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Question
Write IUPAC name of the following
\[\begin{array}{cc}\ce{CH3-CH-CH-CH2-OH}\\|\phantom{.....}|\phantom{.......}\\\ce{OH}\phantom{..}\ce{CH3}\phantom{.....}\end{array}\]
Solution
2-Methylbutane-1,3-diol
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\[\begin{array}{cc}
\phantom{............}\ce{CH2OH}\\
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\phantom{................}\ce{CH3}\\
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\ce{H3C - CH - CH2 - CH - CH - CH2 - CH3}\\
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\end{array}\]
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\[\begin{array}{cc}
\ce{CH3 - CH - CH - CH3}\\
|\phantom{......}|\phantom{..}\\
\ce{OH}\phantom{...}\ce{OH}\phantom{}
\end{array}\]
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|\phantom{..}\\
\ce{OH}
\end{array}\]
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\[\begin{array}{cc}
\phantom{..}\ce{H}\phantom{...}\ce{CH3}\phantom{.}\ce{H}\phantom{..}\\
\phantom{}|\phantom{....}|\phantom{....}|\phantom{}\\
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\phantom{}|\phantom{....}|\phantom{....}|\phantom{}\\
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\end{array}\]
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\[\begin{array}{cc}
\ce{CH3-CH-OCH3}\\
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\end{array}\]
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\[\begin{array}{cc}
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\end{array}\]
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Explain why p-nitrophenol is more acidic than phenol.
Match the structures of the compounds given in Column I with the name of the compounds given in Column II.
Column I | Column II | |
(i) | ![]() |
(a) Hydroquinone |
(ii) | ![]() |
(b) Phenetole |
(iii) | ![]() |
(c) Catechol |
(iv) | ![]() |
(d) o-Cresol |
(v) | ![]() |
(e) guinone |
(vi) | ![]() |
(f) Resorcinol |
(g) Anisole |
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Column I | Column II | ||
(i) | CH3—O—CH3 | (a) | ![]() |
(ii) | \[\begin{array}{cc} \ce{CH3}\phantom{..................}\\ \backslash\phantom{.............}\\ \ce{CH-O-CH3}\\ /\phantom{..............}\\ \ce{CH3}\phantom{..................} \end{array}\] |
(b) | \[\begin{array}{cc} \ce{CH3}\phantom{....}\\ |\phantom{.......}\\ \ce{CH3-C-I + CH3OH}\\ |\phantom{.......}\\ \ce{CH3}\phantom{....} \end{array}\] |
(iii) | \[\begin{array}{cc} \ce{CH3}\phantom{.}\\ |\phantom{....}\\ \ce{H3C-C-O-CH3}\\ |\phantom{....}\\ \ce{CH3}\phantom{..} \end{array}\] |
(c) | ![]() |
(iv) | ![]() |
(d) | CH3—OH + CH3—I |
(e) | \[\begin{array}{cc} \ce{CH3}\phantom{.....................}\\ \backslash\phantom{.................}\\ \ce{CH-OH + CH3I}\\ /\phantom{.................}\\ \ce{CH3}\phantom{.....................} \end{array}\] |
||
(f) | \[\begin{array}{cc} \ce{CH3}\phantom{.....................}\\ \backslash\phantom{.................}\\ \ce{CH-I + CH3OH}\\ /\phantom{.................}\\ \ce{CH3}\phantom{.....................} \end{array}\] |
||
(g) | \[\begin{array}{cc} \ce{CH3}\phantom{....}\\ |\phantom{.......}\\ \ce{CH3-C-OH + CH3I}\\ |\phantom{.......}\\ \ce{CH3}\phantom{....} \end{array}\] |
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\[\begin{array}{cc}
\ce{CH3 - CH - O - CH2 - CH2 - CH3}\\
|\phantom{....................}\\
\ce{CH3}\phantom{.................}
\end{array}\] is 2-Ethoxy-2-methylethane.
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\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{..}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]
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\[\begin{array}{cc}
\phantom{...............}\ce{CH3}\\
\phantom{............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{...}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]
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\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C -CH3}\\
\phantom{.}|\phantom{......}|\phantom{......}|\\
\phantom{....}\ce{CH3\phantom{...}\ce{OH}\phantom{...}\ce{CH3}}\
\end{array}\]
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\[\begin{array}{cc}
\phantom{...............}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3\phantom{...}OH\phantom{...}CH3}\\
\end{array}\]
Write the IUPAC name of the following compound:
\[\begin{array}{cc}
\phantom{...............}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{..}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]