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Write the mathematical equation for the first law of thermodynamics for: Isothermal process - Chemistry

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Write the mathematical equation for the first law of thermodynamics for:

Isothermal process

Deduce the first law of thermodynamics for the isothermal process.

Numerical

Solution

For isothermal process:

For a given temperature (T) and internal energy (U) of the remains constant.

∴ ΔT = 0

∴ ΔU = 0

First law of thermodynamic

ΔU = Q + W

0 = Q + W    ...(∵ ΔU = 0)

∴ Q = – W

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First Law of Thermodynamics
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2021-2022 (March) Set 1

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