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Basicity and Acidity

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Topics

  • Basicity and Acidity
  • Experiment
  • Concentration of Solutions

Basicity and Acidity:

The terms basicity of acids and acidity of bases describe the number of ions that acids or bases can release when they dissociate in water. These properties are important for understanding the strength and reactivity of acids and bases.

1. Basicity of Acids

The basicity of an acid refers to the number of H⁺ ions (protons) that can be released by one molecule of the acid when it dissociates in water.

Types of Acids Based on Basicity:

Type of Acid Monobasic Acids Dibasic Acids Tribasic Acids
Definition These acids release one H⁺ ion per molecule. These acids release two H⁺ ions per molecule. These acids release three H⁺ ions per molecule.
Example Hydrochloric acid (HCl) Sulfuric acid (H₂SO₄) Phosphoric acid (H₃PO₄)
Dissociation Reaction HCl → H⁺ + Cl⁻ H₂SO₄ → H⁺ + HSO₄⁻ , HSO₄⁻ → H⁺ + SO₄²⁻ H₃PO₄ → H⁺ + H₂PO₄⁻ , H₂PO₄⁻ → H⁺ + HPO₄²⁻ , HPO₄²⁻ → H⁺ + PO₄³⁻
Basicity 1 2 3

2. Acidity of Bases

The acidity of a base refers to the number of OH⁻ ions (hydroxide ions) that can be released by one molecule of the base when it dissociates in water.

Type of Base Monoacidic Bases Diacidic Bases Triacidic Bases
Definition These bases release one OH⁻ ion per molecule. These bases release two OH⁻ ions per molecule. These bases release three OH⁻ ions per molecule.
Example Sodium hydroxide (NaOH) Calcium hydroxide (Ca(OH)₂) Aluminum hydroxide (Al(OH)₃)
Dissociation Reaction NaOH → Na⁺ + OH⁻ Ca(OH)₂ → Ca²⁺ + 2OH⁻ Al(OH)₃ → Al³⁺ + 3OH⁻
Acidity 1 2 3

 

Experiment

1. Aim: To observe the effect of solute concentration (lemon juice) on the taste of a solution.

2. Requirements: lemon (1), two beakers, knife, drinking water, stirring rod, and measuring cylinder (to measure water).

3. Procedure: Cut a lemon into two equal halves. Squeeze the juice from each half into two separate beakers.

Add Water:

  • In the first beaker, add 10 ml of water.
  • In the second beaker, add 20 ml of water.

Stir both solutions thoroughly using a stirring rod. Taste the solution in both beakers and observe the difference in sourness.

Solution of lemon juice

4. Observations

  • The solution in the first beaker (with 10 ml of water) tastes more sour.
  • The solution in the second beaker (with 20 ml of water) tastes less sour.

5. Conclusion: The sour taste is due to the lemon juice (solute) in the solutions. Although the quantity of lemon juice is the same in both beakers, the concentration of the solute is higher in the first beaker because it has less water (solvent). The solution in the second beaker is more diluted because the ratio of solute to solvent is smaller.

This experiment shows that the concentration of a solution affects its properties, such as taste.

Concentration of Solutions:

The concentration of a solution refers to the proportion of solute (the substance being dissolved) in the solution. It is an important property that determines how the solution behaves and impacts its characteristics.

1. The Properties of a Solution Depend on

  • The nature of the solute (e.g., salt, sugar, acid, etc.).
  • The nature of the solvent (e.g., water, alcohol, etc.).
  • The proportion of solute in the solution.

2. Types of Solutions Based on Concentration

  • Concentrated Solution: A solution with a high proportion of solute compared to the solvent.
  • Dilute Solution: A solution with a low proportion of solute compared to the solvent.

3. Units to Express Concentration

  • Grams per Litre (g/L): Measures the mass of solute (in grams) dissolved in 1 litre of solution.
  • Molarity (M): Measures the number of moles of solute dissolved in 1 litre of solution.

Represented as: [NaCl] = 1M (1 Molar)

This means 1 mole of sodium chloride (NaCl) is dissolved in 1 litre of solution.

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