and Ionic Sizes, Oxidation States, General Characteristics, Chemical Reactivity and Lanthanoid Contraction and Its Consequences

    • The Actinoids  

      Electronic Configurations, Ionic Sizes, Oxidation States, General Characteristics and Comparison with Lanthanoids between lanthanoids and actinoids

  • Some Applications of d and f Block Elements  
23 Coordination Compounds
24 Haloalkanes and Haloarenes
  • Introduction to Haloalkanes  
    • Halogen derivatives of alkanes and arenes
    • Haloalkanes
  • Classification of Haloalkanes  
    • Classification of haloalkanes
    • Classification of haloalkanes on the basis of the number of halogen atoms
    1. Monohaloalkanes
    2. Dihaloalkanes
    3. Trihaloalkanes
    4. Polyhaloalkanes
    • Classification of monohalocompounds on the basis of hybridisation of the carbon atom to which the halogen is bonded (nature of C-X bond)
    1. Compounds Containing sp3 C—X Bond (X = F, Cl, Br, I)
    2. Compounds Containing sp2 C—X Bond
  • Nomenclature of Haloalkanes  
    • Common and IUPAC names of some monohalogen derivatives
  • Nature of C - X Bond in Haloalkanes  
  • Preparation of Haloalkanes  
    • Preparation of Haloalkanes
    1. By halogenation of alkanes
    2. By halogenation of alkenes
    3. By addition of hydrogen halides to alkenes
    4. From alcohols
    5. By halogen exchange
  • Physical Properties of Haloalkanes  
  • Chemical Properties of Haloalkanes  
    1. Nucleophilic substitution reactions
    2. Elimination reactions
    3. Reaction with metals
    4. Laboratory test for haloalkanes
  • Stereochemistry  
    • Optical activity
    • Chirality
    • Enantiomers
    • Racemic mixture
    • R, S configuration
  • Nucleophilic substitution Mechanism  
    • Nucleophilic substitution (SN) reaction
    • SN2 Mechanism
    • SN1 Mechanism
    • Comparison between SN2 and SN1 reaction
  • Haloarenes  
    • Nomenclature of haloarenes
    • Nature of C- X bond in haloarenes
    • Methods of preparation
    • Physical properties
    • Chemical properties
  • Classification of Haloarenes  
  • Nomenclature of Haloarenes  
  • Nature of C - X Bond in Haloarenes  
  • Preparation of Haloalkanes  
    1. By electrophilic substitution
    2. Sandmeyer's reaction
  • Physical Properties of Haloarenes  
  • Chemical Properties of Haloarenes  
    1. Substitution reactions
    2. Reactions with metals
    3. Nucleophilic substitution reactions
    4. Electrophilic substitution reactions: Halogenation, Nitration, Friedel-Craft's reaction, Sulphonation
    5. Reaction with sodium metal: Wurtz Fittig reaction, Fittig reaction
  • Uses and Environmental Effects of Some Polyhalogen Compounds  
    • Dichloromethane/methylene chloride (CH2Cl2)
    • Chloroform/trichloromethane (CHCl3)
    • Carbon tetrachloride/tetrachloromethane (CCl4)
    • Idoform or triiodomethane (CHI3)
    • Freons
    • Dichlorodiphenyltrichloroethane (DDT)
25 Alcohols, Phenols and Ethers
  • Introduction of Alcohols, Phenols, and Ethers  
    • Oxygen-containing functional groups
    1. Alcohols and phenols
    2. Ethers
  • Alcohol  
    • Uses of Alcohols  
      • Uses of methyl alcohol
      • Uses of ethyl alcohol
  • Classification of Alcohols  
    • Classification of alcohols
    • On the basis of number of -OH groups
    1. Monohydric alcohol
    2. Dihydric alcohol
    3. Trihydric alcohol
    4. Polyhydric alcohol
    • On the basis of nature of C-OH bond
    1. Csp3 - OH bond: Alkyl, Allylic, Benzylic alcohols
    2. Csp2 - OH bond
  • Nomenclature of Alcohols  
  • Isomerism in Alcohols  
    • Isomerism in alcohols
    1. Chain isomerism
    2. Position isomerism
    3. Functional isomerism
    4. Optical isomerism
    5. Cis-trans isomerism
  • Structure of functional group (-OH) of Alcohols  
  • Methods of Preparation of Alcohols  
    • From alkenes
      (i) By acid catalysed hydration: Mechanism of dehydration
      (ii) By hydroboration-oxidation
    • From carbonyl compounds
      (i) By reduction of aldehydes and ketones
      (ii) By reduction of carboxylic acids and esters
    • From Grignard reagents
  • Preparation of Commercially Important Alcohols  
    • Methanol
    • Ethanol
  • Physical Properties of Alcohols  
  • Chemical Properties of Alcohols  
    1. Alcohols as nucleophiles
    2. Protonated alcohols as electrophiles
    • Chemical reactions of alcohols
    1. Reactions involving breaking of O-H bond
      a) Action of metals
      b) Acidic nature of alcohols
      c) Alcohols are weaker acids than water
      d) Esterification
    2. Reactions involving breaking of C-O bond
      a) Reaction with hydrogen halides (HBr, HCI and HI)
      b) Reaction with phosphorus halides (PX3/PX5) and thionyl chloride (SOCl2)
    3. Oxidation of alcohols
      a) Primary alcohols
      b) Secondary alcohols
      c) Tertiary alcohols
      d) Action of copper on alcohol
  • Phenols  
    • Acidic Nature of Phenol  
      • Acidic nature of phenols
      • pKa values of alcohols and phenols
    • Uses of Phenols  
  • Classification of Phenols  
    • Classification of phenols
    1. Monohydric phenols
    2. Dihydric phenols
    3. Tribydric phenols
  • Nomenclature of phenols  
    • Nomenclature of phenols
    1. Monohydric phenols
    2. Dihydric phenols
    3. Trihydric phenols
  • Structure of Functional Group (Ar - OH) of Phenol  
  • Methods of Preparation of Phenols  
    • From chlorobenzene: Dow's method (Commercial method)
    • From benzene sulphonic acid
    • From diazonium salts
    • From cumene (Commercial method)
    • From Aniline (Diazotization method)
  • Physical Properties of phenol  
  • Chemical Properties of Phenol  
    • Chemical Properties of Phenol
    1. Reactions involving cleavage of O-H bond: Reaction with metals, Esterification, Acetylation
    2. Electrophilic aromatic substitution reactions of phenol
      (i) Nitration
      (ii) Halogenation (bromination)
    3. Kolbe's reaction
    4. Reimer-Tiemann reaction
    5. Reaction of phenol with zinc dust
    6. Catalytic hydrogenation
    7. Oxidation reaction
    • Distinguishing test between alcohols and phenols
    • Differentiation between alcohols and phenols
  • Ethers  
    • Preparation of Ethers  
      • From alcohols by dehydration (continuous etherification process)
      • From alkyl halides (Williamson synthesis)
    • Uses of Ethers  
  • Classification of Ethers  
    • Simple or Symmetrical
    • Mixed or Unsymmetrical
  • Nomenclature of ethers  
  • Structure of functional group (R-O-R')  
  • Isomerism of Ether  
    • Isomerism
    1. Chain isomerism
    2. Functional isomerism
    3. Metamerism
  • Physical Properties of Ethers  
  • Chemical Properties of Ethers  
    • Chemical properties of ethers
    • Laboratory test for ethers
    • Reaction involving alkyl group of ether
    • Action of hydrogen halide
    • Hydrolysis (action of dilute H2SO4)
    • Reaction with PCl5
    • Electrophilic substitution reactions: Halogenation, Nitration and Friedel-crafts reaction
26 Aldehydes, Ketones and Carboxylic Acids
  • Introduction of Aldehydes, Ketones and Carboxylic Acids  
  • Classification of Ketones  
    • Classification of ketones
    1. Simple or symmetrical ketones
    2. Mixed or unsymmetrical ketones
  • Nature of Carbonyl Group  
  • Nomenclature of Aldehydes  
  • Nomenclature of Ketones  
  • Aldehydes and Ketones  
    • Preparation of Aldehydes  
      1. From acyl chloride (acid chloride)
      2. From nitriles and esters
      3. From hydrocarbons
        (i) By oxidation of methylbenzene
        (a) Use of chromyl chloride (CrO2Cl2)
        (b) Use of chromic oxide (CrO3)
        (ii) By side chain chlorination followed by hydrolysis
        (iii) By Gatterman – Koch reaction
    • Preparation of Ketones  
      • From acyl chlorides
      • From nitriles
      • From benzene or substituted benzenes
    • Chemical Reactions of Aldehydes and Ketones - Nucleophilic Addition Reactions  
      1. Mechanism of nucleophilic addition reactions
      2. Reactivity
      3. Some important examples of nucleophilic addition and nucleophilic addition-elimination reactions
        (a) Addition of hydrogen cyanide (HCN)
        (b) Addition of sodium hydrogensulphite
        (c) Addition of Grignard reagents
        (d) Addition of alcohols
        (e) Addition of ammonia and its derivatives
    • Chemical Reactions of Aldehydes and Ketones - Reduction  
      • Reduction to alcohols
      • Reduction to hydrocarbons
        (i) Clemmensen reduction
        (ii) Wolff-Kishner reduction
    • Chemical Reactions of Aldehydes and Ketones - Oxidation  
      • Tollens’ test
      • Fehling’s test
      • Oxidation of methyl ketones by haloform reaction
    • Chemical Reactions of Aldehydes and Ketones - Reactions Due to α-hydrogen  
      • Acidity of α-hydrogens of aldehydes and ketones
        (i) Aldol condensation 
        (ii) Cross aldol condensation
    • Chemical Reactions of Aldehydes and Ketones - Other Reactions  
      • Cannizzaro reaction
      • Electrophilic substitution reaction
  • Physical Properties of Aldehydes  
  • Physical Properties of Ketones  
  • Uses of Aldehydes and Ketones  
  • Introduction of Carboxylic Acids  
    • Classification of mono and di carboxylic acids with examples.
  • Classification of Carboxylic Acids  
    • Classification of carboxylic acids
    1. Aliphatic carboxylic acids
      a) Mono-carboxylic acids
      b) Dicarboxylic acids
      c) Tricarboxylic acids
      d) Polycarboxylic acids
    2. Aromatic carboxylic acids
      a) Aromatic mono-carboxylic acids
      b) Aromatic dicarboxylic acids
  • Acids  
    • Nomenclature of Carboxylic Acids  
    • Structure of the Carboxyl group  
    • Methods of Preparation of Carboxylic Acids  
      • Oxidation of primary alcohols and aldehydes
      • Oxidation of alkyl benzene
      • From nitriles and amides (hydrolysis)
      • From aryl amines and alkyl halides
      • Carboxylation of Grignard reagent
      • Hydrolysis of acyl chloride and acid anhydride
      • Hydrolysis of esters
    • Chemical Reactions of Carboxylic Acids - Reactions Involving Cleavege of O-H Bond  
      1. Carboxylic acids are distinctly acidic in nature
        a) Action of active metals
        b) Action of alkali (like NaOH or KOH)
        c) Action of NaHCO3 and Na2CO3
      2. Acidic strength of the carboxylic acids
      3. Carboxylic acids are more acidic than phenols
      4. Effect of substituents on the acidity of carboxylic acids
    • Chemical Reactions of Carboxylic Acids - Reactions Involving Cleavege of C-OH Bond  
      • Reactions involving -OH part of the carboxyl group
      1. Formation of acyl chlorides (action of SOCl2, PCl3, or PCl5)
      2. Formation of esters (action of alcohols): Fischer-Speier esterification
      3. Formation of acid anhydride
      4. Formation of amides
    • Chemical Reactions of Carboxylic Acids - Reactions Involving –COOH Group  
      • Reactions involving -COOH group
      1. Partial reduction to alcohols
      2. Formation of hydrocarbons (Decarboxylation)
    • Chemical Reactions of Carboxylic Acids - Substitution Reactions in the Hydrocarbon Part  
      • Reactions due to the alkyl group and/or aryl group present in the carboxylic acid
      1. α-Halogenation
      2. Ring substitution
  • Physical Properties of Carboxylic Acids  
  • Uses of Carboxylic Acids  
27 Organic Compounds Containing Nitrogen
  • Introduction of Organic Compounds Containing Nitrogen  
  • Classification of Amines  
    • Classification of amines
    1. Aliphatic amines
    2. Aromatic amines
  • Structure of Amines  
  • Physical Properties of Amines  
  • Amines  
    • Nomenclature of Animes  
    • Preparation of Amines  
      • From alkyl halides (by ammonolysis/Hoffmann's ammonolysis method)
      • Gabriel phthalimide synthesis
      • From alkyl cyanides, amides, and nitro compounds
      • From amides (By Hoffmann bromamide degradation)
      • Additional methods for the preparation of amines
    • Chemical Reactions of Amines - Basic Character of Amines  
      • Structure-basicity relationship of amines
        (a) Alkanamines versus ammonia
        (b) Arylamines versus ammonia
    • Chemical Reactions of Amines - Alkylation and Acylation  
      • Alkylation of amines (Hoffmann's exhaustive alkylation)
      • Hoffmann elimination
      • Benzoylation
    • Chemical Reactions of Amines - Carbylamine Reaction  
    • Chemical Reactions of Amines - Reaction with Nitrous Acid  
    • Chemical Reactions of Amines - Reaction with Arylsulphonyl Chloride  
    • Reaction with Grignard Reagent  
    • Chemical Reactions of Amines - Electrophilic Substitution  
      • Bromination
      • Nitration
      • Sulphonation
    • Identification of Primary, Secondary and Tertiary Amines  
      • Action of nitrous acid
      1. Primary amines
      2. Secondary amines
      3. Tertiary amines
      • Hoffmann's carbylamine test (isocyanide test)
      • Hinsberg's test
    • Uses of Amines  
  • Introduction of Diazonium Salts  
    • Introduction
    • Resonance structure 
    • Method of preparation of Diazonium salts
    • Physical properties 
    • Chemical reactions
    1. Replacement reactions involving loss of nitrogen 
    2. Reactions involving retention of diazo group
  • Diazonium Salts  
    • Method of Preparation of Diazonium Salts  
      • Preparation of diazonium salts by reaction of Aniline and nitrous acid
    • Chemical Reaction of Diazonium Salts - Reactions Involving Displacement of Nitrogen  
      • Replacement by halide or cyanide ion,
        - Sandmeyer reaction
        - Gatterman reaction
      • Replacement by iodide ion
      • Replacement by fluoride ion (Balz-Schiemann reaction or Schiemann reaction)
      • Replacement by H
      • Replacement by hydroxyl group
      • Replacement by –NO2 group
    • Chemical Reaction of Diazonium Salts - Reactions Involving Retention of Diazo Group  
      •  Coupling Reactions
    • Importance of Diazonium Salts in Synthesis of Aromatic Compounds  
      • Uses of diazonium salts
  • Cyanides and Isocyanides  
    • Introduction 
    • alkyl cyanides and alkyl isocyanides
    1. Alkyl cyanides - Preparation, Properties, and reactions
    2. Alkyl isocyanides: Preparation, Properties, and reactions
28 Biomolecules
  • Biomolecules  
    • Biomolecules
    • Importance of biomolecules
  • Carbohydrates  
    • Carbohydrates
    • Classification of carbohydrates
  • Classification of Carbohydrates  
    • Classification of carbohydrates
    • On the basis of hydrolysis
    1. Simple carbohydrates
      i) Monosaccharides: Aldoses and Ketoses
    2. Complex carbohydrates
      i) Oligosaccharides: Disaccharides, Trisaccharides, Tetrasaccharides
      ii) Polysaccharides: Homopoly-saccharides and Heteropoly-saccharides
    • On the basis of solubility
    1. Sugars: Reducing and Non-reducing sugars
    2. Non-sugars
  • Structures of Some Monosaccharides  
  • D- and L-configuration  
    • Optical activity
  • Carbohydrates  
    • Monosaccahrides  
      •  D-l Configuration
    • Preparation of Glucose  
      • Preparation of glucose
      1. From sucrose or cane sugar (laboratory method)
      2. From starch (commercial method)
    • Structures of Glucose  
      • Structures of glucose
      1. Open chain structure of glucose
      2. Cyclic structure of glucose
      • Haworth projection formulae
    • Structure of Fructose  
      • Fructose
      • Structure of fructose
      • Haworth projection formulae
    • Oligosaccharides  
      • Sucrose, lactose, maltose
    • Disaccharides - Sucrose, Maltose and Lactose  
    • Polysaccharides - Starch, Cellulose and Glycogen  
  • Importance of Carbohydrates  
  • Introduction of Proteins  
  • Proteins  
    • Amino Acids  
      • Elementary idea of α-amino acids
    • Classification of Amino Acids  
      • Classification of amino acids
      • Based on the number of -NH2 and -COOH groups
      1. Acidic amino acids
      2. Basic amino acids
      3. Neutral amino acids
      • Based on the source
      1. Essential amino acids
      2. Non-essential amino acids
    • Structure of Proteins  
      • Peptide bond and Peptide Linkage
      • Dipeptide, tripeptide
      • Tetrapeptide, Pentapeptide or Hexapeptide
      • Polypeptides
      • Classification of Proteins on the basis of their molecular shape
        (a) Fibrous proteins
        (b) Globular proteins
        - Structure of amines-primary, secondary, tertiary structure and quaternary structures
      • a-Helix structure, β-Pleated sheets
    • Denaturation of Proteins  
  • Introduction of Enzymes  
  • Chemical Coordination  

    Chemical Coordination

    1. Autocrine 
    2. Paracrine 
    3. Endocrine 
    4. Pheromone 
  • Introduction of Vitamins  
    • Classification and functions of vitamins 
  • Vitamins  
    • Classification of Vitamins  
  • Introduction of Nucleic Acids  
    • Structure of DNA
    • Structure of RNA
    • Differences between DNA and RNA
  • Nucleic Acids  
    • Chemical Composition of Nucleic Acids  
      • Chemical composition of nucleic acids
      1. Nitrogen containing heterocyclic compounds (bases)
      2. Sugars
      3. Phosphate group
    • Structure of Nucleic Acids  
    • Biological Functions of Nucleic Acids  
  • Structure of Nucleosides  
  • Structure of Nucleotide  
29 Polymers
  • Introduction to Polymers  
    • Introduction to Polymers  
    • Classification of Polymers Based on Source  

      Natural polymers, Semi-synthetic polymers, Synthetic polymers

    • Classification of Polymers Based on Structure  

      Linear polymers, Branched chain polymers, Cross linked or Network polymers

    • Classification of Polymers Based on Mode of Polymerisation  

      Addition polymers, Condensation polymers

    • Classification of Polymers Based on Molecular Forces  

      Elastomers, Fibres, Thermoplastic polymers, Thermosetting polymers

    • Classification Based on the Types of Monomeric Units  
      • Classification based on the types of monomeric units
      1. Homopolymers
      2. Copolymers
    • Classification Based on the Biodegradability  
      • Classification based on the biodegradability
      1. Non-biodegradable polymers
      2. Biodegradable polymers
    • Some Important Polymers  
      • Rubber
      • Polythene
      • Teflon
      • Polyacrylonitrile
      • Polyamide polymers
      • Polyesters
      • Phenol - formaldehyde and related polymers
      • Buna-S rubber
      • Neoprene
      • Viscose rayon
  • Types of Polymerisation Reactions - Copolymerisation  
  • Types of Polymerisation Reactions - Addition Polymerisation or Chain Growth Polymerisation  
    • Mechanism of Addition Polymerisation
      1) Free radical mechanism
    • Some Important Addition Polymers
      (a) Polythene
      (i) Low density polythene
      (ii) High density polythene
      (b) Polytetrafluoroethene (Teflon)
      (c) Polyacrylonitrile
  • Types of Polymerisation Reactions - Condensation Polymerisation Or Step Growth Polymerisation  
    • Condensation Polymerisation or Step Growth Polymerisation
    • Some Important Condensation Polymers
      (a) Polyamides: Nylons
      (i) Nylon 6, 6
      (ii) Nylon 6
      (b) Polyesters
      (c) Phenol - formaldehyde polymer (Bakelite and related polymers)
      (d) Melamine - formaldehyde polymer
  • Types of Polymerisation Reactions - Rubber  
    • Natural rubber (Vulcanisation of rubber),
    • Synthetic rubbers
    1. Buna-S rubber
    2. Buna-N rubber or nitrile rubber
    3. Neoprene rubber
  • Molecular Mass of Polymers  
  • Biodegradable Polymers  
    • Poly β-hydroxybutyrate – co-β-hydroxy valerate (PHBV)
    • Nylon 2– nylon 6
    • Biodegradable and non-biodegradable polymers
  • Polymers of Commercial Importance  

    Polypropene, Polystyrene, Polyvinyl chloride (PVC), Urea-formaldehyle Resin, Glyptal, Bakelite

30 Chemistry in Everyday Life
31 Principles Related to Practical Chemistry
  • Introduction of Principles Related to Practical Chemistry  
    • Analytical chemistry
    • Analytical chemistry deals with methods for
    1. Qualitative analysis
    2. Quantitative analysis
    • Basic laboratory techniques
  • Qualitative Analysis of Organic Compounds - Detection of Other Elements  
    • Test for Nitrogen
    • Test for Sulphur
    • Test for Halogens
    • Test for Phosphorus
  • Detection of Functional Groups in Organic Compounds  
    • Functional group
    • Test for alcoholic (R-OH) group
    1. Presence of R-OH group
    2. Distinguishing between 1°, 2°, and 3° alcohols (Lucas test)
    • Test for phenolic (Ar-OH) group
    1. Presence of Ar-OH group
    2. Colours produced by some phenolic compounds
    • Test for carbonyl group
    • Test for carboxyl (-COOH) group
    • Test for amino (-NH2) group
  • Chemistry Involved in Preparation of Organic Compounds  
    • Acetanilide
    • p-Nitroacetanilide
    • Aniline yellow/p-aminoazobenzene
    • lodoform
  • Chemistry Involved in Preparation of Inorganic Compounds  
    • Mohr's salt
    • Potash alum
  • Chemistry Involved in Titrimetric Exercises  
    • Titrimetric analysis
    • Concentration or strength of a solution
    • Normality
    • Equivalent weight
    • Types of titrations
    • Acid base titrations
    • Determination of the concentration .(strength) of a given solution of sodium hydroxide by titrating it against a standard solution of oxalic acid
    • Determination of the concentration (strength) of a given solution of hydrochloric acid by titrating it against a standard solution of sodium carbonate
    • Redox titrations
    • Determination of the concentration/molarity of KMnO4 solution by titrating it against a 0.1 M standard solution of oxalic acid
    • Determination of the concentration/molarity of potassium permanganate (KMnO4) solution by titrating it against standard solution of ferrous ammonium sulphate (Mohr's salt)
  • Chemical Principles Involved in the Qualitative Salt Analysis  
    • Systematic qualitative analysis of salts
    • Systematic qualitative analysis of basic radicals (cations)
    • Systematic qualitative analysis of acidic radicals (anions)
  • Chemical Principles Involved in the Determination of Enthalpy of Solution  
    • Enthalpy change
    • Determination of the enthalpy of dissolution of copper sulphate using calorimetric technique
  • Chemical Principles Involved in Enthalpy of Neutralization of Strong Acid and Strong Base  
    • Enthalpy of neutralization
    • Determination of enthalpy of neutralization of strong acid and strong base
  • Chemical Principles Involved in Preparation of Lyophilic and Lyophobic Sols  
    • Colloidal solution
    • Preparation of lyophilic sol
    • Preparation of lyophobic sol
  • Chemical Principles Involved in the Kinetic Study of Reaction of Iodide Ion with Hydrogen Peroxide at Room Temperature  
    • Rate of reaction
    • Kinetic study of reaction of iodide ion with hydrogen peroxide at room temperature
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